Dimethyl Malonate Manufacturers, with SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Dimethyl Malonate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy,, Bangladesh, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Dimethyl Malonate: CAS Number: 108-59-8, EINECS EC Number: 203-597-8, Molecular Formula: C5H8O4 or CH2(COOCH3)2, Molecular Weight: 132.11, HS Code ---**
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SDS MSDS Sheet of Dimethyl Malonate Manufacturers
Dimethyl Malonate
Pure Suppliers
Dimethyl malonate is a diester derivative of malonic acid. It is a common reagent for organic synthesis used, for example, as a precursor for barbituric acid. It is also used in the malonic ester synthesis. Dimethyl malonate is used extensively in the fragrance industry as a raw material in the synthesis of jasmonates.
Properties and Specifications of Dimethyl Malonate:
Appearance: Clear colorless liquid.
Relative density: 1.154
Melting point: -62C.
Boiling point; 180C to 181C.
Flash point: 85C minimum reported.
Solubility: Slightly soluble in water.
Purity: 99.5% minimum.
We manufacture and supply as under:
1,3-Dimethyl-2-Imidazolidinone.
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30
e-mail: info@mubychem.com
USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)
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Last
23 April, 2024
Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.
Global or International Suppliers, Exporters, Importers, Manufacturers
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Dimethyl Malonate SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 16-Oct-20
1. Product Identification
Product Name & Other Names: Dimethyl Malonate.
CAS No.: 108-59-8
EINECS: EC Number: 203-597-8
Molecular Formula: C5H8O4 or CH2(COOCH3)2
Molecular Weight: 132.11
Relevant uses and uses advised against (if any): Industrial Manufacturing Use.
Supplier: As per letterhead above.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Flammable liquids Category 4 - H227
Skin corrosion/irritation Category 2 - H315
Serious eye damage/eye irritation Category 2A - H319
Specific target organ toxicity - single exposure respiratory irritation Category 3 - H335
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements  Irritant |
Signal Words (GHS-US): Warning
Hazard statements (GHS-USA):
H227: Combustible liquid.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
Precautionary statements (GHS-USA):
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P233: Keep container tightly closed.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P337+ P313 If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide for extinction.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P403+235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents/container to comply with local, state and federal regulations.
For the full text of the mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrases:
R36/37/38
3. Composition/Information on Ingredients
Product Name & Other Names: Dimethyl Malonate.
CAS No.: 108-59-8
EINECS: EC Number: 203-597-8
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Combustible liquid. Containers may explode when heated.
Auto-Ignition Temperature: 440C.
Flash Points: 90C.
Flammable Limits: Not available.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Flammable in the presence of open flame.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Avoid solid streams of water.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Cool closed containers exposed to fire with water spray.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up, and remove to an approved disposal container.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Do not ingest. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, bases, oxidizing agents, reducing agents. May form explosive peroxides. Store at room temperature. Keep away from heat and flame.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Not Established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Clear colorless liquid.
Odor: Typical ester-like odor.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.15 to 1.16
Boiling Point: 180C to 181C.
Melting Point: -62C.
Flash point: 85C minimum reported.
Auto-ignition temperature: 440C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water.
Viscosity: Not available.
Molecular Formula: C5H8O4 or CH2(COOCH3)2
Molecular Weight: 132.11
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Oxides carbon & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents, strong acids & bases, moisture, heat and light.
Conditions to Avoid: Incompatibles, exposure to air, heat & light.
11. Toxicological Information
Toxicity data
LD50 Oral - Rat - male and female - > 2000 mg/kg.
LD50 Dermal - Rabbit - > 5000 mg/kg.
Carcinogenic Effects: Not know as carcinogen as per IARC, NTP, ACGIH & OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
Toxicity to fish: LC50: = 16.71 mg/L, 96h (Pimephales promelas).
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - > 1.000 mg/l - 48 h.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
DOT USA & ADR/RID Classification: Not regulated.
Canada TDG Classification: Not regulated.
IATA & IMDG: Not regulated.
15. Regulatory Information
USA:
SARA 302: Not applicable.
SARA 311/312: Acute Health Hazard
SARA 313 Components: No chemicals are reportable under Section 313.
California Prop. 65 Components: None.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H227: Combustible liquid.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
Hazard Symbol:
Xi Irritant
Risk Phrases:
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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