Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine FCC Food Grade Manufacturers, with SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Morpholine or Diethylenimide oxide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine: CAS Number: 110-91-8, EINECS EC Number: 203-815-1, Molecular Formula: C4H9NO or O(CH2CH2)2NH, Molecular Weight: 87.12, HS Code 2934 99 90
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SDS MSDS Sheet of yy Manufacturers
Morpholine
Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine FCC Food Grade Pure Suppliers
Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine is an organic chemical compound having the chemical formula O(CH2CH2)2NH. Morpholine is widely used in organic synthesis. In research and in industry morpholine is used as a solvent for chemical reactions. Morpholine is also used as a chemical emulsifier in the process of waxing fruit.
General Properties and Specifications of Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine:
Appearance: Colorless hygroscopic liquid.
Odor: Fishy. Amine-like.
Assay: 99% minimum. (99.5% + is also offered.)
pH: 10.6 for 5g/l @ 20C.
Relative density: around 1
Melting point: - 5C literature.
Boiling point: 126C to 130C literature.
Flash point: 32C.
Auto-ignition temperature: 310C.
Solubility: Fully miscible with water. Miscible with many organic solvents.
Morpholine FCC Food Grade Specifications:
Tetrahydro-2H-1,4-oxazine; Diethylene Oximide;
Diethylene Imidoxide
C4H9NO --- Formula weight 87.12
CAS: 110-91-8
DESCRIPTION
Morpholine occurs as a clear, colorless, mobile, hygroscopic liquid. It is miscible with water with the evolution of some heat. It is also miscible with acetone, with ether, with castor oil, with methanol, with alcohol, and with many oils such as linseed and pine.
Function: Boiler water additive; component of coatings for fruits and vegetables.
REQUIREMENTS
Identification: The infrared absorption spectrum of a neat dispersion of the sample between two sodium chloride plates exhibits maxima only at the same wavelengths as those of a typical spectrum as shown in the section on Infrared Spectra, using the same test conditions as specified therein.
Assay: Not less than 99.%.
Distillation Range: Between 126C and 130C.
Lead: Not more than 1 mg/kg.
Refractive Index: Between 1.454 and 1.455 at 20°.
Specific Gravity: Between 0.997 and 1.000 at 25C.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
We also manufacture and supply as under:
MES Monohydrate Buffer or 2-Morpholineethane Sulpfnic Acid Monohydrate
3-(N-Morpholino)propanesulfonic Acid
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30
e-mail: info@mubychem.com
USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)
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Last
6 May, 2024
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Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine
SDS GHS, Safety Data Sheet
MSDS GHS, Material Safety Data Sheet 17-Mar-21
1. Product Identification
Product Name & Other Names: Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine.
CAS No.: 110-91-8
EINECS EC No.: 203-815-1
Molecular Formula: C4H9NO or O(CH2CH2)2NH
Molecular Weight: 87.12
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):
Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 3) H311
Acute toxicity, Inhalation (Category 4), H332
Skin corrosion (Sub-category 1B) H314
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements  Toxic |
GHS Label Elements |
GHS Label Elements |
Signal Words: Danger
Hazard statements:
H226: Flammable liquid and vapor.
H302 + H332 Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray or fog for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T = Toxic
C = Corrosive.
R-phrases:
R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R24 Toxic in contact with skin.
R34 Causes burns
R41 Risk of serious damage to eyes.
3. Composition/Information on Ingredients
Product Name & Other Names: Morpholine or Diethylenimide oxide or 1,4-Oxazinane or Tetrahydro-1,4-oxazine.
CAS No.: 110-91-8
EINECS EC No.: 203-815-1
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Flammable.
Flash Points: 32C.
Auto-ignition temperature: 310C.
Products of Combustion: Carbon dioxide, carbon monoxide, fumes & nitrogen compounds.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Foam, Dry powder should be preferred. Water spray or fog may also be used. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion. For this substance/mixture no limitations of extinguishing agents are given.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container.
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.
7. Handling and Storage
Work under hood. Do not inhale substance/mixture. Avoid generation of vapors/aerosols. Keep away from open flames, hot surfaces, and sources of ignition. Take precautionary measures against static discharge.
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, nitriles, acids, aluminum, nonferrous metals. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Hygroscopic.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
USA ACGIH TLV(TWA): 20 ppm (skin); OSHA PEL(TWA): 20 ppm (skin)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Colorless hygroscopic liquid.
Odor: Fishy. Amine-like.
Odor threshold: Not available.
pH: 10.6 for 5g/l @ 20C.
Relative Density around 1
Boiling Point: 126C to 130C literature.
Melting Point: - 5C literature.
Flash point: 32C.
Auto-ignition temperature: 310C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): Not available.
Vapor Density (Air=1): Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Fully miscible with water. Miscible with many organic solvents.
Molecular Formula: C4H9NO or O(CH2CH2)2NH
Molecular Weight: 87.12
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at intense warming. Hygroscopic.
Hazardous Decomposition Products: It emits Carbon dioxide, carbon monoxide, fumes & nitrogen compounds.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, nitriles, acids, aluminum, nonferrous metals.
Conditions to Avoid: Incompatibles, heat & light, sparks, flame.
11. Toxicological Information
Toxicity data
Oral Rat LD50: 1900 mg/kg.
Inhalation Rat LC50: 8000 ppm/8h.
Dermal Rabbit LD50: 500 mg/kg.
Carcinogenicity: IARC = Group 3 (Not classifiable as carcinogenic to humans).
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found.
12. Ecological Information
Toxicity to fish: static test LC50 - Oncorhynchus mykiss (rainbow trout) - 180 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 44,5 mg/l - 48 h.
Persistence and Degradability: Degradable product.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: Bioaccumulation is not expected.
Results of PBT and vPvB assessment: No data available for assessment.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN 2054
Shipping Name: MORPHOLINE
Hazard Class: 8 (3); Packing Group: I.
IATA & IMDG/IMO:
UN Number: UN 2054
Shipping Name: MORPHOLINE
Hazard Class: 8 (3); Packing Group: I.
15. Regulatory Information
USA:
SARA 311/312 Hazards: Fire Hazard: Immediate Health Hazard: Acute. See section 2.
California Proposition 65: This product contains the following Proposition 65 chemicals.
16. Other Information
European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H302+H332: Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
Hazard symbols:
T = Toxic
C = Corrosive.
R-phrases:
R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R24 Toxic in contact with skin.
R34 Causes burns
R41 Risk of serious damage to eyes.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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