Guaiacol or 2-Methoxyphenol Pure & BP Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Guaiacol or 2-Methoxyphenol, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Guaiacol or 2-Methoxyphenol: CAS Number: 90-05-1, EINECS EC Number: 201-964-7, Molecular Formula: C7H8O2 or C6H4(OH)(OCH3), Molecular Weight: 124.14, FEMA Number: 2532, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Guaiacol or 2-Methoxyphenol.

Guaiacol or 2-Methoxyphenol is a naturally-occurring organic compound with the formula C6H4(OH)(OCH3). Although it is biosynthesized by a variety of organisms, this yellowish aromatic oil is usually derived from guaiacum or wood creosote. It is also found in essential oils from celery seeds, tobacco leaves, orange leaves, and lemon peels. Samples darken upon exposure to air and light. Guaiacol is present in wood smoke, resulting from the pyrolysis of lignin. The compound contributes to the flavor of many substances such as whisky and roasted coffee. Guaiacol is used in various flavorants, such as eugenol. Guaiacol is a monomethoxybenzene that consists of phenol with a methoxy substituent at the ortho position. It has a role as an expectorant, a disinfectant, a plant metabolite. Guaiacol is used as a chemical intermediate synthesis for food materials and perfumery products, cosmetics, personal care and industrial cleaning products. It is also used as starting raw material to be chemically transformed by pharmaceutical industries

Properties and Specifications of Guaiacol or 2-Methoxyphenol:
Relative density: 1.1
Melting point: 28C.
Boiling point: 204C to 206C.
Flash point: 82C literature.
Apha color: <80.0
Appearance: Clear, Colourless to Light yellow or pink liquid.
Refractive index: 1.5390 to 1.5450
5% in chloroform solubility: Clear, colorless and no turbidity.
Purity by GC: 99.70%
Water by KF: 0.1% maximum.

DEFINITION
2-Methoxyphenol.
Content: 97.0 per cent to 102.0 per cent (anhydrous substance).

CHARACTERS
Appearance: Crystalline mass or colourless or yellowish liquid, hygroscopic.
Solubility: Sparingly soluble in water, very soluble in methylene chloride, freely soluble in ethanol (96 per cent).
Melting Point: About 28C.

IDENTIFICATION
First identification: A
Second identification: B
A. Infrared absorption spectrophotometry.
B. Thin-layer chromatography. To pass the test: --- Results The principal spot in the chromatogram obtained with the test solution is similar in position, colour and size to the principal spot in the chromatogram obtained with the reference solution.

TESTS
Solution S: Dissolve 1.00 g in ethanol (96 per cent) and dilute to 10.0 mL with the same solvent.
Appearance of solution: Solution S is clear and not more intensely coloured than reference solution.
Acidity or alkalinity: To 5.0 mL of solution S, add 10 mL of carbon dioxide-free water and 0.1 mL of methyl red mixed solution. Not more than 0.05 mL of 0.1 M hydrochloric acid or 0.1 M sodium hydroxide is required to change the colour of the indicator.
Impurity A: To pass the test: Limit: impurity A: not more than the area of the principal peak in the chromatogram obtained with reference solution (0.05 per cent).
Related substances: by Gas chromatography: To pass the test. Limits:
impurity C: maximum 0.4 per cent;
impurity E: maximum 0.2 per cent;
impurity B: maximum 0.15 per cent;
unspecified impurities: for each impurity, maximum 0.10 per cent;
total: maximum 1.0 per cent;
disregard limit: the area of the principal peak in the chromatogram obtained with reference solution (b) (0.05 per cent).
Water: Maximum 0.5 per cent, determined on 2.000 g.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Guaiacol or 2-Methoxyphenol SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 22-Oct-20

Product Name & Other Names: Guaiacol or 2-Methoxyphenol.
CAS No.: 90-05-1
EINECS EC Number: 201-964-7
FEMA Number: 2532
Molecular Weight: 124.14
Chemical Formula: C7H8O2 or C6H4(OH)(OCH3)
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead above.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral Category 4 - H302
Skin corrosion/irritation Category 2 - H315
Serious eye damage/eye irritation Category 2A - H319

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P501 Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directive 67/548/EEC and 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
Risk Phrases:
R22 Harmful if swallowed,
R36/38 Irritating to eyes and skin.

Product Name & Other Names: Guaiacol or 2-Methoxyphenol.
CAS No.: 90-05-1
EINECS EC Number: 201-964-7

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Combustible at high temperature. Forms explosive mixtures with air on intense heating. Containers may explode when heated.
Flammable Limits: Not available.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Flammable in the presence of open flame.
Flash point: 82C literature.
Auto-ignition Temperature: 385C
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use water spray to cool fire-exposed containers.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or under fire conditions, it may produce toxic or irritating fumes. Vapors are heavier than air and may spread along floors.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust/mist/vapor formation. Avoid breathing dust/mist/vapor. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Remove all sources of ignition. Avoid touching the spilled material. Do not let the product enter drains. Absorb the material on a porous, inert material such as earth, sand or vermiculite. Carefully sweep solid/powder up the material without causing dust. Dispose of in accordance with local regulations. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Use a shovel to put the material into a convenient waste disposal container and dispose of according to local and regional authority requirements. Do not contaminate the environment.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust/mist generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Do not ingest. Avoid inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks, sunlight and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, reducing agents, heat, acids and bases. Store under inert gas. Air and light sensitive.

Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies..
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear, Colorless to Light yellow or pink liquid.
Odor: Not available.
Odor threshold: Not available.
pH: 5 to 6.
Relative density: 1.1
Boiling Point: 204C to 206C
Melting Point: 28C
Flash point: 82C.
Auto-ignition temperature: 385C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 124.14
Chemical Formula: C7H8O2 or C6H4(OH)(OCH3).

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents, heat, acids and bases.
Conditions to Avoid: Incompatibles, heat, light, flame and air.

Harmful if swallowed. Irritating to skin.
Toxicity data
Oral LDLO (human): 43 mg/kg.
Oral LD50 (rat): 520 mg/kg.
Oral LD50 (mouse): 621 mg/kg.
Dermal LD50 ( Rabbit ): 4600 mg/kg.
Carcinogenic Effects: Not know as carcinogen.
Mutagenic Effects: Investigated as a mutagen.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Environmental Toxicity:
Toxicity to daphnia and other aquatic invertebrates: EC50 Daphnia magna (Water flea): 26 mg/l; 48 h
Persistence and Degradability: Soluble in water Persistence is unlikely based on information available.
Mobility: Soluble in water and hence likely to be mobile.
Bioaccumulation/ Accumulation: No accumulation is not expected.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

Department of Transportation DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

USA:
SARA 302: Not applicable.
SARA 313: Not applicable.
SARA 311/312 Hazard Categories: See section 2 for more information. Acute Health Hazard.
California prop. 65: Contains no chemical subject to California Prop 65.

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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