Sodium Sulfide Nonahydrate USP NF, Analytical Reagent Grade Manufacturers, with SDS MSDS Sheet

Supplier, Manufacturer, Exporter of Sodium Sulfide Nonahydrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Sodium Sulfide: CAS Number:1313-84-4 for Nonahydrate & (1313-82-2 for Anhydrous), EINECS EC Number:215-211-5, Molecular Formula: Na2S.9H2O, Molecular Weight:240,18 HS Code ---**

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Sodium Sulphate or Sodium Sulfide.

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MSDS Sheet of Sodium Sulfide Manufacturers

Spanish Fabricantes de nonahidrato de sulfuro de sodio

Portuguese Fabricantes de Sulfeto de Sódio Nonahidratado

Korean 황화나트륨 비수화물 제조업체

Sodium Sulfide
Pure Nonahydrate Analytical Reagent USP FCC Food Grade Suppliers
Sodium Sulfide Nonahydrate

Sodium sulfide Na2S, or more commonly its hydrate Na2S-9H2O are colorless water-soluble salts that give strongly alkaline solutions. When exposed to moist air, Na2S and its hydrates emit hydrogen sulfide, which smells like rotten eggs. Some commercial samples are specified as Na2S·xH2O, where a weight percentage of Na2S is specified. Commonly available grades have around 60% Na2S by weight, which means that x is around 3. Such technical grades of sodium sulfide have a yellow appearance owing to the presence of polysulfides. These grades of sodium sulfide are marketed as 'sodium sulfide flakes'. Although the solid is yellow, solutions of it are colorless.

Sodium Sulfide USP Grade Specifications
Na2S-9H2O 240.18
Sodium sulfide nonahydrate.
Disodium sulfide nonahydrate CAS 1313-84-4

Sodium Sulfide contains not less than 98.0 percent and not more than 103.0 percent of Na2S.9H2O.

Identification: [NOTE—Conduct this test in a fume hood.] Transfer about 100 mg of Sodium Sulfide, to a suitable container, add 10 mL of 3 N hydrochloric acid, and cover the top of the container with filter paper saturated with a 0.2 M lead acetate solution: a brownish or silvery-black color forms on the paper.
Limit of iron: Dissolve about 5.0 g in 100 mL of water: the solution is clear and colorless.
Limit of sulfite and thiosulfate: Dissolve 3.0 g in 200.0 mL of filtered and degassed water. Add 100.0 mL of 0.2 N zinc sulfate, mix, and allow to stand for 30 minutes. Filter, add 1 mL of starch, and titrate 100.0 mL of the filtrate with 0.01 N iodine: not more than 3.0 mL is required.


Sodium Sulfide Nonahydrate Analytical Reagent Grade Specifications
Na2S-9H2O --- Formula Weight 240.18
CAS Number 1313-84-4
NOTE: To enhance stability, storage below 10C is recommended.

REQUIREMENTS
Appearance: Crystals, colorless or with only a slight yellow color
Assay: 98.0% Na2S-9H2O

MAXIMUM ALLOWABLE
Ammonium (NH4): 0.005%
Sulfite and thiosulfate (as SO4): 0.1%
Iron: Passes test.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We also manufacture and supply as under:

Cadmium Sulfide

Selenium Sulfide

Sodium Sulfide

Stannic Sulfide

Iron Sulphide

Heptanesulfonic Acid Sodium Salt

Soda-Lime

Sodium Acetate

Sodium Bicarbonate

Sodium Bromide

Sodium Bromate

Sodium Butyrate

Sodium Chloride IP BP USP

Sodium Citrate

Sodium Diacetate

Sodium Formaldehyde Bisulfite

Sodium Formate

Sodium Hydroxide Pellets

Sodium Molybdate

Sodium Nitrite

Sodium Nitrate

Sodium Perborate

Sodium Phosphate

Sodium Selenite Pentahydrate

Sodium Sulfate

Sodium Sulfide

Sodium Thiosulfate

and many other sodium salts.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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Last 18 August, 2024

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Sodium Bromate Sodium Lactobionate
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Sodium Sulfide Nonahydrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
18-Nov-20

1. Product Identification

Product Name & Other Names: Sodium Sulfide Nonahydrate or Sodium monosulfide nonahydrate or Sodium sulphide nonahydrate.
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5
Molecular Weight: 240.18
Chemical Formula: Na2S-9H20
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1B) H314
Acute aquatic toxicity (Category 1) H400

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
toxic.png
Toxic

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Words: Danger

Hazard statements:
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T: Toxic
C: Corrosive
N: Dangerous for the environment
Risk Phrases:
R22 Harmful if swallowed.
R24 Toxic in contact with skin.
R31 Contact with acids liberates toxic gas.
R34 Causes burns.
R41 Risk of serious damage to eyes
R50 Very toxic to aquatic organisms.

3. Composition/Information on Ingredients

Product Name & Other Names: Sodium Sulfide Nonahydrate or Sodium monosulfide nonahydrate or Sodium sulphide nonahydrate.
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Products of Combustion: Sulphur oxides, Sodium oxides, fumes.
Fire: Sodium Sulfide Nonahydrate is not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use water to cool fire-exposed containers.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. On decomposition it may emit hydrogen sulfide. Containers may explode on heating.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Corrosive solid. Avoid touching the spilled material. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Do not ingest. Do not breathe dust. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, metals, acids.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not established for the product. However, if Hydrogen sulfide is released in handling and use, then observe its limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Yellowish powder.
Odor: rotten egg-like.
Odor threshold: Not available.
pH: Alkaline
Relative density: around 1.43
Boiling Point: 920C - lit.
Melting Point: 50C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It soluble in water.
Viscosity: Not available.
Molecular Weight: 240.18
Chemical Formula: Na2S-9H20

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. One can say it is moderately stable in atmospheric condition. Aqueous solutions and moist solid may slowly give off hydrogen sulfide gas. Air and light sensitive. May discolor on exposure to air. Liberates toxic hydrogen sulfide on contact with acids. Reacts violently with carbon, diazonium salts; n,n-dichloromethylamine, o-Nitroaniline, diazonium salt, water. Reacts with water to form strong solutions and Hydrogen sulfide Reacts with acid more vigorously, producing corrosive solutions, and hydrogen sulfide. Also incompatible with Acids, Aluminum, Zinc. Decomposes in air at 920-950 deg. C.
Hazardous Decomposition Products: It emits toxic hydrogen sulfide fumes when heated to decomposition. It may form sodium oxide and sulfur.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, metals & acids.
Conditions to Avoid: Incompatibles and moisture.

11. Toxicological Information

Toxicity data
Oral LD50 Mouse: 205 mg/kg
Oral LD50 Rat: 208 mg/kg; Intraperitoneal LD50 147 mg/kg
LD50 Dermal: < 340 mg/kg ( Rabbit )
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Toxicity to fish: LC50: 7.7 - 29.1 mg/L, 96h (Poecilia reticulata) for Na2S
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IMDG/IMO:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IATA:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED

15. Regulatory Information

USA:
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minims) reporting levels established by SARA Title III, Section 313.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

16. Other Information

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H311 = Toxic in contact with skin.
H314 = Causes severe skin burns and eye damage.
H400 = Very toxic to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T: Toxic
C: Corrosive
N: Dangerous for the environment
Risk Phrases:
R22 Harmful if swallowed.
R24 Toxic in contact with skin.
R31 Contact with acids liberates toxic gas.
R34 Causes burns.
R41 Risk of serious damage to eyes
R50 Very toxic to aquatic organisms.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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