1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Butanediol or Tetramethylene Glycol, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol: CAS Number: 110-63-4, EINECS EC Number: 203-786-5, Molecular Formula: C4H10O2, Molecular Weight: 90.12, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for 1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol.

1,4-Butanediol, colloquially known as BD, is the organic compound with the formula HOCH2CH2CH2CH2OH. It is a colorless viscous and almost odorless liquid. 1,4-Butanediol is used industrially as a solvent and in the manufacture of some types of plastics, elastic fibers, polyurethanes and in organic chemistry.

Properties and Specifications of 1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol:
Appearance: Clear colorless liquid (wax-like solid when cold)
Odor: Faint
Specific Gravity: 1.012
Boiling Point: 228C.
Freezing Point: 20.1C.
Flash Point: 134C
Purity: 99.5% minimum.
Moisture: 0.05% maximum.

MUBY CHEMICALS
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1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol, SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 03-Oct-20

Product Name & Other Names: 1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol.
CAS Number: 110-63-4
EINECS EC Number: 203-786-5
Molecular Formula: C4H10O2
Molecular Weight: 90.12
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4 (H302)
Specific target organ toxicity - single exposure (Category 3), Central nervous system (H336)

Hazard Statements:
H302: Harmful if swallowed.
H336 May cause drowsiness or dizziness.

Precautionary Statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P273: Avoid release to the environment.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful R22
Risk Phrase:
R22 = Harmful if swallowed.
R67 Vapors may cause drowsiness and dizziness.

Product Name & Other Names: 1,4-Butanediol or Butane Diol or BD or Tetramethylene Glycol.
CAS Number: 110-63-4
EINECS EC Number: 203-786-5

Eye Contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin Contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.

Extinguishing Media Recommended: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Non-Recommended: Do not use direct water jet on burning material.
Extinguishing Procedure: Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Avoid open flames or other sources of ignition.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acid chlorides, acid anhydrides, reducing agents. Keep air contact to a minimum. Keep away from ignition sources and naked flame.

Exposure Limits: Clear guidelines are not established. Keep it to minimum. Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath.
Respiratory Protection: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear colorless liquid (wax-like solid when cold).
Odor: Faint.
Odor threshold: Not available.
pH: 7 to 8.
Relative density: 1.012
Flash Point (C): 134C.
Boiling Point (C): 228C.
Melting Point/Freezing Point (C): 20.1C.
Auto-ignition temperature: 350C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water.
Viscosity: Not available.
Molecular Formula: C4H10O2
Molecular Weight: 90.12

Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid contact with like strong oxidizing agents, acid chlorides, acid anhydrides, reducing agents.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed during combustion.
Conditions to avoid: Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.

LD50 Dermal - rat - >5,000 mg/kg
LD50 Oral - rat - 1500 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: static test LC50 - Pimephales promelas (fathead minnow) - > 30.000 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 813 mg/l - 48 h
Biodegradability: Not available. Expected to be readily biodegradable
Precautions: Prevent contamination of soil, ground, and surface water.
Results of PBT and vPvB assessment: Not available.

In accordance with local environmental laws. Avoid disposing into drainage systems and into the environment.

DOT USA: Not dangerous goods.
ADR/RID Europe: Not dangerous goods.
IMDG & ADR/RID: Not dangerous goods.
IATA: Not dangerous goods.

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H336 May cause drowsiness or dizziness.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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