Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate USP BP Ph Eur FCC Food Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Calcium ascorbate or Ascorbic acid calcium salt USP BP Ph Eur FCC Food Grade, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate: CAS Number: 5743-27-1 or 5743-28-2, EINECS EC Number: 227-261-5, Molecular Formula: Ca(C6H7O6)2-2H2O, Molecular Weight: 426.34, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate.

Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate is a compound with the molecular formula CaC12H14O12. It is the calcium salt of ascorbic acid, one of the mineral ascorbates. It is approximately 10% calcium by mass. As a food additive, it has the E number E 302. It is approved for use as a food in several countries. It is used as an antioxidant. Calcium ascorbate can extend the shelf life of food and beverage products and protect against deterioration of color, flavor, and overall quality. It is generally used as calcium ascorbate dehydrate.

General Properties and Specifications of Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate:
Appearance: White crystalline powder.
Odor: Odorless.
pH: about 6 to 7.5
Solubility: Soluble in water.

DEFINITION
Calcium Ascorbate contains NLT 98.0% and NMT 101.0% of calcium ascorbate dihydrate (C12H14CaO12-2H2O), calculated on the as-is basis.

IDENTIFICATION
A. Identification Tests General, Calcium: A 100 mg/mL solution meets the requirements.
B. A 100 mg/mL solution decolorizes a 100 mg/mL solution of dichlorophenol–indophenol.
C. Infrared Absorption.

ASSAY
Acceptance criteria: 98.0%–101.0% on the as-is basis
Arsenic: NMT 3 µg/g
Limit of Fluoride: NMT 10 ppm
Optical Rotation: +95° to +97°
pH: 6.8–7.4
Loss on Drying: Dry 3 g at 105C for 2 h: it loses NMT 0.1% of its weight.

Calcium Ascorbate BP Ph Eur Grade Specifications:
C12H14CaO12,2H2O --- 426.3 --- 5743-28-2
Action and use: Excipient.

DEFINITION
Calcium di[(R)-2-[(S)-1,2-dihydroxyethyl]-4-hydroxy-5-oxo-2H-furan-3-olate] dihydrate.
Content: 99.0 per cent to 100.5 per cent of C12H14CaO12,2H2O.

CHARACTERS
Appearance: White or slightly yellowish, crystalline powder.
Solubility: Freely soluble in water, practically insoluble in ethanol (96 per cent).

IDENTIFICATION
First identification: A, B, E
Second identification: A, C, D, E
A. Specific optical rotation (see Tests).
B. Infrared absorption spectrophotometry.
C. Dilute 1 mL of solution S (see Tests) to 10 mL with water. To 2 mL of the solution add 0.2 mL of a 100 g/L solution of ferrous sulfate. A deep violet colour develops.
D. To 1 mL of solution S add 0.2 mL of dilute nitric acid and 0.2 mL of silver nitrate solution. A grey precipitate is formed.
E. The substance gives reaction (b) of calcium.

TESTS
Solution S: Dissolve 5.00 g in carbon dioxide-free water and dilute to 50.0 mL with the same solvent.
Appearance of solution: Solution S is clear and not more intensely coloured than reference solution. Examine the colour of the solution immediately after preparation of the solution.
pH: 6.8 to 7.4 for solution S.
Specific optical rotation: + 95 to + 97 (dried substance), determined using freshly prepared solution S.
Fluorides: Maximum 10 ppm.
Copper: Maximum 5 ppm.
Iron: Maximum 2 ppm.
Loss on drying: Maximum 0.1 per cent, determined on 1.000 g by drying in an oven at 105C for 2 h.

ASSAY
Dissolve 80.0 mg in a mixture of 10 mL of dilute sulfuric acid and 80 mL of carbon dioxide-free water. Add 1 mL of starch solution. Titrate with 0.05 M iodine until a persistent violet-blue colour is obtained.
1 mL of 0.05 M iodine is equivalent to 10.66 mg of C12H14CaO12,2H2O.

Calcium Ascorbate FCC Food Grade:
C12H14CaO12·2H2O Formula wt 426.34
INS: 302 CAS: 5743-27-1

DESCRIPTION
Calcium Ascorbate occurs as a white to slightly yellow, crystalline powder. It is soluble in water, slightly soluble in alcohol, and insoluble in ether. The pH of a 1:10 aqueous solution is between 6.8 and 7.4.
Function: Antioxidant.

REQUIREMENTS
Identification: A 1:10 aqueous solution gives positive tests for Calcium, Appendix IIIA, and it decolorizes dichlorophenol–indophenol.
Assay: Not less than 98.0% and not more than 100.5% of C12H14CaO12·2H2O.
Lead: Not more than 2 mg/kg.
Optical (Specific) Rotation: Between +95° and +97°.
Oxalate: Passes test.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Calcium ascorbate or Ascorbic acid calcium salt SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 19-Jan-21

Product Name & Other Names: Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate.
CAS Number: 5743-27-1 or 5743-28-2
EINECS EC Code: 227-261-5
Chemical Formula: Ca(C6H7O6)2-2H2O
Molecular Weight: 426.34
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name & Other Names: Calcium ascorbate or Ascorbic acid calcium salt or Calcium diascorbate.
CAS Number: 5743-27-1 or 5743-28-2
EINECS EC Code: 227-261-5

Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.
Notes to Physician: Treat symptomatically.

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Calcium oxide, Fumes and Oxides of carbon.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Physical state and appearance: White crystalline powder.
Odor: Odorless.
Odor threshold: Not available.
pH: about 6 to 7.5
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Chemical Formula: Ca(C6H7O6)2-2H2O
Molecular Weight: 426.34

Stability: It is stable.
Conditions of instability: Incompatible materials
Incompatibility with various substances: Heat, light, strong oxidizing agents.
Polymerization: Will not occur.
Hazardous decomposition products formed under fire conditions: Carbon oxides, Calcium oxide, Fumes.

Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Mutagenic Effects: Not available.
Reproductive Toxicity: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Ecotoxicity: The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Not dangerous for the ozone layer.
Products of Biodegradation: The product itself and its products of degradation are not toxic.
BOD5 and COD: Not available.
Persistence and Degradability: No information available.
Bioaccumulation/ Accumulation: No information available.
Mobility: No information available.
Results of PBT and vPvB assessment: No information available.

Waste Disposal: Waste must be disposed of in accordance with federal, state, and local environmental control regulations.

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods
IMDG/IMO: Not dangerous goods
IATA/ICAO: Not dangerous goods.

USA Federal and State Regulations:
SARA 311/312 Hazards: No SARA Hazards
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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