N'N-Dimethyl Formamide or DMF Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of N'N-Dimethyl Formamide or DMF, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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N'N-Dimethyl Formamide or DMF: CAS Number: 68-12-2, EINECS EC Number: 200-679-5, Molecular Formula: C3H7NO or (CH3)2NC(O)H, Molecular Weight: 73.09, HS Code 2924 19 00

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for N'N-Dimethyl Formamide or DMF.

Dimethylformamide or DMF is an organic compound with the formula (CH3)2NC(O)H. The primary use of DMF is as a solvent with low evaporation rate. DMF is used in the production of acrylic fibers and plastics. It is also used as a solvent in peptide coupling for pharmaceuticals, in the development and production of pesticides, and in the manufacture of adhesives, synthetic leathers, fibers, films, and surface coatings.

General Properties and Specifications of N'N-Dimethyl Formamide or DMF:
Appearance: Colorless transparent liquid without visible impurities.
Odor: Fishy odor.
Assay: 99.8% minimum.
Methanol: 50 mg/kg maximum.
Chroma (Pt-Co)#: 5 maximum.
Refractive index: n25D 1.427-1.429
Moisture: 0.05% maximum.
Formic acid: 30 mg/kg maximum.
Dimethyl amine: 15 mg/kg maximum.
pH (20% solution): 6.5-8.0
Fe: 0.05 mg/kg maximum.
Relative density: 0.95
Melting point: -61C.
Boiling point: 152C to 154C.
Flash point: 58C.
Auto-ignition Temperature: 440C.
Solubility: Miscible with water.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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N'N-Dimethyl Formamide or DMF SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 09-Nov-20

Product Name & Other Names: N'N-Dimethyl Formamide or DMF
CAS No.: 68-12-2.
EINECS EC Number: 200-679-5
Molecular Formula: C3H7NO or (CH3)2NC(O)H
Molecular Weight: 73.09
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 3, H226
Acute toxicity, dermal Category 4, H312
Acute toxicity, inhalation Category 4, H332
Serious eye damage/eye irritation Category 2A, H319
Reproductive toxicity Category 1B, H360D

Hazard Statements:
H226: Flammable liquid and vapor.
H312+H332: Harmful in contact with skin or if inhaled
H319: Causes serious eye irritation.
H360D May damage the unborn child.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P370+378: In case of fire: Use Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
F Flammable
Xn Harmful
X1 Irritant
Risk Phrase:
R10 Flammable
R21/22 Harmful by in contact with skin and by inhalation.
R36 Irritating to eyes.
R61 May cause harm to the unborn child.

Product Name & Other Names: N'N-Dimethyl Formamide or DMF
CAS No.: 68-12-2.
EINECS EC Number: 200-679-5

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable. Containers may explode when heated.
Products of Combustion: Carbon oxides, nitrogen oxides and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive, and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations .Vapors can accumulate in low areas.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Vapors can accumulate in low areas.
Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements, or confined areas.

Precautions for safe handling: Do not handle or store near an open flame, heat, or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Avoid prolonged exposure. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from heat, sources of ignition (spark or flame) and sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, alkali metals, halogens, halides, reducing agents, triethylaluminium, nitrates, metallic oxides, nonmetallic oxides, halogenated hydrocarbon, isocyanates, sodium, sodium borohydride, hydrides, oxides of phosphorus, azides, bromine, chlorine, chromium(VI) oxide, potassium permanganate, triethylaluminium, chlorates.

Airborne Exposure Limits: Exposure guidelines have not been established for this product.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless transparent liquid without visible impurities.
Odor: Fishy odor.
Odor threshold: Not available.
pH: 6.5-8.0 for 20% solution.
Relative density: 0.95
Flash Point: 58C.
Boiling point: 52C to 154C.
Melting point/Freezing point: -61C
Auto-ignition temperature: 440C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water.
Viscosity: Not available.
Molecular Formula: C3H7NO or (CH3)2NC(O)H
Molecular Weight: 73.09

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon oxides, nitrogen oxides and toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, alkali metals, halogens, halides, reducing agents, triethylaluminium, nitrates, metallic oxides, nonmetallic oxides, halogenated hydrocarbon, isocyanates, sodium, sodium borohydride, hydrides, oxides of phosphorus, azides, bromine, chlorine, chromium(VI) oxide, potassium permanganate, triethylaluminium, chlorates.
Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Toxicity data:
LD50 Oral -Rat: 3010 mg/kg.
LD50 Dermal -Rabbit: 1,500 mg/kg.
LC50 Inhalation -Rat: 4 h - > 5,85 mg/l
Carcinogenicity: Not expected to be hazardous by OSHA ACGIH and NTP criteria.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: Experiments have shown reproductive toxicity effects on laboratory animals.

Toxicity to fish: flow-through test LC50 - Lepomis macrochirus (Bluegill sunfish) - 7.100 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 13.100 mg/l - 48 h.
Persistence and Degradability: Persistence is unlikely due to water solubility.
Mobility: Likely to be mobile.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe:
Proper shipping name: N,N-DIMETHYLFORMAMIDE.
Class: 3.
UN number: 1265
Packing group: III.
IATA & IMDG/IMO:
Proper shipping name: N,N-DIMETHYLFORMAMIDE.
Class: 3.
UN number: 1265
Packing group: III.

USA:
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European/International Regulations European Labeling in Accordance with EC Directives
H226: Flammable liquid and vapor.
H312+H332: Harmful in contact with skin or if inhaled
H319: Causes serious eye irritation.
H360D May damage the unborn child.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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