L-Histidine Hydrochloride Monohydrate BP Ph Eur Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of L-Histidine Hydrochloride Monohydrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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L-Histidine Hydrochloride Monohydrate L-Histidine HCl Monohydrate CAS Number 5934-29-2, EINECS EC Number: 211-438-9 or 611-821-4, Molecular Formula: C6H10N3O2Cl-H2O, Molecular Weight: 209.63, HS Code 29224990 or 29332990

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for L-Histidine Hydrochloride Monohydrate L-Histidine HCl Monohydrate.

General Properties and Specifications of L-Histidine Hydrochloride Monohydrate L-Histidine HCl Monohydrate:
Appearance: White crystalline powder.
Solubility of 10% aq. solution: Clear colourless.
Assay: 99.0% minimum.
Specific rotation: +8.5 to + 9.5° (C=2, 5N HCl).
Loss on drying: 0. 0.5 % maximum.
Sulfated Ash: 0.1 % maximum.
Sulfate (SO4): 0.01 % maximum.
Iron (Fe): 0.001 % maximum.
Heavy Metals (Pb): 0.001 % maximum.
Ammonium (NH4): 0.01 % maximum.
Homogeneity by TLC: Passes test.
pH: 3.0 - 5.0 for 50g/l in CO₂-free water.
Melting Point: 254C.
Solubility: Soluble in water.
Storage: Room temperature.

Histidine Hydrochloride Monohydrate BP Ph Eur Grade Specifications:
C6H10ClN3O2,H2O -- 209.6 -- CAS 5934-29-2
Action and use: Amino acid.

DEFINITION
(2S)-2-Amino-3-(1H-imidazol-4-yl)propanoic acid hydrochloride monohydrate.
Product of fermentation or of protein hydrolysis.
Content: 98.5 per cent to 101.0 per cent (dried substance).

CHARACTERS
Appearance: White or almost white, crystalline powder or colourless crystals.
Solubility: Freely soluble in water, slightly soluble in ethanol (96 per cent).

IDENTIFICATION
First identification: A, B, C, F
Second identification: A, B, D, E, F
A. Specific optical rotation.
B. pH.
C. Infrared absorption spectrophotometry.
D. Thin-layer chromatography.
E. Dissolve 0.1 g in 7 mL of water and add 3 mL of a 200 g/L solution of sodium hydroxide. Dissolve 50 mg of sulfanilic acid in a mixture of 0.1 mL of hydrochloric acid and 10 mL of water and add 0.1 mL of sodium nitrite solution. Add the second solution to the first and mix. An orange red colour develops.
F. About 20 mg gives reaction (a) of chlorides.

L-Histidine Monohydrochloride FCC Food Grade Specifications:
L-_-Amino-4(or 5)-imidazolepropionic Acid Monohydrochloride
C6H9N3O2-HCl-H2O Formula weight 209.63
CAS: monohydrate CAS 5934-29-2

DESCRIPTION
L-Histidine Monohydrochloride occurs as white crystals or as a crystalline powder. It is soluble in water, and insoluble in alcohol and in ether. It melts with decomposition at about 250C (after drying).
Function: Nutrient.

REQUIREMENTS
Identification: The infrared absorption spectrum of the sample exhibits relative maxima at the same wavelengths as those of a typical spectrum as shown in the section on Infrared Spectra, using the same test conditions as specified therein.
Assay: Not less than 98.5% and not more than 101.5% of C6H9N3O2·HCl·H2O, calculated on the dried basis.
Lead: Not more than 5 mg/kg.
Loss on Drying: Not more than 0.3%.
Optical (Specific) Rotation [α]D20°: Between +8.5° and +10.5°, calculated on the dried basis.
Residue on Ignition: Not more than 0.1%.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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L-Histidine Hydrochloride Monohydrate or L-Histidine HCl Monohydrate
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 02-Oct-20

Product Name & Other Names: L-Histidine Hydrochloride Monohydrate or L-Histidine HCl Monohydrate.
CAS No.: 5934-29-2
EINECS: EC Number: 211-438-9 or 611-821-4
Molecular Weight: 209.63
Molecular Formula: C6H10N3O2Cl-H2O
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead above.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352-IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi = Irritant
Risk Phrase:
R36: Irritating to eyes.

Product Name & Other Names: L-Histidine Hydrochloride Monohydrate or L-Histidine HCl Monohydrate.
CAS No.: 5934-29-2
EINECS: EC Number: 211-438-9 or 611-821-4

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Not easily combustible. Combustible at high temperature.
Auto-Ignition Temperature: Not available.
Products of Combustion: Nitrogen oxides, carbon dioxide, carbon monoxide, chlorine or hydrochloric acid and toxic fumes.
Fire: Flammable in the presence of open flame.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Fire-extinguishing work is done from the windward and a suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents. Keep away from sources of ignition. Storage: Room temperature.

Airborne Exposure Limits: Not Established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White crystalline powder.
Odor: It has typical floral odor.
Odor threshold: Not available.
pH: 3.0 - 5.0 for 50g/l in CO₂-free water.
Relative density: Not available.
Boiling Point: Not available.
Melting Point: 254C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 209.63
Molecular Formula: C6H10N3O2Cl-H2O

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Nitrogen oxides, carbon dioxide, carbon monoxide, chlorine or hydrochloric acid and toxic fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents.
Conditions to Avoid: Incompatibles, flame, heat & light.

Toxicity data
ORL-RAT LD50 >2000 mg/kg.
Carcinogenic Effects: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Germ cell mutagenicity: Not available.
Reproductive toxicity: Not available.
Teratogenic Effects: Not available.

Environmental Fate: Not available.
Environmental Toxicity: Not known. Toxicity to fish cannot be ruled out.
Products of Biodegradation: Hazardous short-term degradation products are not likely. However, long term degradation products may arise.
Persistence and degradability: Not available.
Bioaccumulative potential: Not available.
Mobility: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of containers and unused contents in accordance with federal, state, and local requirements.

USA DOT Classification: Not regulated
Canada TDG Classification: Not regulated
IATA: Not regulated
ADR/RID Europe: Not regulated
IMDG: Not regulated.

USA:
SARA 311/312 Hazards: Immediate Health Hazard: Yes
California prop. 65: Contains no chemical subject to California Prop 65.

Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H319 = Causes serious eye irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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