Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride CAS Number 59-88-1, EINECS EC Number: 200-444-7 or 248-259-0, Molecular Formula: C6H5NHNH2- HCl, Molecular Weight: 144.60, HS Code 29280090 or 29215990

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride.

Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride is a white to off-white solid with a weak aromatic odor.

General Properties and specifications of Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride:
Appearance: White to off-white crystalline powder.
Odor: Weak aromatic odor.
Assay: 99% minimum.
Solubility of 2% aq. solution: Clear
Sulphated Ash: 0.05% maximum.
Melting Point: 250C to 254C decomposes.
Solubility: Soluble in water.
Storage: Room temperature.

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Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 16-Oct-23

Product Name & Other Names: Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride.
CAS No.: 59-88-1
EINECS EC Code: 200-444-7 or 248-259-0
Molecular Weight: 144.60
Chemical Formula: C6H5NHNH2- HCl
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Skin sensitization (Category 1), H317
Germ cell mutagenicity (Category 2), H341
Carcinogenicity (Category 1B), H350
Specific target organ toxicity - repeated exposure (Category 1), H372
Acuate aquatic toxicity (Category 1), H400

Hazard Statements:
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P234 Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304+P341+P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P390 Absorb spillage to prevent material damage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
Xi Irritant
C Corrosive
N Dangerous for the environment.
Risk Phrase:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R36/38: Irritating to eyes,and skin.
R43 May cause sensitization by skin contact.
R45 May cause cancer.
R48 Danger of serious damage to health by prolonged exposure.
R51 Toxic to aquatic organisms.

Product Name & Other Names: Phenylhydrazine Hydrochloride or Phenylhydrazinium Chloride.
CAS No.: 59-88-1
EINECS EC Code: 200-444-7 or 248-259-0

Inhalation: If inhaled, it will cause irritation and damage to the nose and throat. It can cause headaches, bleeding from nose coughing and chest discomfort. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: It will cause irritation and burns to mouth, digestive tract and stomach. It may lead to pain, nausea, vomiting, and even collapse. Contact the medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush your eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Toxic fumes, carbon dioxide, carbon monoxide, hydrogen chloride, and nitrogen oxides may be formed in fire.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Mop and pick up the material and place in an appropriate waste disposal container. Soak up with inert absorbent material and dispose of it as hazardous waste. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Avoid mist formation. Wear full protective equipment and ensure proper ventilation. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Vacuum or sweep up and remove to an approved disposal container. Contact Environment Agency.

Precautions for safe handling: Keep away from heat and source of fire, preferably in a ventilated area. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Keep locked up in tightly closed container. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not ingest. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents etc. Containers may be hazardous when empty since they retain product residues. Do not store near food items.

Airborne Exposure Limits: No data found.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full-face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White to off-white crystalline powder.
Odor: Weak aromatic odor.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: 250C to 254C decomposes.
Initial boiling point and boiling range: Decomposes.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Molecular Weight: 144.60
Chemical Formula: C6H5NHNH2- HCl

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, nitrogen oxides (NOx), hydrogen chloride, and toxic fumes may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Oxidizing agents.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

4-HOUR EXPOSURE.
Acute oral toxicity (LD50): 100mg/kg Estimate.
Acute dermal toxicity (LD50): 300mg/kg Estimate.
Acute toxicity of the vapor (LC50): - 4 h - 0,51 mg/l - dust/mist Estimate.
Carcinogenicity: Presumed to have carcinogenic potential for humans.
Mutagenic Effects: Suspected of causing genetic defects.
Developmental Toxicity: Not available.
Reproductive Effects: May cause heritable genetic damage.
Causes damage to organs through prolonged or repeated exposure.

Toxicity to fish: Not available.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of containers and unused contents in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe
UN Number: 2811
Proper shipping name: Toxic solid, organic, n.o.s. (phenylhydrazinium chloride).
Class: 6.1, Packing group: III.
IMDG & IATA
UN Number: 2811
Proper shipping name: Toxic solid, organic, n.o.s. (phenylhydrazinium chloride).
Class: 6.1, Packing group: III.

USA:
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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