Sulfuric Acid or Sulphuric Acid 0.1 Normal, 1 Normal etc BP Ph Eur USP NF FCC Food Analytical Reagent Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Sulphuric Acid or Sulfuric Acid 0.1N, 1N etc, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Sulfuric Acid or Sulphuric Acid: CAS Number: 7664-93-9, EINECS EC Number: 231-639-5, Molecular Formula: H2SO4, Molecular Weight: 98.08, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Sulfuric Acid or Sulphuric Acid.

Sulfuric Acid or Sulphuric Acid is a mineral acid composed with molecular formula H2SO4. It is a colorless, odorless, and syrupy liquid that is soluble in water and is synthesized in reactions that are highly exothermic. It is corrosiveness and hygroscopic. Contact, sulfuric acid can cause severe chemical burns.

Sulfuric Acid BP Ph Eur Grade Specifications:
Sulphuric Acid
Ph. Eur.
H2SO4 --- 98.1 --- CAS 7664-93-9
Preparation: Dilute Sulfuric Acid

CHARACTERS
Appearance: Colourless, oily liquid, very hygroscopic.
Solubility: Miscible with water and with ethanol (96 per cent) producing intense heat.
Relative density: About 1.84.

IDENTIFICATION
A. Carefully add 1 mL to 100 mL of water. The solution is strongly acid.
B. The solution obtained in identification test A gives reaction (a) of sulfates.

TESTS
Appearance of solution: The solution is clear and colourless.
Carefully pour, while cooling, 5 mL into 30 mL of water and dilute to 50 mL with the same solvent.
Chlorides: Maximum 50 ppm.
Nitrates: Add 5 mL to 5 mL of water. Cool to room temperature and add 0.5 mL of indigo carmine solution. The blue colour persists for at least 1 min.
Arsenic: Maximum 1 ppm.
Iron: Maximum 25 ppm.

ASSAY
Weigh accurately a ground-glass-stoppered flask containing 30 mL of water. Introduce 0.2 mL, cool and weigh again. Titrate with 1 M sodium hydroxide, determining the end-point potentiometrically.
1 mL of 1 M sodium hydroxide is equivalent to 49.04 mg of H2SO4.

Sulfuric Acid USP NF Grade Specifications:
H2SO4 --- 98.08
Sulfuric acid [CAS 7664-93-9].

Sulfuric Acid contains not less than 95.0 percent and not more than 98.0 percent, by weight, of H2SO4.

[Caution: When Sulfuric Acid is to be mixed with other liquids, always add it to the diluent and exercise great caution.]

Packaging and storage: Preserve in tight containers.
Identification: It responds to the tests for Sulfate.
Residue on ignition: Evaporate 22 mL (40 g) to dryness, and ignite: not more than 2 mg of residue remains (0.005%).
Chloride: A dilution of 1.1 mL (2.0 g) in water shows no more chloride than corresponds to 0.15 mL of 0.020 N hydrochloric acid (0.005%).
Arsenic: --- (1 ppm).
Heavy metals: -- the limit is 5 ppm.
Reducing substances: Carefully dilute 4.4 mL (8.0 g) with about 50 mL of ice cold water, keeping the solution cold during the addition. Add 0.10 mL of 0.10 N potassium permanganate: the solution remains pink for 5 minutes.
Assay: Place about 1 mL of Sulfuric Acid in an accurately weighed, glass-stoppered flask containing about 20 mL of water, and weigh again to obtain the weight of the test specimen. Dilute with about 25 mL of water, cool, add methyl orange, and titrate with 1 N sodium hydroxide. Each mL of 1 N sodium hydroxide is equivalent to 49.04 mg of H2SO4.

Sulfuric Acid FCC Food Grade:
H2SO4 --- Formula weight 98.07
INS: 513 CAS 7664-93-9]

DESCRIPTION
Sulfuric Acid occurs as a clear, colorless or slightly brown, oily liquid. It is very caustic and corrosive. It is miscible with water and with alcohol with the generation of much heat and contraction in volume. Sulfuric Acid should be added cautiously to the diluent when mixed with other liquids. Some commercially available concentrations of Sulfuric Acid are expressed in degrees Baume and others (above 93.0%) as a percentage of H2SO4.
Function: Acidifier.

REQUIREMENTS
Identification: A sample gives positive tests for Sulfate.
Assay: Not less than the minimum or within the range of Baume or the percentage of H2SO4 claimed or implied by the vendor.
Arsenic: Not more than 3 mg/kg.
Chloride: Not more than 0.005%.
Iron: Not more than 0.02%.
Lead: Not more than 5 mg/kg.
Nitrate: Not more than 10 mg/kg.
Reducing Substances (as SO2): Passes test.
Selenium: Not more than 0.002%.

Sulfuric Acid Analytical Reagent Grade:
H2SO4 --- Formula Weight 98.08
CAS Number: 7664-93-9

REQUIREMENTS
Appearance: Free from suspended or insoluble matter
Assay: 95.0-98.0% H2SO4

MAXIMUM ALLOWABLE
Color (APHA): 10
Residue after ignition: 5 ppb
Chloride (Cl): 0.2 ppm
Nitrate (NO3): 0.5 ppm
Ammonium (NH4): 2 ppm
Substances reducing permanganate (as SO2): 2 ppm
Arsenic (As): 0.01 ppm
Heavy metals (as Pb): 1 ppm
Iron (Fe): 0.2 ppm
Mercury (Hg): 5 ppb.

Sulfuric Acid, Ultratrace Analytical Reagent Grade
(suitable for use in ultratrace elemental analysis)
H2SO4 --- Formula Weight 98.08
CAS Number 7664-93-9

NOTE. Reagent must be packaged in a preleached Teflon bottle and used in a clean environment to maintain purity.

MAXIMUM ALLOWABLE
Chloride (Cl): 0.2 ppm
Nitrate (NO3): 0.5 ppm
Aluminum (Al): 1 ppb
Barium (Ba): 1 ppb
Boron (B): 5 ppb
Cadmium (Cd): 1 ppb
Calcium (Ca): 1 ppb
Chromium (Cr): 1 ppb
Cobalt (Co): 1 ppb
Copper (Cu): 1 ppb
Iron (Fe): 5 ppb
Lead (Pb): 1 ppb
Lithium (Li): 1 ppb
Magnesium (Mg): 1 ppb
Manganese (Mn): 1 ppb
Molybdenum (Mo): 1 ppb
Mercury (Hg): 1 ppb
Potassium (K): 1 ppb
Selenium: 100 ppb
Silicon (Si): 5 ppb
Sodium (Na): 5 ppb
Strontium (Sr): 1 ppb
Tin (Sn): 1 ppb
Titanium (Ti): 1 ppb
Vanadium (V): 1 ppb
Zinc (Zn): 1 ppb
Zirconium (Zr): 1 ppb.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Sulfuric Acid or Sulphuric Acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 20-Nov-20

Product Name & Other Names: Sulfuric Acid or Sulphuric Acid.
CAS No.: 7664-93-9
EINECS EC Number: 231-639-5
Molecular Weight: 98.08
Chemical Formula: H2SO4
Relevant identified uses of the substance or mixture and uses advised against: Laboratory chemicals, Manufacture of substances. For Industrial use.
Details of the supplier of the safety data sheet: As per letter head.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive to Metals Category 1 H290
Skin corrosion/irritation Category 1A, B, C H314
Specific target organ toxicity - Respiratory system, H335

Hazard statements:
H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

Precautionary statements:
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340+P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C Corrosive
Risk Phrases:
R35 Causes severe burns.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.

Product Name & Other Names: Sulfuric Acid or Sulphuric Acid.
CAS No.: 7664-93-9
EINECS EC Number: 231-639-5
Percent: < 99% in water.

Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eye with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to and unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Medical Conditions generally Aggravated by Exposure: Repeated exposure of the eyes can produce eye irritation. Inhalation can produce respiratory irritation or sensitization.

Flash Point: NA
Fire Extinguishing Media: Adapt extinguishing media to the environment. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire Fighting Procedures: Wear self contained breathing apparatus for firefighting if necessary.
Unusual Fire and Explosion Hazards: Flammable hydrogen gas may be produced on prolong contact with metals such as aluminum, tin lead and zinc.
Hazardous combustion products: Sulfur oxide and toxic fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law. Small quantities of liquid spill may be neutralize with alkali solution.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, and bases. Air and light sensitive.

Components with workplace control parameters
USA ACGIH TLV: 0.2 mg/m3
USA OSHA PEL: 1 mg/m3 Vacated.
Engineering Controls Ventilation required: It should be handled or transferred in an approved fume hood or with adequate ventilation.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance and Physical State: Colorless liquid.
Odor: Not available.
Odor threshold: Not available.
pH: Highly acidic.
Relative density: Varies with assay.
Melting point/freezing point: Varies with assay.
Initial boiling point and boiling range: Varies with assay.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility in Water: Soluble
Viscosity: Not available.
Molecular Weight: 98.08
Chemical Formula: H2SO4

Stability: It is stable under ordinary conditions of use and storage.
Reactivity: Reacts with metals to release hydrogen.
Materials to Avoid (Incompatibility): Strong oxidizing agents, Strong acids.
Hazardous Decomposition Products: Thermal decomposition may produce sulfur oxide and toxic fumes.
Hazardous Polymerization: Will not occur.

Results of component toxicity test:
Oral LD50: 2140 mg/kg ( Rat ).
Dermal LD50: Not listed.
Inhalation LC50: 510 mg/m3 ( Rat ) 2 h.
Carcinogenicity:
IARC: Group 1 - Carcinogenic to Humans.
NTP: Known Carcinogen
ACGIH: A2 - Suspected Human Carcinogen.
Mutagenic Effects: No information available.
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Toxicity to fish: LC50 - Gambusia affinis (Mosquito fish) - 42 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 29 mg/l - 24 h.
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No information available.

State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.

DOT USA, TDG Canada & ADR/RID Europe:
Proper shipping name: SULPHURIC ACID
Hazard Class: 8
Packaging group: II
UN Number: UN1830
IATA:
Proper shipping name: SULPHURIC ACID
Hazard Class: 8
Packaging group: II
UN Number: UN1830
IMO/IMDG:
Proper shipping name: SULPHURIC ACID
Hazard Class: 8
Packaging group: II
UN Number: UN1830

USA:
SARA Section 311/312 Hazard Classes: Immediate (acute) health hazard
California Proposition 65: Listed.

Section 16: Other Information
European Labeling in Accordance with EC Directives:
H290: May be corrosive to metals
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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