Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane or TMP or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane or TMP or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol or Trimethylol propane: CAS Number: 77-99-6, EINECS EC Number: 201-074-9, Molecular Formula: C6H14O3 or CH3CH2C(CH2OH)3, Molecular Weight: 134.17, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane or TMP or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol or Trimethylol propane.

Trimethylolpropane or TMP or 1,1,1-Tris(hydroxymethyl)propane or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol or Trimethylol propane is the organic compound with the formula CH3CH2C(CH2OH)3. This colorless to white solid with a faint odor. Trimethylolpropane or Trimethylol propane is widely used building block in the polymer industry. TMP is mainly consumed as a precursor to alkyd resins.

General Properties and Specifications of Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane or TMP or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol or Trimethylol propane:
Appearance: White solid; powder, granules, or flakes. Hygroscopic.
Odor: Faint odor.
Assay: 98%
Water: 0.1% maximum.
Relative density: about 1.08
Melting point: 58C literature.
Boiling point: 289C literature.
Flash point: 172C.
Solubility: Soluble in water and alcohol.

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Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane or TMP or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol or Trimethylol propane
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 26-Mar-21

Product Name & Other Names: Trimethylolpropane or 1,1,1-Tris(hydroxymethyl)propane or TMP or 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol or Trimethylol propane.
CAS No.: 77-99-6
EINECS EC Number: 201-074-9
Chemical Formula: C6H14O3 or CH3CH2C(CH2OH)3
Molecular Weight: 134.17
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazard statements:
H361 Suspected of damaging fertility or the unborn child.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P281: Use personal protective equipment as required.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful.
Risk Phrase:
R61 May cause harm to the unborn child.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Flash Point: 172C.
Fire/Explosion: Not considered to be a fire and explosion hazard. May burn at high temperature.
Extinguishing Medium: Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture: Carbon oxides and fumes may evolve.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Avoid dust formation. Avoid breathing vapors, dust/mist, or gas. Ensure adequate ventilation. Do not touch or walk through this product. Stop leak if safe to do so. Prevent entry into waterways, drains, confined areas. Collect material and place it into loosely covered plastic containers for later disposal.

Precautions for safe handling: Use with adequate ventilation. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash hands before eating. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agent.

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

Physical State: White solid; powder, granules, or flakes. Hygroscopic.
Odor: Faint odor.
Odor threshold: Not available.
pH: Not available.
Relative density: about 1.08
Melting Point: 58C literature.
Initial boiling point and boiling range: 289C literature.
Auto-ignition temperature: Not available.
Flash point: 172C literature.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water and alcohol.
Viscosity: Not available.
Chemical Formula: C6H14O3 or CH3CH2C(CH2OH)3
Molecular Weight: 134.17

Chemical Stability: Stable under recommended temperatures and pressures.
Incompatibility (Materials to Avoid): Strong oxidizing agents.
Conditions to Avoid: Incompatible materials, excessive heat.
Hazardous Decomposition Products: Carbon oxides.
Hazardous Polymerization: Will not occur.

Toxicity to Animals:
LD50 Oral Rat: 14100 mg/kg.
LC50 Inhalation Rat: 0.29 mg/L 4 h.
LD50 Dermal Rabbit: > 10.000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC.
Teratogenicity: Not available.
Reproductive Toxicity: Suspected of damaging the unborn child.

Toxicity to fish: static test LC50 Alburnus: > 1.000 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 13.000 mg/l - 48 h.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO: Not dangerous goods.
IATA/ICAO: Not dangerous goods.

USA:
SARA 302: Not subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312: Chronic Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H361 Suspected of damaging fertility or the unborn child.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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