Boron trifluoride etherate or Boron trifluoride diethyl etherate or Boron trifluoride ethyl etherate or Ethoxyethane or Trifluoroborane Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Boron trifluoride etherate or Boron trifluoride diethyl etherate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Boron trifluoride etherate or Boron trifluoride diethyl etherate or Boron trifluoride ethyl etherate or Ethoxyethane or Trifluoroborane: CAS Number: 109-63-7, EINECS EC Number: 203-689-8, Molecular Formula: BF3-O(C2H5)2, Molecular Weight: 141.93, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Boron trifluoride etherate or Boron trifluoride diethyl etherate or Boron trifluoride ethyl etherate or Ethoxyethane or Trifluoroborane.

Boron trifluoride etherate, or Boron trifluoride diethyl etherate or Boron trifluoride ethyl etherate or Ethoxyethane or Trifluoroborane is the chemical compound with the formula BF3O(C2H5)2. It is a colorless liquid, although older samples can appear brown. The compound is used as a source of boron trifluoride in many chemical reactions that require a Lewis acid. It is used as a catalyst used in the preparation of other chemicals. It is also used as a Lewis acid

General Properties and Specifications of Boron trifluoride etherate or Boron trifluoride diethyl etherate or Boron trifluoride ethyl etherate or Ethoxyethane or Trifluoroborane:
CAS Number: 109-63-7
Molecular weight: 141.93 g.mol-1
Appearance: Colorless or straw yellow transparent fuming liquid.
Assay: 99% minimum or 47.5-49.5 % w/w (as BF3).
Water: 0.3% maximum.
Relative density: around: around 1.15
Melting point: -58C.
Boiling point: 126C to 129C.
Flash point: 58C.
Autoignition temperature: 185C.
Storage temperature: 2C to 8C.

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Boron Trifluoride Etherate or Boron trifluoride diethyl etherate SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 03-Oct-20

Product Name & Other Names: Boron Trifluoride Etherate or Boron trifluoride diethyl etherate or Boron trifluoride ethyl etherate or Ethoxyethane or Trifluoroborane.
CAS No.: 109-63-7
EINECS EC No.: 203-689-8
Molecular Formula: BF3-O(C2H5)2
Molecular Weight: 141.93
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 3) H226
Skin corrosion (Category 1C), H314
Acute toxicity, Inhalation (Category 4) H332
Specific target organ toxicity - repeated exposure (Category 1) Inhalation, Kidney H372

Hazard statements:
H226: Flammable liquid and vapor.
H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.
H372: Causes damage to organs (Kidney) through prolonged or repeated exposure if inhaled.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P309 + P310: IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder, and Sand for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P410: Protect from sunlight.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbol(s):
C = Corrosive.
Xn = Harmful.
R-phrase(s):
R 10 Flammable.
R34 Causes burns.
R20 Harmful by inhalation.
R41 Risk of serious damage to eyes.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to physicians: Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal oedema may occur. Marked decrease in blood pressure may occur with frothy sputum, and high pulse pressure.

Flammability of the Product: Flammable.
Auto-Ignition Temperature: 185C.
Flash Points: 58C.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder and Sand for extinction. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use dry chemical, CO2, sand, cement, or regular foam. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion. Avoid solid water stream.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures it may produce toxic or irritating fumes. These substances will accelerate burning when involved in a fire. Some may burn rapidly with flare burning effect. Some may decompose explosively when heated or involved in a fire. May ignite combustibles (wood paper, oil, clothing, etc.). Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Fire may cause evolution of: Hydrogen fluoride, boron compounds May not get in touch with: Water Caution! in contact with water product releases boron trifluoride. Self-ignition possible due to air moisture.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand or vermiculite. Carefully sweep solid/powder up the material without causing dust. Dispose of in accordance with local regulations. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water and disposed of promptly, preferably by incineration.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Provide appropriate exhaust ventilation at places where dust/mist/vapor is formed. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Do not ingest. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. If you feel unwell, seek medical attention.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alcohol, alkalis, lithium aluminum hydride, alkali metals, water, acids.
Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Recommended storage temperature 2C - 8C.

Airborne Exposure Limits: Not Established. Keep it below 0.2 ppm. Provide adequate ventilation.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless or straw yellow transparent fuming liquid.
Odor: Stinging odor.
Odor threshold: Not available.
pH: Acidic.
Relative density: around 1.15
Melting point/freezing point: -58C.
Initial boiling point and boiling range: 126C to 129C.
Flash point: 58C.
Auto-ignition temperature: 185C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Formula: BF3-O(C2H5)2
Molecular Weight: 141.93

Stability: Stable under ordinary conditions of use and storage. Vapour/air-mixtures are explosive at intense warming. Violent reactions possible with air and water.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Toxic Fumes along with Hydrogen fluoride, Boron compounds.
Hazardous Polymerization: Will not occur.
Incompatibilities: Heat, strong oxidizing agents, alcohol, alkalis, lithium aluminum hydride, alkali metals, water, acids.
Conditions to Avoid: Incompatibles, heat, flame, sparks & light. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Do not allow water to enter container because of violent reaction. Reacts dangerously with glass. Do not store in glass containers.

Toxicity data:
LD50 Oral – Rat: 326 mg/kg.
LC50 Inhalation - Rat - 4 h - 1,21 mg/l.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Teratogenicity: No information found .
Reproductive Effects: No information found.
Mutagenicity: No information found.
To the best of our knowledge, the toxicological properties have not been thoroughly investigated.

Toxicity to fish:
Leuciscus idus: LC50: 22-46 mg/L/96h
static test LC50 Leuciscus idus (Golden orfe): > 100 mg/l; 96 h (Estimated by analogy with similar material).
Persistence and Degradability: No information available.
Bioaccumulation/ Accumulation: No information available.
Mobility: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
Harmful to water bodies due to pH shift.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

DOT USA & ADR/RID Europe:
UN Number: UN2604
Shipping Name: BORON TRIFLUORIDE DIETHYL ETHERATE
Hazard Class: 8(3); Packing Group: I.
IATA, & Canada TDG:
UN Number: UN2604
Shipping Name: BORON TRIFLUORIDE DIETHYL ETHERATE
Hazard Class: 8(3); Packing Group: I.

USA:
SARA 311/312 Hazards: Fire Hazard, Immediate Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.
H372: Causes damage to organs (Kidney) through prolonged or repeated exposure if inhaled.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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