DETA Phosphonate or DTPMP Phosphonate or diethylenetriamine penta(methylene phosphonic acid) Manufacturers, with SDS MSDS Sheet

Supplier, Manufacturer, Exporter of DETA Phosphonate or DTPMP Phosphonate or diethylenetriamine penta(methylene phosphonic acid), Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Peru, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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DETA or DTPMP or Diethylenetriamine penta(methylene phosphonic acid) CAS Number 15827-60-8, EINECS EC Number 239-931-4 or 206-896-8, HS Code ---**; Molecular Weight 573.20, Molecular Formula: C9H28N3O15P5

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Diethylenetriamine penta(methylene phosphonic acid).

In the USA, UAE, Iran Iraq, Kuwait, Saudi Arabia and other oil producing areas, several hundred chemical compounds are used in hydraulic fracturing also called fracking, fracing or frac. In some areas like UK only 'Non-Hazardous' chemicals are permitted for fracturing fluids by the Environment Agency. All chemicals have to be declared publicly and increasingly, food additive based chemicals are available to allow fracking to take place safely.

Mubychem is an internationally preferred source for Stimulation Chemicals and Hydraulic Fracturing Chemicals. We serve various oil and shale gas producing countries like USA UAE, Kuwait, Iran, Iraq, Saudi Arabia, UK, Europe India etc. We are never too far from your well-site with multiple 24/7 company owned or rented warehouses in the India, USA and across the globe. With customers in several countries, we sell almost all the fracturing chemicals.

Specifications of DETA Phosphonate or DTPMP Phosphonate or diethylenetriamine penta(methylene phosphonic acid):
Appearance: Brown Liquid
Active component %: 48.0-52.0
Chloride (Cl-) %: 12.0-17.0
Fe(as Fe3+) ppm: 35 max
Density(20C)g/cm3: 1.35-1.45
pH value (1% water solution): 2.0

DETA or DTPMP Phosphonate is having chemical formula C9H28N3O15P5 and M.W. 573.20 & CAS Registry Number 15827-60-8 is has chelating and anti corrosion properties.
DTPMP is an organophosphonic acid compound exihibiting excellent sequestration of metal ions at stoichiometric concentration and thresold inhibition of metal salt precipitation at sub stoichiometric concentrations. It is a nitrogenous organic polyphosphonic acid. It shows very good inhibition of the precipitation of barium sulfate (BaSO4). At high alkali and high temperature (above 210C) environments DTPMPA has better scale and corrosion inhibition effect than other phosphonates.

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DETA Phosphonate or DTPMP Phosphonate or diethylenetriamine penta(methylene phosphonic acid) SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 17-Oct-20

Product Name & Other Names: DETA Phosphonate, diethylenetriamine penta(methylene phosphonic acid)
CAS No.: 15827-60-8
Molecular Weight: 573.20
Chemical Formula: C9H28N3O15P5
Relevant uses and uses advised against (if any): Scale Inhibitor
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive to Metals, Category 1, H290
Skin corrosion/irritation Category 1A, B, C, H314
Hazardous to the aquatic environment, long-term hazard Category 4, H413

Hazard Statements:
H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
H413: May cause long lasting harmful effects to aquatic life.

Precautionary Statements
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P310: Immediately call a POISON CENTER or doctor/physician
P390: Absorb spillage to prevent material damage.
P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor.
P405: Store locked up.
P406: Store in corrosive resistant/ container with a resistant inner liner.
P405: Store locked up.
P501: Dispose of contents/container in accordance with all federal, state and local regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
C Corrosive
Risk Phrases:
R34 = Causes burns.
R41 = Risk of serious damage to eyes.

Ingredient: Diethylenetriaminepenta (methylenephosphonic acid)
CAS No.: 15827-60-8
Percent: 45-55%
Ingredient: Hydrochloric acid (Hydrogen chloride)
CAS No.: 7647-01-0
Percent: 5-15%

After inhalation: Move victim to fresh air. In case of respiratory difficulties seek medical attention.
In case of skin contact: After contact with skin, wash immediately with plenty of water. Change contaminated clothing. In case of skin reactions, consult a physician.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Remove contact lenses. Subsequently seek the immediate attention of an ophthalmologist.
After swallowing: Rinse mouth and drink large quantities of water. Consult physician.

Fire and explosion hazard: Slight fire hazard. Dust/air mixtures may ignite or explode.
Extinguishing media: Regular dry chemical, carbon dioxide, water, and regular foam.
Firefighting: Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Do not get water directly on material.
Large fires: Flood with fine water spray. Reduce vapors with water spray. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Keep unnecessary people away, isolate hazard area and deny entry.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, strong oxidizing agents, metal salts of sulfites/sulfides, alkalis. Emptied containers retain vapor and product residue.
Suitable materials of construction: Glass lining, PVC, polypropylene, glass reinforced plastic, and polyethylene.
Unsuitable materials of construction: Mild steel, carbon steel, aluminum, and other metals.

OSHA TWA ACGIH TWA: 15827-60-8 Diethylenetriaminepenta (methylenephosphonic acid) PEL: Not Established TLV: Not established
OSHA TWA ACGIH TWA: 7647-01-0 Hydrochloric acid {Hydrogen chloride} CEIL: 5 ppm CEIL: 2 ppm)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Brown colored liquid
Odor: Characteristic
Odor threshold: Not available.
pH: <1
Relative density: 1.35 – 1.42
Melting point/freezing point: Not available.
Boiling Point: >212 F
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water and other polar solvents
Viscosity: Not available.

Stability: Is stable under ordinary conditions of use and storage. Stability decreases in the presence of moisture
Hazardous Decomposition Products: Phosphines, Carbon Monoxide, Carbon Dioxide, Nitrogen Oxides
Hazardous Polymerization: Will not occur
Incompatibilities: Reducing agents, strong oxidizing agents, metal salts of sulfites/sulfides, alkalis
Conditions to Avoid: Strong heat generation when combines with Alkalis

11. Toxicological Information
CAS 15827-60-8:
NTP: NA
IARC: NA
ACGIH: NA
OSHA: NA
CAS# 7647-01-0:
NTP: NA
IARC: 3
ACGIH: A4
OSHA: NA
Acute toxicity:
LC50, Inhalation, Mouse, 1108. PPM, 1 H.
TCLo, Inhalation, Rat, 685.0 UG/M3, 24 D.
Acute toxicity, LCLO, Inhalation, Human, 1300. PPM, 30 M.
Acute toxicity, LDLO, Route of Application: Unreported., Human, 81.00 MG/KG.
Eyes, Species: Rabbit, 5.000 MG, 30 S.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: No information available.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

Domestic Land DOT USA & ADR/RID Europe
Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Phosphonic acid, Hydrochloric acid)
Hazard Class: 8, Packing Group: II
UN/NA: UN3265
International (Water, I.M.O.)
Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Phosphonic acid, Hydrochloric acid)
Hazard Class: 8, Packing Group: II
UN/NA: UN3265

European/International Regulations European Labeling in Accordance with EC Directives:
H290 = May be corrosive to metals.
H314 = Causes severe skin burns and eye damage.
H318 = Causes serious eye damage.
H413 = May cause long lasting harmful effects to aquatic life.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Shale Gas Hydraulic Fracturing Chemicals
Acetic Acid Solution	Ammonium Persulfate or Persulphate
Acid Viscosifier	Acid Emulsifier
ATMP Phosphonate, Amino tris (methylene phosphonic acid)	Ammonium Bifluoride
Barium Sulfate Remover	BHMT or BHMTPMPA Biocide Solution
Boron & Zirconium based Guar Cross Linker	BME Iron Reducer or Dissolver
Calcium Chloride Anhydrous & Solution	Cement Defoamer
Citric Acid Solution	Clay Stabilizer
Corrosion Inhibitors	DETA Phosphonate or DTPMP Phosphonate
Didecyl Dimethyl Ammonium Chloride Solution	Diverting Agent
Encapsulated Citric Acid	Encapsulated Gel Breaker
Fe46 Liquid Iron Control Blend	Friction Reducer
Flow Back Aid, Water Recovery Surfactant	Foam or Finofoam 810
Foam 418 Heavy Crude Foamer	Gel Sweep
Glycerin Solution	Glutaraldehyde Solution
HP HT Lube	Hydroxy ethylidene diphosphonic acid, HEDP phosphonate
Hydrogen Sulfide Scavenger	Potassium Chloride
KI (Stabilised) & Initiator	KCl Substitute or Potassium Chloride Substitute
Non Emulsifier	Paraffin Dispersant
Potassium Hydroxy Ethylidene,1-Diphosphonic Acid, HEDP-Kx	Phthalic Acid, EDTA, BPA based Diverting Agents
Scale Inhibitor Chemicals	Sodium Chlorite Solution
Sodium Glutaraldehyde Bisulfite Bisulphite	Extended Release Solids - Scale Paraffin Asphaltene Inhibitor
Sodium Bromate	Tetrakis Hydroxymethyl Phosphonium Sulfate THPS
Xanthan Gum Slurry	Zinc Chloride