Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Epichlorohydrin or 2-(Chloromethyl)oxirane, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane: CAS Number: 106-89-8 or 67843-74-7, EINECS EC Number: 203-439-8, Molecular Formula: C3H5ClO, Molecular Weight: 92.52, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane.

Epichlorohydrin or (S)-(+)-2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane is a colorless liquid with a pungent, garlic-like odor, moderately soluble in water, but miscible with most polar organic solvents. Epichlorohydrin is used as a precursor in the synthesis of many organic compounds. Epichlorohydrin is largely used in the production of epoxy resins. It is also used in the manufacture of elastomers, glycidyl ethers, cross-linked food starch, surfactants, plasticizers, dyestuffs, pharmaceutical products, oil emulsifiers, lubricants, and adhesives; as a solvent for resins, gums, cellulose, esters, paints, and lacquers; as a stabilizer in chlorine-containing substances such as rubber, pesticide formulations, and solvents; and in the paper and drug industries as an insect fumigant.

General Properties and Specifications of Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane:
Appearance: Colorless liquid.
Odor: Pungent, garlic-like odor.
Assay: 99% minimum.
Relative density: around 1.18
Melting point: -57C literature.
Boiling point: 116C to 118C literature.
Flash point: 32C literature.
Solubility: Moderately soluble in water, but miscible with most polar organic solvents.

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Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane SDS GHS, Safety Data Sheet
MSDS GHS, Material Safety Data Sheet 18-Oct-20

Product Name & Other Names: Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane.
CAS No.: 106-89-8 or 67843-74-7
EINECS EC No.: 203-439-8
Molecular Formula: C3H5ClO
Molecular Weight: 92.52
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 3) H301
Acute toxicity, Dermal (Category 3) H311
Acute toxicity, Inhalation (Category 3) H331
Skin corrosion (Sub-category 1B) H314
Skin sensitization (Category 1) H317
Carcinogenicity (Category 1B) H350

Hazard statements:
H226: Flammable liquid and vapor.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H350 May cause cancer.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray or fog for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T = Toxic
C = Corrosive.
R-phrases:
R 10 Flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R34 Causes burns
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact
R45 May cause cancer.

Product Name & Other Names: Epichlorohydrin or 2-(Chloromethyl)oxirane or 1-Chloro-2,3-epoxypropane.
CAS No.: 106-89-8 or 67843-74-7
EINECS EC No.: 203-439-8

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable.
Flash Points: 32C.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes & Hydrochloric Acid.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use water spray or fog. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container.
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong reducing agents, strong acids, strong bases, aluminum chloride, amines, anilines, metallic chlorides, chlorites, tin, zinc. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage.

Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless liquid.
Odor: Pungent, garlic-like odor.
Odor threshold: Not available.
pH: Not available.
Relative Density: around 1.18
Boiling Point: 116C-118C
Melting Point: -57C literature.
Flash point: 32C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): 4.87mmHg @ 25C.
Vapor Density (Air=1): 4.3.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Moderately soluble in water, but miscible with most polar organic solvents.
Viscosity: Not available.
Molecular Formula: C3H5ClO
Molecular Weight: 92.52

Stability: Stable under ordinary conditions of use and storage. Slow hydrolysis to ethanol and chloroacetic acid will cause slow corrosion of common metals.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide Ethyl alcohol, Hydrochloric acid & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong reducing agents, strong acids, strong bases, aluminum chloride, amines, anilines, metallic chlorides, chlorites, tin, zinc.
Conditions to Avoid: Incompatibles, heat & light, sparks, flame.

Toxicity data
ORL-RAT LD50 - 175 - 282 mg/kg
Dermal Rabbit LD50 - 515 mg/kg
Carcinogenicity: May cause cancer.
ACGIH (American Conference of Governmental Industrial Hygienists): A3 - Animal Carcinogen.
IARC (International Agency for Research on Cancer): Group 2A - Probably Carcinogenic to Humans.
NTP (National Toxicology Program): Reasonably Anticipated to be a Human Carcinogen.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found.

Environmental Toxicity:
Toxicity to fish: static test LC50 Pimephales promelas (fathead minnow): 10.6 - 13.2 mg/l; 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 Daphnia magna (Water flea): 24 mg/l; 48 h.
Persistence and Degradability: degradable product.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: Bioaccumulation is not expected.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

USA DOT Classification:
UN Number: UN 2023
Shipping Name: EPICHLOROHYDRIN
Hazard Class: 6.1(3); Packing Group: II
Canada TDG Classification:
UN Number: UN 2023
Shipping Name: EPICHLOROHYDRIN
Hazard Class: 6.1(3); Packing Group: II
IATA & ADR/RID Europe
UN Number: UN 2023
Shipping Name: EPICHLOROHYDRIN
Hazard Class: 6.1(3); Packing Group: II

USA:
SARA 302 Components: Not are subject to the reporting of SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard: Immediate Health Hazard: Acute. See section 2.

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H350: May cause cancer.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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