Ethanol or Ethyl alcohol and Absolute alcohol Pure, BP Ph Eur, Analytical Reagent, FCC Food Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ethanol or Ethyl alcohol and Absolute alcohol, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Ethanol or Ethyl alcohol or Absolute alcohol: CAS Number: 64-17-5, EINECS EC Number: 200-578-6, Molecular Formula: C2H5OH or C2H6O, Molecular Weight: 46.07, FEMA Number: 2419, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Ethanol or Ethyl alcohol and Absolute alcohol.

Ethanol or Ethyl alcohol, is a chemical compound, a simple alcohol with the chemical formula C2H5OH. Ethanol is a volatile, flammable, colorless liquid with a slight characteristic odor. It is a the principal active ingredient found in alcoholic drinks. Ethanol is used in medical wipes and most commonly in antibacterial hand sanitizer gels as an antiseptic for its bactericidal and anti-fungal effects. It is a common solvent in industry. FDA has labeled ethanol as a Generally Recognized as Safe (GRAS) substance, which means that a panel of qualified experts determined that ethanol is safe to use in food products.

Properties and General Specifications of Ethanol or Ethyl alcohol:
Appearance: Colorless liquid
Density: 0.79 @ 20C
Melting point: -114.1C
Boiling point: 78.2C
Solubility: Miscible with water.

Ethyl Alcohol Analytical Reagent Grade Specifications:
Ethanol
CH3CH2OH --- Formula Wt 46.07
CAS Number 64-17-5

Suitable for use in ultraviolet spectrophotometry or general use. Product labeling shall designate the one or both of these uses for which suitability is represented on the basis of meeting the relevant requirements and tests. The ultraviolet spectrophotometry requirements include all of the requirements for general use.

MAXIMUM ALLOWABLE
Color (APHA) 10
Solubility in water: Passes test
Residue after evaporation: 0.001%
Acetone, isopropyl alcohol: Passes test
Titrable acid: 0.0005 meq/g
Titrable base: 0.0002 meq/g
Methanol (CH3OH): 0.1%
Substances darkened by sulfuric acid: Passes test
Substances reducing permanganate: Passes test
Specific Use
Ultraviolet Spectrophotometry
Wavelength (nm) 270-400 Absorbance (AU): 0.01
Wavelength (nm) 240 Absorbance (AU): 0.05
Wavelength (nm) 230 Absorbance (AU): 0.15
Wavelength (nm) 220 Absorbance (AU): 0.25
Wavelength (nm) 210 Absorbance (AU): 0.40

Ethyl Alcohol, Absolute Analytical Reagent Grade Specifications:
Ethanol, Absolute
CH3CH2OH --- Formula Weight 46.07
CAS Number 64-17-5

MAXIMUM ALLOWABLE
Water (H2O): 0.2%
Color (APHA): 10
Solubility in water: Passes test
Residue after evaporation: 0.001%
Acetone, isopropyl alcohol: Passes test
Titrable acid: 0.0005 meq/g
Titrable base: 0.0002 meq/g
Methanol (CH3OH): 0.1%
Substances darkened by sulfuric acid: Passes test
Substances reducing permanganate: Passes test.

Ethyl Alcohol FCC Food Grade Specifications:
Alcohol; Ethanol
C2H6O Formula wt 46.07
CAS: [64-17-5]

DESCRIPTION
Ethyl Alcohol occurs as a clear, colorless, mobile liquid. It is miscible with water, with ether, and with chloroform. It boils at about 78C and is flammable. Its refractive index at 20C is about 1.364.
Note: This monograph applies only to undenatured ethyl alcohol.
Function: Extraction solvent; carrier solvent.

REQUIREMENTS
Assay: Not less than 94.9% by volume (92.3% by weight) of C2H6O.
Acidity (as acetic acid): Not more than 0.003%.
Alkalinity (as NH3): Not more than 3 mg/kg.
Fusel Oil: Passes test.
Ketones, Isopropyl Alcohol: Passes test.
Lead: Not more than 0.5 mg/kg.
Methanol: Passes test.
Nonvolatile Residue: Not more than 0.003%.
Solubility in Water: Passes test.
Substances Darkened by Sulfuric Acid: Passes test.
Substances Reducing Permanganate: Passes test.

DEFINITION
Content: ethanol (C2H6O; Mr 46.07): 95.1 per cent V/V (92.6 per cent m/m) to 96.9 per cent V/V (95.2 per cent m/m) at 20C, calculated from the relative density using the alcoholimetric tables.

CHARACTERS
Appearance: Colourless, clear, volatile, flammable liquid, hygroscopic.
Solubility: Miscible with water and with methylene chloride. It burns with a blue, smokeless flame.
Boiling point: about 78C.

IDENTIFICATION
First identificationıA, B.
Second identificationıA, C, D.
A. It complies with the test for relative density.
B. Infrared absorption spectrophotometry. Comparison Ph Eur reference spectrum ethanol (96 per cent).
C. Mix 0.1 ml with 1 ml of a 10 g/l solution of potassium permanganate and 0.2 ml of dilute sulphuric acid in a test-tube. Cover immediately with a filter paper moistened with a freshly prepared solution containing 0.1 g of sodium nitroprusside and 0.5 g of piperazine hydrate in 5 ml of water. After a few minutes, an intense blue colour appears on the paper and becomes paler after 10-15 min.
D. To 0.5 ml add 5 ml of water, 2 ml of dilute sodium hydroxide solution, then slowly add 2 ml of 0.05 M iodine. A yellow precipitate is formed within 30 min.

TESTS
Appearance: It is clear and colourless when compared with water. Dilute 1.0 ml to 20 ml with water. After standing for 5 min, the dilution remains clear when compared with water.
Acidity or alkalinity: To 20 ml add 20 ml of carbon dioxide-free water and 0.1 ml of phenolphthalein solution. The solution is colourless. Add 1.0 ml of 0.01 M sodium hydroxide. The solution is pink (30 ppm, expressed as acetic acid).
Relative density: 0.805 to 0.812.
Absorbance: Maximum 0.40 at 240 nm, 0.30 between 250 nm and 260 nm and 0.10 between 270 nm and 340 nm. The absorption curve is smooth. Examine between 235 nm and 340 nm, in a 5 cm cell using water as the compensation liquid.
Volatile impurities: To pass the test by gas chromatography.
Residue on evaporation: Maximum 25 ppm m/V. Evaporate 100 ml to dryness on a water-bath and dry at 100-105C for 1 h. The residue weighs a maximum of 2.5 mg.
STORAGE
Protected from light.
IMPURITIES
A. 1,1-diethoxyethane (acetal),
B. acetaldehyde
C. acetone,
D. benzene,
E. cyclohexane,
F. CH3-OH: methanol,
G. butan-2-one (methyl ethyl ketone),
H. 4-methylpentan-2-one (methyl isobutyl ketone),
I. CH3-(CH2)2-OH: propanol,
J. propan-2-ol (isopropyl alcohol),
K. CH3-(CH2)3-OH: butanol,
L. butan-2-ol,
M. 2-methylpropanol (isobutanol),
N. furane-2-carbaldehyde (furfural),
O. 2-methylpropan-2-ol (1,1-dimethylethyl alcohol),
P. 2-methylbutan-2-ol,
Q. pentan-2-ol,
R. CH3-(CH2)4-OH: pentanol,
S. CH3-(CH2)5-OH: hexanol,
T. heptan-2-ol,
U. hexan-2-ol,
V. hexan-3-ol.

Ethanol BP Ph Eur Grade Specifications:
Absolute Alcohol; Dehydrated Alcohol
(Anhydrous Ethanol, Ph Eur)
C2H6O --- 46.07 --- 64-17-5

DEFINITION
Content: Not less than 99.5 per cent V/V of C2H6O (99.2 per cent m/m), at 20C, calculated from the relative density using the alcoholimetric tables.

IDENTIFICATION
First identificationıA, B.
Second identificationıA, C, D.
A. It complies with the test for relative density.
B. Infrared absorption spectrophotometry. Comparison Ph Eur reference spectrum of anhydrous ethanol.
C. Mix 0.1 ml with 1 ml of a 10 g/l solution of potassium permanganate and 0.2 ml of dilute sulphuric acid in a test-tube. Cover immediately with a filter paper moistened with a freshly prepared solution containing 0.1 g of sodium nitroprusside and 0.5 g of piperazine hydrate in 5 ml of water. After a few minutes, an intense blue colour appears on the paper and becomes paler after 10-15 min.
D. To 0.5 ml add 5 ml of water, 2 ml of dilute sodium hydroxide solution, then slowly add 2 ml of 0.05 M iodine. A yellow precipitate is formed within 30 min.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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ETHANOL or ETHYL ALCOHOL or ABSOLUTE ALCOHOL SDS, SAFETY DATA SHEET
MSDS SHEET, MATERIAL SAFETY DATA SHEET 18-Oct-20

Product Name & Other Names: Ethanol or Ethyl alcohol or Absolute alcohol.
CAS Number: 64-17-5
EINECS EC Number: 200-578-6
FEMA Number: 2419
Molecular Formula: C2H5OH or C2H6O
Molecular Weight: 46.07
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 2, H225
Serious eye damage/eye irritation Category 2B, H319

Hazard statements (GHS-US):
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.

Precautionary statements (GHS-US):
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P261: Avoid breathing vapors.
P264: Wash … thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P403+235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents/container to authorized agents only.

According to European Directive 67/548/EEC as amended.
Hazard Symbol:
F = Flammable.
Xi = Irritant.
Risk Phrase:
R11 Highly flammable.
R36 Irritating to eyes.

Product Name & Other Names: Ethanol or Ethyl alcohol or Absolute alcohol.
CAS Number: 64-17-5
EINECS EC Number: 200-578-6

Eye Contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin Contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.

Extinguishing Media Recommended: CO2, foam, dry chemicals, sand, water fog.
Non-Recommended: Do not use direct water jet on burning material.
Extinguishing Procedures: Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray. For large fires, apply water from as far as possible. Keep containers and surroundings cool with water spray. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.
Environmental precautions: Do not let the product enter drains, soil, or water sources. Prevent further leakage or spillage if safe to do so.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Avoid open flames or other sources of ignition.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like rubber, various plastics, strong oxidizing agents, acids, acid chlorides, acid anhydrides, alkali metals and ammonia. Keep away from ignition sources and naked flame. - No smoking. Take measures to prevent the build-up of electrostatic charge. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded.

Respiratory Protection: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear colorless liquid
Odor: Pungent alcoholic.
Odor threshold: Not available.
pH: 7
Relative density: 0.79
Melting point/freezing point: -114.1C.
Initial boiling point and boiling range: 78.2C.
Flash point: 9.7C.
Auto-ignition temperature: 455C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water.
Viscosity: Not available.
Molecular Formula: C2H5OH or C2H6O
Molecular Weight: 46.07

Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid contact with strong acids and oxidizing agents. Hazardous polymerization will not occur.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed during combustion.
Conditions to Avoid: Heat, sparks, open flames, and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Avoid rubber, various plastics, strong oxidizing agents, acids, acid chlorides, acid anhydrides, alkali metals and ammonia, direct sunlight. Extremely high or low temperatures.

LD 50 ORAL/RAT (mg/Kg): 7060 mg/kg
LD 50 DERMAL/RABBIT (mg/Kg): 15800 mg/kg.
LC50 inhalation rat: 38 mg/l /4h
Carcinogenic Effects: Not a reported carcinogen by NTP, ACGIH, OSHA.
IARC: Group 1: Carcinogenic to humans, (based on effects of drinking alcoholic beverages).
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. ECOLOGICAL INFORMATION

Toxicity to fish: flow-through test LC50 - Pimephales promelas - 15300 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test LC50 - Ceriodaphnia dubia (water flea) - 5.012 mg/l - 48h.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

In accordance with local environmental laws. Avoid disposing into drainage systems and into the environment.

DOT USA, ADR/RID Europe & TDG Canada
UN-No: UN1170
Proper Shipping Name: Ethanol
Hazard Class: 3; Packing Group: II
IMDG/IMO
UN-No: UN1170
Proper Shipping Name: Ethanol
Hazard Class: 3; Packing Group: II
IATA
UN-No: UN1170
Proper Shipping Name: Ethanol
Hazard Class: 3; Packing Group: II

USA:
SARA 311/312 Hazards: Fire Hazard, Immediate Acute Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
F = Flammable.
Xi = Irritant.
Risk Phrase:
R11 Highly flammable.
R36 Irritating to eyes.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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