Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Sodium Picramate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide: CAS Number: 831-52-7, EINECS EC Number: 212-603-8, Molecular Formula: C6H4N3O5Na, Molecular Weight: 221.1, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.

Sodium picramate appears as a red-brown solid. Sodium Picramate is used as a synthetic red dye. It is often added to henna powder, to obtain more intense and resistant hair colors than those obtainable with henna alone, and to accelerate or cancel the oxidation times necessary for the release of the pigment.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide
SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 20-Apr-21

Product Name & Other Names: Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.
CAS Number: 831-52-7
EINECS EC Number: 212-603-8
Molecular Formula: C6H4N3O5Na
Molecular Weight: 221.1
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per the letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable solids (Category 1), H228
Acute toxicity, oral (Category 4), H302
Acute toxicity, dermal (Category), 4H312
Sensitization, Skin (Category 1), H317
Specific target organ toxicity, repeated exposure (Category 2), H373
Acute toxicity, inhalation (Category 4), H332
Hazardous to the aquatic environment, acute hazard (Category 2), H401

Hazard statements:
H228: Flammable solid.
H302 + H302 + H332: Harmful if swallowed, in contact with skin and if inhaled.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide for extinction.
P391: Collect spillage.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to European Directive 67/548/EEC as amended:
Hazard symbols:
Xn Harmful
Xi Irritant.
Risk-phrases:
R10 Flammable
R20 Harmful by inhalation
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R43 May cause sensitization by skin contact.
R48 Danger of serious damage to health by prolonged exposure.

Product Name & Other Names: Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.
CAS Number: 831-52-7
EINECS EC Number: 212-603-8

Eye Contact: Do not allow victim to rub eye (s). Let the eye (s) water naturally for a few minutes. If particle/dust does not dislodge, flush with lukewarm, gently flowing water for 5 minutes or until particle/dust is removed, while holding eyelid (s) open. If irritation persists, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye.
Skin Contact: Remove contaminated clothing, shoes, and leather goods (e.g., watchbands, belts). Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm gently flowing water and non-abrasive soap for 5 minutes. If irritation persists, repeat flushing. Obtain medical advice. Completely decontaminate clothing, shoes and leather goods before reuse or else discard.
Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. Obtain medical advice.
Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 2 – 8 oz. (60 – 240 ml) of water.

Fire and Explosion Hazards: Flammable Solids.
Extinguishing Media: Use means of extinction appropriate for the surrounding fire conditions such as water spray, carbon dioxide, dry chemical, or foam.
Fire Fighting: Apart from oxides of carbon. toxic fumes of nitrogen oxide may result from combustion. As with any fire, fire fighters should be fully trained and wear full protective clothing including an approved, self-contained breathing apparatus which supplies a positive air pressure within a full-face piece mask. Do not use water directly on material. Do not allow water run-off to enter sewers or watercourses. Use water spray to cool unopened containers. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Procedures for Cleanup: Stop release if possible, to do so safely. Contain spill, isolate hazard area, and deny entry. Sweep up or vacuum. Place contaminated material in suitable, labeled containers for final disposal. Dispose of waste material consistent with the requirements of waste disposal authorities.
Personal Precautions: Gloves and coveralls or other protective clothing are recommended for persons responding to an accidental release. Close-fitting safety goggles may be necessary in some circumstances to prevent eye contact.
Environmental Precautions: This product can pose a threat to the environment. Contamination of soil and water should be prevented. Keep spillage from entering soil, streams, or sewers.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. generating dust and the release of dust into the workplace. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Do not store with incompatible materials like oxidizing agents.

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Red-brown solid.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Soluble in water.
Viscosity: Not available.
Molecular Formula: C6H4N3O5Na
Molecular Weight: 221.1

Stability and Reactivity: Stable and not considered reactive under normal temperatures and pressures. Hazardous polymerization or runaway reactions will not occur.
Incompatibilities: Oxidizing agents. Avoid excessive heat.
Hazardous Decomposition Products: High temperature operations will generate carbon oxide fume. Under such conditions, nitrogen dioxide will also be generated and can cause respiratory distress.

Acute Toxicity (Oral LD50): > 378 mg/kg Mouse
LC50 Inhalation - Rat - 1 h - > 3,900 mg/m3
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Ecotoxicity: May cause long lasting harmful effects to aquatic life.
Toxicity to fish: No information available.
Persistence and Degradability: Readily biodegradable.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Do not wash the material down drain. Put uncontaminated material back into the process if possible. Place contaminated material in suitable, labeled containers for disposal. Dispose of waste material consistent with the requirements of waste disposal authorities.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I
IATA/ICAO:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I
IMDG/IMO:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I

USA Regulations:
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H228: Flammable solid.
H302 + H302 + H332: Harmful if swallowed, in contact with skin and if inhaled.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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