CAS Number, 1341-49-7, Ammonium Bifluoride Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ammonium Bifluoride, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Peru, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Ammonium Bifluoride.

In the USA, UAE, Iran Iraq, Kuwait, Saudi Arabia and other oil producing areas, several hundred chemical compounds are used in hydraulic fracturing also called fracking, fracing or frac. In some areas like UK only 'Non-Hazardous' chemicals are permitted for fracturing fluids by the Environment Agency. All chemicals have to be declared publicly and increasingly, food additive based chemicals are available to allow fracking to take place safely.

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Ammonium Bifluoride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 30-Sep-20

Product Name & Other Names: Ammonium Bifluoride; Ammonium hydrogen difluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Molecular Weight: 57.04
Chemical Formula: NH4HF2
Recommended uses and uses advised against (if any): Fracturing and Industrial use only.
SUPPLIER: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral: Category 3, H301
Skin corrosion/irritation Category 1A, B, C, H314
Serious eye damage/eye irritation Category 1, H318
Specific target organ toxicity, repeated exposure Category 2, H373

Hazard Statements:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements:
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P273: Avoid release to the environment.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P:273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. P337+P313: If eye irritation persists get medical advice/attention.
Remove contact lenses if present and easy to do – continue rinsing.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403+P404: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T = Toxic
Xn = Harmful
Risk Phrases:
R 20 Harmful by inhalation.
R 25 = Toxic if swallowed.
R41 Risk of serious damage to eyes.
R48 Danger of serious damage to health by prolonged exposure.

Product Name & Other Names: Ammonium Bifluoride; Ammonium hydrogen difluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Ammonia, Nitrogen oxides, Hydrofluoric acid and fumes.
Fire: Ammonium Bifluoride is not considered to be a fire hazard.
Explosion: Ammonium Bifluoride is not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Toxic! Do not ingest. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, and bases.

Airborne Exposure Limits:
2.5 mg/m3 USA (OSHA) - Table Z-1 Limits for Air Contaminants
(Vacated) TWA: 2.5 mg/m3 OSHA PEL
TWA 2.5 mg/m3 ACGIH TLV
TWA: 2.5 mg/m3 NIOSH IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Ammonium Bifluoride is white crystals, powder or granules.
Odor: Pungent.
Odor threshold: Not available.
pH: 3.5.
Relative density: 1.5
Boiling Point: 240C
Melting Point: 125C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is freely soluble in water.
Viscosity: Not available.
Molecular Weight: 57.04
Chemical Formula: NH4HF2

Stability: Ammonium Bifluoride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic hydrogen fluoride fumes when heated to decomposition. It may form Ammonia, Nitrogen oxides and Hydrogen fluoride and Fluorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong acids, and bases.
Conditions to Avoid: Incompatibles and direct sunlight and moisture.

Acute toxicity
Toxic, and may be fatal, if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Cough, Shortness of breath, Headache, Nausea
Toxicity data
ORL-RAT LD50 130 mg kg-1
LD50 Intraperitoneal – rat – 31 mg/kg
LC50 – mouse – 342 mg/kg – 1 hour
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Toxicity to fish: Not available.
Toxicity to daphnia and other aquatic invertebrates: Not available.
Environmental Toxicity: Not available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

USA DOT, IMDG & Canada TDG, ADR/RID Europe Classification:
UN-Number: 1727
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID
CLASS 8: Packing group: II
IATA/ICAO
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID.

USA:
SARA 302 Components: Not listed.
SARA 313 Components: Not listed.
SARA 311/312 Hazardous Categorization: Acute Health Hazard.

European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T = Toxic
Xn = Harmful
Risk Phrases:
R 25 = Toxic if swallowed.
R 20 Harmful by inhalation.
R41 Risk of serious damage to eyes.
R48 Danger of serious damage to health by prolonged exposure.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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PARAMETERS	TYPICAL ANALYSIS
NH4HF2%	96.0 minimum
NH4F%	4.0 maximum
F%	65.0 minimum
Fe ppm	10 maximum
SO4 ppm	100 maximum
SiO2 ppm	100 maximum
Cl ppm	30 maximum
As ppm	10 maximum
Pb ppm	5.0 maximum
Ni ppm	10 maximum
Cu ppm	30 maximum
Sb ppm	10 maximum
H2O ppm	1000 maximum

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