Ethyl Ether or Diethyl Ether or Ether USP BP Ph Eur GradeManufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ethyl Ether or Diethyl Ether or Ether, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Ethyl Ether or Diethyl Ether or Ether CAS Number 60-29-7, EINECS EC Number: 200-467-2, Molecular Formula: C4H10O or (CH3CH2)2O, Molecular Weight: 74.12, HS Code 29091900

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Ethyl Ether or Diethyl Ether or Ether.

Ethyl Ether or Diethyl Ether or Ether is an organic compound belonging to a large group of compounds called ethers; its molecular structure consists of two ethyl groups linked through an oxygen atom, as in C2H5OC2H5. Ethyl ether is a colouless, volatile, highly flammable liquid with a powerful, characteristic odor and a hot, sweetish taste. It is a widely used solvent. It was formerly used as a general anesthetic.

General Properties and Specifications of Ethyl Ether or Diethyl Ether or Ether:
Appearance: Colorless, volatile, highly flammable liquid.
Odor: Characteristic Sweet, Pungent Odor.
Assay: 98%. May contain BHT as a stabilizer.
Residue on evaporation: 0.001% maximum.
Melting point: -116.3C.
Boiling point: 34.6C
Flash point: −45C.
Relative density: 0.71
Auto-ignition temperature: 160C.

Ether USP Grade Specifications:
C4H10O -- 74.12
Ethane, 1,1′-oxybis-;
Ethyl ether CAS 60-29-7
UNII: 0F5N573A2Y

DEFINITION
Ether contains NLT 96.0% and NMT 98.0% of ether (C4H10O), the remainder consisting of alcohol and water.
[Caution: Ether is highly volatile and flammable. Its vapor, when mixed with air and ignited, may explode.]

Limit of Nonvolatile Residue:
Sample: 50 mL
Analysis: Allow the Sample to evaporate spontaneously from a tared dish, and dry at 105C for 1 h.
Acceptance criteria: 0.003%; the weight of the residue is NMT 1 mg.
Limit of Low-Boiling Hydrocarbons: To pass chromatographic test.
Limit of Aldehyde:
Solution A: A mixture of 1 mL of alkaline mercuric–potassium iodide and 17 mL of a saturated solution of sodium chloride
Sample: 20 mL
Analysis: Place the Sample in a glass-stoppered cylinder, and add 7 mL of Solution A. Insert the stopper in the cylinder, shake vigorously for 10 s, and then set aside for 1 minute.
Acceptance criteria: The water layer shows no turbidity.
Limit of Peroxide: To pass the test.
Specific Gravity: 0.713–0.716, indicating 96.0%–98.0% of C4H10O
Acidity:
Analysis: Exercise great care to avoid contamination from carbon dioxide when adding the Ether and titrating. To 10 mL of water in a glass-stoppered flask, add 0.10 mL of bromothymol blue and 0.010 N sodium hydroxide until a blue color persists after vigorous shaking. Add 25 mL of Ether and shake briskly to mix the two layers. If no blue color remains, titrate with 0.010 N sodium hydroxide until the blue color is restored and persists for several min.
Acceptance criteria: 0.003% as CH3COOH; NMT 0.80 mL of 0.010 N sodium hydroxide is required.
Water Determination: NMT 0.5%; except when labeled as intended for anesthetic use, it contains NMT 0.2%.

DEFINITION
Diethyl ether.
It may contain a suitable non-volatile antioxidant at a suitable concentration.

CHARACTERS
Appearance: Clear, colourless, volatile liquid.
Solubility: Soluble in water, miscible with ethanol (96 per cent), with methylene chloride and with fatty oils. It is highly flammable.

TESTS
Acidity: To 20 mL of ethanol (96 per cent) add 0.25 mL of bromothymol blue solution and, dropwise 0.02 M sodium hydroxide ;until a blue colour persists for 30 s. Add 25 mL of the substance to be examined, shake and add, dropwise, 0.02 M sodium hydroxide until the blue colour reappears and persists for 30 s. Not more than 0.4 mL of 0.02 M sodium hydroxide is required.
Relative density: 0.714 to 0.716.
Distillation range: Do not distil if the substance to be examined does not comply with the test for peroxides. It distils completely between 34.0C and 35.0C. Carry out the test using a suitable heating device and taking care to avoid directly heating the flask above the level of the liquid.
Aldehydes: To 10.0 mL in a ground-glass-stoppered cylinder add 1 mL of alkaline potassium tetraiodomercurate solution and shake for 10 s. Allow to stand for 5 min, protected from light. The lower layer may show a yellow or reddish-brown opalescence but not a grey or black opalescence.
Peroxides: Place 8 mL of potassium iodide and starch solution in a 12 mL ground-glass-stoppered cylinder about 15 mm in diameter. Fill completely with the substance to be examined, mix and allow to stand protected from light for 5 min. No colour develops.
Non-volatile matter: Maximum 20 mg/L.
After ensuring that the substance to be examined complies with the test for peroxides, evaporate 50 mL to dryness on a water-bath and dry the residue in an oven at 100-105C. The residue weighs a maximum of 1 mg.
Substances with a foreign odour: Moisten a disc of filter paper 80 mm in diameter with 5 mL of the substance to be examined and allow to evaporate. No foreign odour is perceptible immediately after evaporation.
Water: Maximum 2 g/L, determined on 20 mL.

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Ethyl Ether or Diethyl Ether or Ether SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 18-July-23

Product Name & Other Names: Ethyl Ether or Diethyl Ether or Ether.
CAS No.: 60-29-7
EINECS EC No.: 200-467-2
Molecular Formula: C4H10O or (CH3CH2)2O
Molecular Weight: 74.12
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 1), H224
Acute toxicity, Category 4, Oral, H302
Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336

Hazard statements:
H224: Extremely flammable liquid and vapor.
H302 Harmful if swallowed.
H336 May cause drowsiness or dizziness.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray or fog for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
F = Extremely Flammable.
Xn = Harmful.
R-phrases:
R12 Extremely flammable.
R22 Harmful if swallowed
R67 Vapors may cause drowsiness and dizziness.
3. Composition/Information on Ingredients
Product Name & Other Names: Ethyl Ether or Diethyl Ether or Ether.
CAS No.: 60-29-7
EINECS EC No.: 200-467-2

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Extremely Flammable. Forms explosive mixtures with air.
Flash Points: -45C.
Products of Combustion: Carbon dioxide, Carbon monoxide and fumes.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use water spray or fog. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Avoid a solid water jet on the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water spray to prevent pressure build-up, auto-ignition, or explosion.
Unsuitable extinguishing media: For this substance/mixture no limitations of extinguishing agents are given. However solid water jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and a suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. Use water spray to cool unopened containers. Pay attention to flashback.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep up or swab the material without causing dust/mist. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Do not ingest. Do not breathe dust, vapors, or mist . Work under hood. Ensure proper ventilation. Provide appropriate exhaust ventilation at places where dust/mist is formed. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents and acids. Keep away from open flames, hot surfaces, and sources of ignition. Take precautionary measures against static discharge.

Airborne Exposure Limits:
USA ACGIH TLV: TWA 4000 ppm. STEL 500 ppm Skin.
OSHA PEL(TWA): Vacated TWA 400 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear colorless liquid.
Odor: Characteristic Sweet, Pungent Odor.
Odor threshold: Not available.
pH: Not available.
Relative density: around 0.71
Boiling Point: 34.6C
Melting Point: -116.3C.
Flash Point: -45C.
Auto-ignition Temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water.
Viscosity: Not available.
Molecular Formula: C4H10O or (CH3CH2)2O
Molecular Weight: 74.12

Stability: Stable under ordinary conditions of use and storage. May form explosive peroxides. Forms explosive mixtures with air. Air sensitive: Light sensitive: Hygroscopic
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide and fumes.
Hazardous Polymerization: Hazardous polymerization does not occur.
Incompatibilities: Strong oxidizing agents. Strong acids.
Conditions to Avoid: Light. Exposure to moisture Exposure to air. Heat, flames, static discharge, and sparks. Extremes of temperature and direct sunlight.

Toxicity data
Oral-Rat LD50: 1211 mg kg.
Dermal-Rabbit LD50: >20000 mg/kg.
Inhalation - Rat LC50: - 4 hr. 97.5 mg/l
Carcinogenicity: Not listed as causing cancer.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Mutagenicity: No information found.
Neurotoxicity: No information found.

Toxicity to fish: LC50 - Leuciscus idus (Golden orfe) - 2840 mg/l - 48 h (Diethyl ether).
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 1380 mg/l - 48 h (Diethyl ether).
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Will likely be mobile in the environment due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. State and local disposal regulations may differ from federal disposal regulations. Dispose of containers and unused contents in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN 1155, Hazard Class: 3, Packing Group: I
Shipping Name: Diethyl ether.
IMDG/IMO:
UN Number: UN 1155, Hazard Class: 3, Packing Group: I
Shipping Name: Diethyl ether.
IATA/ICAO:
UN Number: UN 1155, Hazard Class: 3, Packing Group: I
Shipping Name: Diethyl ether.

European Labeling in Accordance with EC Directives:
H224: Extremely flammable liquid and vapor.
H302 Harmful if swallowed.
H336 May cause drowsiness or dizziness.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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