Acetonitrile or Ethanenitrile or Methyl cyanide Pure and Reagent Grade Manufacturers, SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Acetonitrile or Methyl cyanide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Acetonitrile or Ethanenitrile or Methyl cyanide: CAS Number: 75-05-8, EINECS EC Number: 200-835-2, Molecular Formula: C2H3N or CH3CN, Molecular Weight: 41.05, HS Code ---**

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Acetonitrile or Ethanenitrile or Methyl cyanide is the chemical compound with the formula CH3CN. This colourless liquid is the simplest organic nitrile. It is used as a polar aprotic solvent in organic synthesis and in the purification of butadiene. In the laboratory, it is used as a medium-polarity solvent that is miscible with water and a range of organic solvents, but not saturated hydrocarbons. It is widely used in battery applications because of its relatively high dielectric constant and ability to dissolve electrolytes. Industrially, it is used as a solvent for the manufacture of pharmaceuticals and photographic film.

Properties and General Specifications of Acetonitrile or Ethanenitrile or Methyl cyanide:
Appearance: Colorless liquid.
Odor: Faint, distinct, fruity.
Relative Density: 0.786
Melting point: -46C to -44C.
Boiling point: 81.3C to 82.1C.
Flash point: 5.6C
Auto-ignition temperature: 524C
Solubility: Miscible with water.
Assay: 99.8% minimum.
Residue on Evaporation: 0.0005% maximum.
Water (by KF): 0.001% maximum.

Acetonitrile Reagent Grade Specifications:
CH3CN --- Formula Wt 41.05
CAS Number 75-05-8

Suitable for use in high-performance liquid chromatography, extraction-concentration analysis, ultraviolet spectrophotometry, or general use. Product labeling shall designate the one or more of these uses for which suitability is represented on the basis of meeting the relevant requirements and tests. The ultraviolet spectrophotometry and liquid chromatography suitability requirements include all of the requirements for general use. The extraction-concentration suitability requirements include only the general use requirement for color.

MAXIMUM ALLOWABLE
Color (APHA): 10
Residue after evaporation: 0.005%
Titrable acid: 8 eq/g
Titrable base: 0.6 eq/g
Water: 0.3%

Specific Use Ultraviolet Spectrophotometry:
Wavelength (nm) 254 and Absorbance (AU) 0.01
Wavelength (nm) 220 and Absorbance (AU) 0.05
Wavelength (nm) 190 and Absorbance (AU) 1.00

Liquid Chromatography Suitability:
Absorbance: Passes test
Gradient elution: Passes test

Extraction-Concentration Suitability:
Absorbance: Passes test
GC-FID: Passes test
GC-ECD: Passes test.

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Acetonitrile or Ethanenitrile or Methyl cyanide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 28-Sep-20

Product Name & Other Names: Acetonitrile or Ethanenitrile or Methyl cyanide.
CAS No.: 75-05-8.
EINECS EC Number: 200-835-2
Molecular Formula: C2H3N or CH3CN
Molecular Weight: 41.05
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 2 - H225
Acute toxicity, oral Category 4 - H302
Acute toxicity, dermal Category 4 - H312
Acute toxicity, inhalation Category 4 - H332
Serious eye damage/eye irritation Category 2A - H319

Hazard Statements:
H225: Highly flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H319: Causes serious eye irritation.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P370+378: In case of fire: Use Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
Xn Harmful
Xi Irritant
Risk Phrases:
R11 Highly flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R36 Irritating to eyes.

Product Name & Other Names: Acetonitrile or Ethanenitrile or Methyl cyanide.
CAS No.: 75-05-8.
EINECS EC Number: 200-835-2

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable. Containers may explode when heated.
Products of Combustion: Carbon oxides and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations .Vapors can accumulate in low areas.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move containers to a safe and open area if the leak is irreparable. Vapors can accumulate in low areas. Dike the spilled material, where this is possible.

Precautions for safe handling: Do not handle or store near an open flame, heat, or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Avoid prolonged exposure. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from heat, sources of ignition (spark or flame) and sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, bases, oxidizing agents, reducing agents, alkali metals.

Airborne Exposure Limits:
USA ACGIH TWA= 20 ppm.
OSHA PEL (TWA) (ppm)=40 ppm
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear and colorless liquid.
Odor: Faint, distinct, fruity.
Odor threshold: Not available.
pH: Not available.
Relative density: 0.786
Flash Point: 5.6C.
Boiling point: 81.3C to 82.1C.
Melting point/Freezing point: -46C to -44C.
Auto-ignition temperature: 524C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water.
Viscosity: Not available.
Molecular Formula: C2H3N or CH3CN
Molecular Weight: 41.05

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, bases, oxidizing agents, reducing agents, alkali metals.
Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Toxicity data:
LD50 Oral - Mouse - 617 mg/kg.
LC50 Inhalation - Mouse - male and female - 4 h - 6,022 mg/l.
LD50 Dermal - Rabbit - male and female - > 2.000 mg/kg.
Carcinogenicity: Not expected to be hazardous by OSHA criteria.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
Sensitization: May cause sensitization by skin contact.
Local effects: Harmful if swallowed. Harmful if inhaled or absorbed through the skin. Causes serious eye irritation.

Toxicity to fish: flow-through test LC50 - Pimephales promelas (fathead minnow) -
1.640 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test LC50 - Artemia salina (Brine shrimp) - 400 mg/l - 24 h.
Persistence and Degradability: This material is biodegradable.
Mobility: Expected to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

Department of Transportation (DOT-USA) & ADR/RID:
Proper shipping name: Acetonitrile.
Class: 3; Packing group: III.
UN number: 1648
Air transport (IATA) & IMDG:
Proper shipping name: Acetonitrile.
Class: 3; Packing group: III.
UN number: 1648

USA:
SARA 302 Components: Not subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: Does not contain any chemical components with CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H225: Highly flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H319: Causes serious eye irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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