Strong & Dilute Hypo or Soda Bleach or Sodium Hypochlorite Solution Pentahydrate Pure and USP BP Ph Eur Grade Manufacturers, SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Strong & Dilute Sodium Hypochlorite Solution Pentahydrat, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Sodium Hypochlorite: CAS Number: 7681-52-9 (anhydrous), 7681-52-8 (pentahydrate), EINECS EC Number: 231-668-3, Molecular Formula: NaOCl (anhydrous), Molecular Weight: 74.44, HS Code ---**
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SDS MSDS Sheet of Sodium Hypochlorite Solution Manufacturers
Sodium Hypochlorite
Soda Bleach or Hypo or Solution and Pentahydrate Pure and USP BP Ph Eur Grade Suppliers
Sodium hypochlorite is a chemical compound with the formula NaOCl. Anhydrous sodium hypochlorite can be prepared; however, it is highly unstable and decomposes explosively on heating or friction. Sodium hypochlorite can also be obtained as a crystalline pentahydrate NaOCl•5H2O, which is not explosive and is much more stable than the anhydrous compound. The formula is sometimes given as 2NaOCl•10H2O. The transparent light greenish yellow orthorhombic crystals contain 44% NaOCl by weight and melt at 25−27C. The compound decomposes rapidly at room temperature, so it must be kept under refrigeration. At lower temperatures, however, it is quite stable.
At typical ambient temperatures, sodium hypochlorite is more stable in dilute solutions that contain solvated Na+ and OCl− ions. The density of the solution is 1.093 g/mL at 5% concentration, and 1.21 g/mL at 14%, 20C. Solutions are commercial forms of sodium hypochlorite. Sodium hypochlorite solution is a liquid with an odor of chlorine. Usually it is clear but some solutions are greenish to yellow in color. Sodium hypochlorite is also known as soda bleach or chlorine bleach. It is an excellent sterilizer, oxidizer and discoloring agent, and also acts as a germicide, fungicide and deodorant.
General Specifications of Sodium Hypochlorite Solution:
Available chlorine: Minimum 12.00% weight. Other Dilutions can be offered.
Specific gravity at 25C: Minimum 1.170
Total alkali as NaOH: Maximum 1.50% weight
Appearance: Colorless to Yellowish liquid
Odor: Chlorine like Odor
Boiling point: Decomposes.
Fusion point:-25 ºC (Sol. at 12% NaOCl)
Solubility in water: It is 100% soluble in water
pH: >9
Sodium Hypochlorite Solution USP Grade Specifications
NaClO --- 74.44 --- CAS 7681-52-9
Hypochlorous acid, sodium salt.
Sodium Hypochlorite Solution contains not less than 4.0 percent and not more than 6.0 percent, by weight, of NaClO.
Caution: This Solution is not suitable for application to wounds.
Packaging and storage: Preserve in tight, light-resistant containers, at a temperature not exceeding 25C.
Identification:
A: The Solution at first colors red litmus blue and then bleaches it.
B: The addition of 3 N hydrochloric acid to the Solution causes an evolution of chlorine.
C: The solution obtained in Identification test B responds to the flame test for Sodium.
Assay: Weigh accurately, in a glass-stoppered flask, about 3 mL of Solution, and dilute it with 50 mL of water. Add 2 g of potassium iodide and 10 mL of 6 N acetic acid, and titrate the liberated iodine with 0.1 N sodium thiosulfate, adding 3 mL of starch as the endpoint is approached. Perform a blank determination, and make any necessary correction. Each mL of 0.1 N sodium thiosulfate is equivalent to 3.722 mg of NaClO.
Strong Sodium Hypochlorite Solution BP Ph Eur Grade Specifications:
DEFINITION
Strong Sodium Hypochlorite Solution is an aqueous solution of sodium hypochlorite containing not less than 8% of available chlorine. It may contain suitable stabilising agents.
Content of available chlorine, Cl: Not less than 8.0% w/w.
Total alkalinity: Not more than 1.8% w/w, calculated as NaOH, when determined by the following method. To 25 mL add 50 mL of water and 35 mL of hydrogen peroxide solution (20 vol) and titrate with 0.5M hydrochloric acid using methyl orange solution as indicator. Each mL of 0.5M hydrochloric acid is equivalent to 20 mg of NaOH. Determine the weight per mL of the solution and calculate the total alkalinity as a percentage weight in weight.Specifications of Sodium Hypochlorite Pentahydrate
Available chlorine wt% (Typical value): minimum 39.0 -- (42.0)
Aqueous solution: Pale yellow transparent
NaOH wt%: 0.05
NaCl wt%: 0.12
NaClO3 wt%: 0.05
NaBrO3 wt%: 0.005
Molecular formula: NaOCl-5H2O
Molecular weight: 164.52
Density g/cc: 1.6
Melting point : 25C-27C
Stability: Stable for 1 year below 7C
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Manufacturers:
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Sodium Hypochlorite Solution SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 17-Nov-20
1. Product Identification
Product Name & Other Names Sodium Hypochlorite Solution or Soda Bleach or Hypo.
CAS No.: 7681-52-9 (anhydrous), 7681-52-8 (pentahydrate)
EINECS EC Number: 231-668-3
Molecular Weight: 74.44
Molecular Formula: NaOCl (anhydrous)
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Skin corrosion (Category 1A B C), H314
Hazardous to the aquatic environment, acute hazard Category 1, H400
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements  Corrosive |
GHS Label Elements |
Signal Word: Danger
Hazard Statements:
H314 - Causes severe skin burns and eye damage.
H400 - Very toxic to aquatic life.
Precautionary Statements - Prevention
P260: Do not breath dust/mist.
P264: Wash face, hands and any exposed skin thoroughly after handling
P271: Use only outdoors or in a well-ventilated area
P272: Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection
P285: In case of inadequate ventilation wear respiratory protection
Precautionary Statements - Response
P302 + P352: IF ON SKIN: Wash with plenty of water.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333+P313: If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313: If eye irritation persists: Get medical advice/ attention
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor.
P391: Collect spillage.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
C Corrosive
N Dangerous for the environment
Risk Phrases:
R34 Causes burns.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
3. Composition/Information on Ingredients
Product Name & Other Names Sodium Hypochlorite Solution or Soda Bleach or Hypo.
CAS No.: 7681-52-9 (anhydrous), 7681-52-8 (pentahydrate)
EINECS EC Number: 231-668-3
Percentage: 5% to 25% active in water.
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
5. Fire Fighting Measures
Fire: It is not combustible, but substance is an oxidizer diluted with water.
Fire Extinguishing Media: Dry chemical, carbon dioxide. Do not use a heavy water stream.
Special hazards arising from the substance or mixture: Hydrogen chloride gas, Chlorine and Sodium oxide with along with irritating fumes.
Special Information: This oxidizing material can increase the flammability of adjacent combustible materials. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Oxidizing material diluted with water. Neutralize spill. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong reducing agents, powdered metals, amines, ammonia, strong acids, organic materials, methanol. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from organic or other readily oxidizable materials.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: 2 mg/m3 STEL.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Colorless to light, greenish-yellow liquid.
Odor: Pungent, Chlorine like.
Odor threshold: Not available.
pH: >9
Relative density: 1.1 to 1.2
Boiling Point: >100C
Melting Point: 13.6C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water
Viscosity: Not available.
Molecular Weight: 74.44
Molecular Formula: NaOCl (anhydrous).
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage. Contact with most metals will generate flammable hydrogen gas. Contact with water will generate considerable heat. Reacts with amines and ammonia compounds to form explosively unstable compounds. May be corrosive to metals. May be corrosive to: Aluminum, stainless steel, carbon steel, copper, bronze.
Hazardous Decomposition Products: Hydrogen chloride gas, Chlorine and Sodium oxide..
Hazardous Polymerization: Will not occur.
Incompatibilities: Powdered metals, Amines, Ammonia, Strong acids, Organic materials, Methanol, Forms shock-sensitive mixtures with certain other materials. Avoid Strong reducing agents and Heat.
Conditions to Avoid: Heat, moisture, flames, ignition sources and incompatibles.
11. Toxicological Information
Oral rat LD50: NA.
Carcinogenic Effects: Not a reported carcinogen by NTP ACGIH OSHA. IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Sodium hypochlorite).
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
12. Ecological Information
Environmental Fate: No information found.
Environmental Toxicity:
Toxicity to fish: LC50 Western mosquitofish (Gambusia affinis) 125 mg/l, 96 hours
Very toxic to aquatic life. Avoid release to the environment.
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. Dispose of container and unused contents in accordance legal requirements.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe
Proper Shipping Name: SODIUM HYPOCHLORITE
Hazard Class: 8
UN/NA: UN1791
Packing Group: III
IMDG/IMO & IATA/ICAO
Proper Shipping Name: Hypochlorite solution
Hazard Class: 8
UN/NA: UN1791
Packing Group: III
15. Regulatory Information
SARA 302: Not Listed
SARA 311/312: Acute Health Hazard. See section 2.
SARA 313: Not Listed
California Prop 65: California No Significant Risk Level: The product is not listed.
Section 16. Other Information
European Labeling in Accordance with EC Directives:
H314 - Causes severe skin burns and eye damage.
H400 - Very toxic to aquatic life.
Hazard Symbols:
C Corrosive
N Dangerous for the environment
Risk Phrases:
R34 Causes burns.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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