Manganese Dioxide or Manganese(IV) Oxide Manufacturers, with SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Manganese Dioxide or Manganese(IV) Oxide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy Portugal, Bangladesh, etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Manganese Dioxide or Manganese(IV) Oxide CAS Number 1313-13-9 or 197667-28-0, EINECS EC Number: 215-202-6, Molecular Formula: MnO2, Molecular Weight: 86.94, HS Code 28201010 or 28201000
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SDS MSDS Sheet of Manganese Dioxide or Manganese(IV) Oxide Manufacturers
Manganese Dioxide
Manganese(IV) Oxide Suppliers
Manganese Dioxide or Manganese(IV) Oxide is a blackish or brown solid occurs naturally as a mineral. The principal use for Manganese Dioxide or Manganese(IV) Oxide is for dry-cell batteries. It is also used as a pigment and as a precursor to other manganese compounds.
General Properties and Specifications of Manganese Dioxide or Manganese(IV) Oxide:
Appearance: Brown black powder.
Mn Content: Not more than 42.73%
Assay: Not less than 60% (Minimum 80% assay can also be offered.)
Relative Density: about 5.03
Melting Point: 535C.
Solubility: Insoluble in water.
Storage: Below 30C. Short term shipment may be ambient.
We also manufacture and supply as under:
Manganese Dioxide or Manganese(IV) Oxide
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30
e-mail: info@mubychem.com
USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)
Copyright and Usual Disclaimer is Applicable.
Last
11 June, 2024
Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.
Global or International Suppliers, Exporters, Importers, Manufacturers
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Manganese Dioxide or Manganese(IV) Oxide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 11-Jun-24
1. Product Identification
Product Name & Other Names: Manganese Dioxide or Manganese(IV) Oxide.
CAS No.: 1313-13-9 or 197667-28-0
EINECS EC-No.: 215-202-6
Molecular Weight: 86.94
Chemical Formula: MnO2
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral Category 4 - H302
Acute toxicity, inhalation Category 4 - H332
Specific target organ toxicity, repeated exposure Category 2 - H373
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements  Irritant |
GHS Label Elements |
Signal Words: Warning
Hazard statements:
H302: Harmful if swallowed.
H332: Harmful if inhaled.
H373: Causes damage to organs through prolonged or repeated exposure.
Precautionary statements:
P201 Obtain special instructions before use.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn = Harmful.
Risk Phrases:
R20/22 Harmful by inhalation and if swallowed.
R48 Danger of serious damage to health by prolonged exposure.
3. Composition/Information on Ingredients
Product Name & Other Names: Manganese Dioxide or Manganese(IV) Oxide.
CAS No.: 1313-13-9 or 197667-28-0
EINECS EC-No.: 215-202-6
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush your eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Avoid solid streams of water since the stream will scatter and spread the fire. Water spray may be used to keep fire exposed containers cool. Manganese/manganese oxides will be formed on combustion. It can aid combustion by release of oxygen.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and a suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Mop up and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Keep away from heat. Keep away from sources of ignition. Stop leaking without risk. Pick up and dispose of hazardous waste. Keep in suitable, closed containers for disposal. Finish cleaning by spreading water on the contaminated surface and dispose as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and reducing agents. Storage: Below 30C. Short term shipment may be ambient.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
USA ACGIH: 0.2 mg/m3 TWA (as Mn) (listed under Manganese, inorganic compounds).
USA OSHA - Final PELs: 5 mg/m3 Ceiling (as Mn) (listed under Manganese compounds, n.o.s.).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): Use only under a chemical fume hood. For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full-face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Brown black powder.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: about 5.03
Boiling Point: Not available.
Melting Point: 535C.
Flash point: Not available.
Auto-ignition temperature: 510C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Density (Air=1): Not available.
Vapor Pressure (mm Hg): Not available.
Evaporation Rate (BuAc=1): Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water.
Viscosity: Not available.
Molecular Weight: 86.94
Chemical Formula: MnO2
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Manganese/manganese oxides will be formed on combustion.
Hazardous Polymerization: Not reported.
Incompatibilities: Strong oxidizing agents and reducing agents.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles. Avoid dust formation, Excess heat.
11. Toxicological Information
Acute toxicity estimate Oral – 500.1 mg/kg.
Acute toxicity estimate Inhalation - 1,6 mg/l - dust/mist.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Carcinogenicity: Not available.
Danger of serious damage to health by prolonged exposure.
12. Ecological Information
Toxicity to daphnia and other aquatic invertebrates: No data available.
Persistence and Degradability: No data available.
Mobility: No data available.
Results of PBT and vPvB assessment: No data available.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.
IATA: Not regulated.
15. Regulatory Information
USA:
SARA 311/312: Acute: Yes; Chronic: Yes. See section 2.
California Proposition 65: Not listed.
16. Other Information
European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H332: Harmful if inhaled.
H373: Causes damage to organs through prolonged or repeated exposure.
Hazard Symbols:
Xn = Harmful.
Risk Phrases:
R2022 Harmful by inhalation and if swallowed.
R48 Danger of serious damage to health by prolonged exposure.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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