2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of 2,2,6,6-Tetramethyl-1-piperidinyloxy, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO: CAS Number: 2564-83-2, EINECS EC Number: 219-888-8, Molecular Formula: C9H18NO, Molecular Weight: 156.25, HS Code ---**

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SDS MSDS Sheet of 2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO Manufacturers

2,2,6,6-Tetramethyl-1-piperidinyloxy
2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO Pure Suppliers
2,2,6,6-Tetramethyl-1-piperidinyloxy

2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO is a catalyst employed in the oxidation of primary alcohols to aldehydes with NaOCl. It has been used as a stable free radical employed for radical trapping in mechanistic studies and appears to react preferentially with carbon-centered radicals.

Properties and Specifications of 2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO:
Appearance: Orange to Red Powder or Solid or Crystals.
Assay: 99% minimum.
Turbidity of solution 50mg/ml in Ethanol: Clear to slightly hazy.
pH: 8.3 (9 g/l in water @ 20C).
Melting Point: 36C - 38C (literature).
Boiling Point: 193C
Flash Point: 67C
Relative Density: 0.91
Storage: Refrigerated.

We also manufacture and supply as under:

Aniline

n, n-Dimethylaniline

2,6 Xylidine or 2,6-Dimethylaniline

Tetramethyl Ethylenediamine.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 1 October, 2023

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2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet
26-Nov-20

1. Product & Company Identification

Product Name & Other Names: 2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO.
CAS No.: 2564-83-2
EINECS EC Number: 219-888-8
Molecular Weight: 156.25
Chemical Formula: C9H18NO
Relevant uses and uses advised against (if any): Scale Inhibitor
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive to Metals, Category 1, H290
Skin corrosion/irritation Category 1A, B, C, H314

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Word: Warning

Hazard Statements:
H290 - May be corrosive to metals.
H314 - Causes severe skin burns and eye damage.

Precautionary Statements
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 - Wash hands thoroughly after handling.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405: Store locked up.
P501: Dispose of contents/container in accordance with all federal, state and local regulations

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C Corrosive
Risk Phrases:
R34 = Causes burns.
R41 = Risk of serious damage to eyes.

3. Composition/Information on Ingredients

Product Name & Other Names: 2,2,6,6-Tetramethyl-1-piperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl free radical or TEMPO.
CAS No.: 2564-83-2
EINECS EC Number: 219-888-8

4. FIRST AID MEASURES

Always seek medical attention after first aid measures are provided.

After inhalation: Move victim to fresh air. In case of respiratory difficulties seek medical attention.
In case of skin contact: After contact with skin, wash immediately with plenty of water. Change contaminated clothing. In case of skin reactions, consult a physician.
After eye contact:  Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Remove contact lenses. Subsequently seek the immediate attention of an ophthalmologist.
After swallowing: Rinse mouth and drink large quantities of water. Consult physician.

5. FIRE FIGHTING MEASURES

Fire and explosion hazard: Slight fire hazard. Dust/air mixtures may ignite or explode.
Extinguishing media: Regular dry chemical, carbon dioxide, water, and regular foam.
Firefighting: Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Do not get water directly on material.
Large fires: Flood with fine water spray. Reduce vapors with water spray. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small spills: Sweep and collect spilled material in appropriate container for disposal.
Large spills: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Keep unnecessary people away, isolate hazard area and deny entry.

7. HANDLING AND STORAGE

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cold, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids and alkalis. Emptied containers retain vapor and product residue. Store refrigerated.

8. Exposure Controls/Personal Protection

Exposure Guidelines: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Orange to Red Powder or Solid or Crystals.
Odor: Not available.
Odor threshold: Not available.
pH: 8.3 (9 g/l in water @ 20C).
Relative density: 0.91
Melting point/freezing point: 36C - 38C (literature).
Boiling Point: 193C.
Flash point: 67C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water and other polar solvents
Viscosity: Not available.
Molecular Weight: 156.25
Chemical Formula: C9H18NO

10. Stability and Reactivity

Stability: Is stable under ordinary conditions of use and storage. Stability decreases in the presence of moisture
Hazardous Decomposition Products: Carbon Monoxide & Dioxide, Nitrogen Oxides, fumes.
Hazardous Polymerization: Will not occur
Incompatibilities: Strong oxidizing agents, strong acids and alkalis.
Conditions to Avoid: Strong heat generation, sunlight, incompatibles.

11. Toxicological Information

Acute animal toxicity: Not available.
Carcinogenicity: Not defined as a carcinogen by any agency.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Environmental Toxicity: No information found.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
Proper Shipping Name: Corrosive solid, basic, organic, n.o.s. (2,2,6,6-Tetramethylpiperidinooxy)
Hazard Class: 8, Packing Group: II
UN/NA: UN3263
IMDG/IMO & IATA/ICAO:
Proper Shipping Name: Corrosive solid, basic, organic, n.o.s. (2,2,6,6-Tetramethylpiperidinooxy)
Hazard Class: 8, Packing Group: II
UN/NA: UN3263

15. Regulatory Information

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA):  This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312: Acute health hazard, Chronic Health Hazard.
California Prop 65: Not listed on California Prop 65.

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives:
H290 = May be corrosive to metals.
H314 = Causes severe skin burns and eye damage.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C Corrosive.
Risk Phrases:
R34 = Causes burns.
R41 = Risk of serious damage to eyes.

 

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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