Copper Carbonate and Basic Copper Carbonate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Copper Carbonate n Basic Copper Carbonate Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Copper Carbonate and Basic Copper Carbonate: CAS Number: 1184-64-1 and (12069-69-1 for Basic Copper Carbonate), EINECS EC Number: 214-671-4 or 231-325-8 and (235-113-6 for Basic Copper Carbonate), Molecular Formula: CuCO3 and [CuCO3-Cu(OH)2 for Basic Copper Carbonate], Molecular Weight: 123.55 and (221.12 for Basic Copper Carbonate), HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Copper Carbonate and Basic Copper Carbonate.

Copper (II) carbonate often called basic copper carbonate or cupric carbonate is a blue-green compound with chemical formula CuCO3. Copper Carbonate is a water insoluble Copper source that can easily be converted to other Copper compounds. Copper (II) carbonate is rarely encountered because it is difficult to prepare and readily reacts with water moisture from the air. Basic copper carbonate is a chemical compound, more properly called copper (II) carbonate hydroxide. It is an ionic compound (a salt) consisting of the ions copper (II) Cu2+, carbonate CO2−3, and hydroxide OH−. The name most commonly refers to the compound with formula Cu2CO3(OH)2. This compound is often improperly called (even in chemistry articles) copper carbonate, cupric carbonate, and similar names. The terms "copper carbonate", "copper(II) carbonate", and "cupric carbonate" almost always refer (even in chemistry texts) to a basic copper carbonate (or copper(II) carbonate hydroxide). Even chemistry text books confuse Copper Carbonate and Basic Copper Carbonate.

Copper Carbonate is used as active ingredient in wood preservative and copper chemical. It is also used for semiconductor in electronic devices, electronic ceramic, ceramic colorant, reagent in analytical chemistry, insecticide for potato, catalyst, purification of hydrogen, solvents for chromic iron ores, desulfurizing oils, medicine, paints.

Specifications of Copper Carbonate:
CAS Number: 12069-69-1
Molecular Formula: CuCO3
Relative Density: 3.9
Solubility in Water: Insoluble
Melting Point: 200C
Boiling Point: 290C decomposes
Assay: 46% to 50%
Appearance: Green powder
Chlorides: 0.05
Sulphates: 0.5
Iron: 0.1

Specifications of Basic Copper Carbonate:
Description :- A green colour free flowing powder. Free from visible extraneous matter and added modifying agents.
Chemical Formula : Cu(OH)2.CuCO3
Total copper content: 55 % minimum
pH of 1 % slurry: 6.5 to 8.5
Sulphate as 'SO4': 700 ppm maximum
Chloride as 'Cl': 700 ppm maximum
Sodium as 'Na': 2500 ppm maximum
Potassium as 'K': 50 ppm maximum
Iron as 'Fe': 300 ppm maximum
Arsenic as 'As': 55 ppm maximum
Lead as 'Pb':200 ppm maximum
Cadmium as 'Cd': 55 ppm maximum
Calcium as 'Ca': 300 ppm maximum
Moisture content % ( Loss on drying at 100C ): 0.1 % maximum
Matter insoluble in acid %: 0.1 % maximum.

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Copper Carbonate and Basic Copper Carbonate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 10-Oct-20

Product Name & Other Names: Copper Carbonate and Basic Copper Carbonate.
CAS No.: 1184-64-1 and (12069-69-1 for Basic Copper Carbonate)
EINECS EC Number: 214-671-4 or 231-325-8 and (235-113-6 for Basic Copper Carbonate)
Molecular Weight: 123.55 and (221.12 for Basic Copper Carbonate)
Chemical Formula: CuCO3 and [CuCO3-Cu(OH)2 for Basic Copper Carbonate]
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Acute toxicity, Oral Category 4, H302
Skin irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Hazardous to the aquatic environment, acute hazard Category 2, H401

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H401: Toxic to aquatic life.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn: Harmful
Xi: Irritant
Risk Phrase:
R22: Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R52 Harmful to aquatic organisms.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt, or waistband. If large amounts were swallowed, get medical advice.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.
Note to physician: Treat symptomatically.

Fire: Not considered to be a fire hazard. Irritating fumes, carbon oxides and copper oxide may form in fires.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire. Avoid a solid water stream as it may scatter and spread fire. Water spray may be useful in cooling equipment exposed to heat and flame.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to authority requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, and bases.

Airborne Exposure Limits: USA - ACGIH TLV and USA. NIOSH: TWA: 1 mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Copper green crystal or powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water.
Viscosity: Not available.
Molecular Weight: 123.55 and (221.12 for Basic Copper Carbonate)
Chemical Formula: CuCO3 and [CuCO3-Cu(OH)2 for Basic Copper Carbonate]

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Burning may produce fumes, carbon oxides and copper oxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, caustic alkalis and strong oxidizing agents.
Conditions to Avoid: Heat, incompatibles.

Acute toxicity: LD50 Oral - Rat - 1350 mg/kg (Basic Copper Carbonate)
Carcinogenicity: The product is not classed as carcinogen by IARC, ACGIH, NTP, OSHA.
Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.

Toxicity to fish: No information available.
Environmental Toxicity: Harmful to aquatic life. Avoid release to the environment.
Persistence and degradability: No information available.
Mobility in soil: No information available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA &ADR/RID Europe: Not available.
IMDG: Not available.
IATA: Not available.

SARA 311/312: Acute Health Hazard. See section 2.
California Proposition 65: Not listed.

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H401 = Toxic to aquatic life.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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