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Calcium Bromide Dihydrate Crystals and Solution Manufacturers, SDS GHS MSDS Sheet
Calcium Bromide: CAS Number: 7789-41-5 (anhydrous), 22208-73-7 (dihydrate), EINECS EC Number: 232-164-6, Molecular Formula: CaBr2, Molecular Weight: 199.89 g/mol (anhydrous), 235.98 g/mol (dihydrate), HS Code ---**
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SDS MSDS Sheet of Calcium Bromide Manufacturers
Solid Crystals and Solution
Calcium bromide is the name for compounds with the chemical formula CaBr2(H2O)x. Individual compounds include the anhydrous material (x = 0), the hexahydrate (x = 6), and the dihydrate (x = 2).
Calcium bromide 52% solution is used as a completion and work-over fluid to control wellbore pressures in upstream oil & gas operations. It can be used alone or mixed with calcium chloride and/or zinc/calcium bromide to achieve a clear, solids-free fluid over a wide range of densities and crystallization temperatures. It provides inhibition, preventing hydration and migration of swelling clays, and can be use for packer fluids or to adjust the density of other brine system.
Specifications of Calcium Bromide Solution:Specification of Calcium Bromide Dihydrate:
Color: 30 APHA maximum
Assay: 52% by weight CaBr2
Crystallization Temperature: 20F (-7C)
Turbidity: 6 NTU maximum
Bulk Density: 14.2 lb/gal
Specific Gravity: 1.6 to 1.7
Appearance: White Flakes or Powder
Content: 95 % minimum
Moisture: 4.5 % maximum
pH Value: 6-9
Insoluble in water: 3% maximum
Chloride: 0.1 % maximum
Sulfide: 0.05 % maximum
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Last 19 February, 2018
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Calcium Bromide SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Product: Calcium Bromide
CAS No.: 7789-41-5 (anhydrous), 22208-73-7 (dihydrate)
EINECS EC Number: 232-164-6
Molecular Weight: 199.89 g/mol (anhydrous), 235.98 g/mol (dihydrate)
Chemical Formula: CaBr2
Recommended usage: Industrial Manufacturing.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Serious eye damage/eye irritation Category 1 (H318)
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Words: Danger
H318: Causes serious eye damage.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
R41: Risk of serious damage to eyes.
Full text of S-statement & R-phrases: see section 16
3. Composition/Information on Ingredients
Product: Calcium Bromide (Generally as 45% to 55% solution)
CAS No.: 7789-41-5 (anhydrous), 22208-73-7 (dihydrate)
EINECS EC Number: 232-164-6
4. First Aid Measures
Always seek medical advice after the first aid treatment.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately.
Ingestion: Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician immediately.
Skin Contact: In case of contact, wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician immediately.
Eye Contact: Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Call a physician immediately.
5. Fire Fighting Measures
Fire: Not considered to be a fire hazard. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and clothing.
6. Accidental Release Measures
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment.
Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. Do not flush caustic residues to the sewer. Carefully pick up solid with minimum of dusting and collect in metal container with covers with disposal.
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids). Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. Store away from acids.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a full face piece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids. glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: White crystals or powder for solid and clear solution for liquid.
Specific Gravity: Not available.
pH: 6 to 9
% Volatiles by volume @ 21C (70F): Not available.
Boiling Point: Not available..
Melting Point: Not available.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Bromine, Hydrogen Bromide and Calcium Oxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, Strong acids, Strong reducing agents.
Conditions to Avoid: Incompatibilities and heat
11. Toxicological Information
Oral Rat LD50: 4100 mg/kg ( Rat ).
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
12. Ecological Information
Toxicity: Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h(Calcium bromide)
Persistence and degradability: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Mobility in soil: Not available.
13. Disposal Considerations
Although not a listed RCRA hazardous waste, it may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
DOT USA & ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
15. Regulatory Information
SARA 313: No
SARA 311/312: Acute: Yes.
Section 16 - Additional Information
H318 = Causes serious eye damage. Xn Harmful, R41 Risk of serious damage to eyes.
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.