Toluene or Methylbenzene Manufacturers, with SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Toluene, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Toluene or Methylbenzene: CAS Number: 108-88-3, EINECS EC Number: 203-625-9, Molecular Formula: C7H8, Molecular Weight: 92.14, HS Code 29023000 or 29215140
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SDS MSDS Sheet of Toluene Manufacturers
Toluene
Methylbenzene Analytical Reagent Pure Suppliers
Toluene is an aromatic hydrocarbon, a clear, colorless liquid which becomes a vapor when exposed to air at room temperature.
General Properties and Specifications of Toluene:
Appearance: Colorless liquid.
Odor: Sharp sweet.
Assay: 99.8%
Residue on evaporation: 0.0005%
Water by KF:
0.001%
Melting point: -95C.
Boiling point: 111C.
Flash point: 4C.
Relative density: about 0.87
Toluene Analytical Reagent Grade Specifications:
Methylbenzene
C6H5CH3 --- Formula Weight 92.14
CAS Number 108-88-3
REQUIREMENTS
Assay: 99.5% C6H5CH3
MAXIMUM ALLOWABLE
Color (APHA): 10
Residue after evaporation: 0.001%
Substances darkened by sulfuric acid: Passes test.
Sulfur compounds (as S): 0.003%
Water (H2O): 0.03%
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
We also manufacture and supply as under:
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
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e-mail: info@mubychem.com
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e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)
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Last
18 May, 2024
Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.
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Toluene or Methylbenzene SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 05-Sept-21
1. Product Identification
Product Name & Other Names: Toluene or Methylbenzene.
CAS No.: 108-88-3
EINECS EC No.: 203-625-9
Molecular Formula: C7H8
Molecular Weight: 92.14
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):
Flammable liquids (Category 2) H225
Aspiration hazard (Category 1), H304
Skin irritation (Category 2), H315
Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336
Reproductive toxicity (Category 2), H361d
Specific target organ toxicity - repeated exposure (Category 2), Central nervous system, H373
Long-term (chronic) aquatic hazard (Category 3), H412
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements  Flammable |
GHS Label Elements |
GHS Label Elements |
Signal Words: Danger
Hazard statements:
H225: Highly flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P281: Use personal protective equipment as required.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P370+378: In case of fire: Use water spray, fog, carbon dioxide (CO2), foam, dry powder for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
F = Flammable.
Xi = Irritant.
Xn = Harmful.
N = Dangerous for the environment.
R-phrases:
R10 Flammable.
R26 Very toxic by inhalation
R38 Irritating to skin.
R67 Vapors may cause drowsiness and dizziness.
R63 Possible risk of harm to the unborn child.
R48 Danger of serious damage to health by prolonged exposure.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. Composition/Information on Ingredients
Product Name & Other Names: Toluene or Methylbenzene.
CAS No.: 108-88-3
EINECS EC No.: 203-625-9
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Flammable.
Auto-Ignition Temperature: 535C.
Flash Points: 4C.
Products of Combustion: Carbon dioxide, Carbon monoxide and fumes.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Prefer dry powder and sand. Use water spray or fog, carbon dioxide (CO2), foam, dry powder. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Avoid a solid water jet on the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water spray to prevent pressure build-up, auto-ignition, or explosion.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. Use water spray to cool unopened containers.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep up or swab the material without causing dust/mist. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Do not ingest. Do not breathe dust vapors or mist. Work under hood. Ensure proper ventilation. Provide appropriate exhaust ventilation at places where dust/mist is formed. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like Acids, Bases, Halogens, Strong oxidizing agents, Metallic salts.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Employ Properly operating chemical fume hood designed for hazardous chemicals.
USA. ACGIH TLV TWA: 20 ppm.
USA. OSHA PEL TWA: 200 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Colorless liquid.
Odor: Sharp sweet odor.
Odor threshold: Not available.
pH: Not available.
Relative density: about 0.87
Boiling Point: 111C literature.
Melting Point: -95C literature.
Flash Point: 4C
Auto-ignition Temperature: 535C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very slightly soluble in water.
Viscosity: Not available.
Molecular Formula: C7H8
Molecular Weight: 92.14
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. Vapors may form explosive mixture with air. Heat sensitive.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide and fumes.
Hazardous Polymerization: Will ordinarily not occur.
Incompatibilities: Acids, Bases, Halogens, Strong oxidizing agents, Metallic salts.
Conditions to Avoid: Exposure to heat, flames, and sparks. Extremes of temperature and direct sunlight.
11. Toxicological Information
Toxicity data
Oral-Rat LD50: 5580 mg/kg.
Inhalation-Rat LC50: - 4-hour 25.7 mg/L.
Dermal Rabbit LD50: >5000 mg/kg
Carcinogenicity: May cause cancer.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Mutagenicity: May cause genetic defects.
Neurotoxicity: No information found.
12. Ecological Information
Toxicity to fish: flow-through test LC50 - Oncorhynchus kisutch (coho salmon) - 5,5 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates EC50 - Ceriodaphnia dubia (water flea) - 3,78 mg/l - 48 h.
Persistence and Degradability: Not likely to persist.
Mobility: Likely to be mobile.
Bioaccumulation/ Accumulation: Not likely to accumulate.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN1294, Hazard Class: 3, Packing Group: II
Shipping Name: Toluene.
IATA/ICAO & IMDG/IMO
UN Number: UN1294, Hazard Class: 3, Packing Group: II
Shipping Name: Toluene.
15. Regulatory Information
USA:
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard, Chronic Health Hazard. See section 2.
California prop. 65: Contains no chemical subject to California Prop 65.
16. Other Information
European Labeling in Accordance with EC Directives:
H225: Highly flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
F = Flammable.
Xi = Irritant.
Xn = Harmful.
N = Dangerous for the environment.
R-phrases:
R10 Flammable.
R26 Very toxic by inhalation
R38 Irritating to skin.
R67 Vapors may cause drowsiness and dizziness.
R63 Possible risk of harm to the unborn child.
R48 Danger of serious damage to health by prolonged exposure.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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