Potassium ferrocyanide trihydrate or Potassium hexacyanoferrate(II) trihydrate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Potassium ferrocyanide or hexacyanoferrate(II) trihydrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Potassium ferrocyanide trihydrate or Potassium hexacyanoferrate(II) trihydrate: CAS Number: 14459-95-1 for trihydrate (or 13943-58-3 anhydrous), EINECS EC Number: 237-722-2, Molecular Formula: K4Fe(CN)6-3H2O, Molecular Weight: 422.39, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Potassium ferrocyanide trihydrate or Potassium hexacyanoferrate(II) trihydrate.

Synonyms: Potassium ferrocyanide or Potassium ferrocyanate or Potassium hexacyanidoferrate(II) or Potassium hexacyanoferrate(II) or (Yellow) Prussiate of Potash or Tetrapotassium ferrocyanide

Potassium ferrocyanide or Potassium ferrocyanate or Potassium hexacyanidoferrate(II) is the inorganic compound with formula K4[Fe(CN)6]-3H2O. It is the potassium salt of the coordination complex [Fe(CN)6]4−. Potassium ferrocyanide finds many niche applications in industry. It and the related sodium salt are widely used as anti-caking agents for both road salt and table salt. The potassium and sodium ferrocyanides are also used in the purification of tin and the separation of copper from molybdenum ores. Potassium ferrocyanide is used in the production of wine and citric acid. It can also be used in animal feed.

Properties and Specifications of Potassium ferrocyanide or Potassium ferrocyanate or Potassium hexacyanidoferrate(II) or (Yellow) Prussiate of Potash or Tetrapotassium ferrocyanide:

Appearance: Light yellow, crystalline granules.
Relative Density: 1.85
Boiling point: Decomposes.
Solubility: Soluble in water. Insoluble in ethanol, ether.
Assay [K4Fe(CN)6•3H2O]: 98.5% - 102.0%
Insoluble matter: 0.01% maximum.
Chloride as Cl: 0.03% maximum.
Sulfates as SO4: limit about 0.01% maximum.

Potassium Ferrocyanide Trihydrate Analytical Reagent Grade Specifications:
Potassium Hexacyanoferrate(II) Trihydrate
K4Fe(CN)6-3H2O --- Formula Weight 422.39
CAS Number 14459-95-1

MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Chloride (Cl): 0.01%
Sulfate (SO4): Passes test.

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Potassium ferrocyanide trihydrate or Potassium hexacyanoferrate(II) trihydrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 14-Nov-20

Product Name & Other Names: Potassium ferrocyanide or Potassium ferrocyanate or Potassium hexacyanidoferrate(II) or Potassium hexacyanoferrate(II) or (Yellow) Prussiate of Potash or Tetrapotassium ferrocyanide.
CAS No.: 14459-95-1 for trihydrate (or 13943-58-3 for anhydrous)
EINECS EC Number: 237-722-2
Chemical Formula: K4Fe(CN)6-3H2O
Molecular Weight: 422.39
Relevant uses and uses advised against (if any): Industrial Manufacturing
SUPPLIER: As per Letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Long-term (chronic) aquatic hazard Category 3 - H412
Labeling according GHS & Regulation (EC) No 1272/2008

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May Causes mild eye irritation.
EUH032: Contact with acids liberates very toxic gas.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P273: Avoid release to the environment.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
None
Risk Phrases:
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong acids, strong oxidizing agents, ammonia, hydrochloric acid, cyanides. Containers may be hazardous when empty.

Airborne Exposure Limits:
USA ACGIH TLV: TWA: 1 mg/m3.
OSHA PEL: (Vacated) TWA: 1 mg/m3.
Ventilation System: In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered.
Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage. For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Safety glasses. Maintain eye wash fountain and quick-drench facilities.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Yellow crystals, small pellets or powder.
Odor: Not available.
Odor threshold: Not available.
pH: 8 to 10
Relative density: 1.85
Melting point/freezing point: 70C.
Initial boiling point and boiling range: Decomposes.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water. Insoluble in ethanol, ether.
Viscosity: Not available.
Chemical Formula: K4Fe(CN)6-3H2O
Molecular Weight: 422.39

Stability: Stable under ordinary conditions of use and storage. Light sensitive. It may liberate toxic cyanide fumes when it is mixed with acids
Hazardous Decomposition Products: When heated to decomposition, substance may emit oxides of carbon and nitrogen along with potassium and iron compound.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong acids, strong oxidizing agents, ammonia, hydrochloric acid, cyanides. Contact with acids liberates very toxic gas. Heating can release hazardous gases.
Conditions to Avoid: Avoid temperatures above 60°C, direct sunlight. Avoid dust formation. Incompatible materials.

LD50 Oral - Rat - 3613 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity:
Toxicity to fish: LC50: > 100 mg/L, 96h (Pimephales promelas).
Toxicity to daphnia & other aquatic invertebrates: EC50 - Daphnia (water flea) - 32 mg/l - 48 h.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused material in accordance with federal, state and local requirements.

DOT USA, TDG Canada & ADR/RID Europe: Not regulated as dangerous goods.
IMDG/IMO: Not dangerous goods
IATA: Not dangerous goods.

SARA 311/312: Acute: No; Chronic: No; Fire: No; Pressure: No; Reactivity: No (Pure / Solid)
SARA 313: Not applicable
SARA 302: Not applicable
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H412: Harmful to aquatic life with long lasting effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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