Ammonium Thiocyanate or Ammonium Rhodanide Extra Pure and Analytical Reagent Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ammonium Thiocyanate or Ammonium Rhodanide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Ammonium Thiocyanate or Ammonium Rhodanide: CAS Number: 1762-95-4, EINECS EC Number: 217-175-6, Molecular Formula: NH4SCN, Molecular Weight: 76.12, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Ammonium Thiocyanate or Ammonium Rhodanide.

Ammonium thiocyanate is an inorganic compound with the formula NH4SCN. Ammonium thiocyanate is a colorless crystalline solid. It is soluble in water. Ammonium thiocyanate is used in the manufacture of herbicides, thiourea, and transparent artificial resins, in matches, as a stabilizing agent in photography, in various rust-proofing compositions, as an adjuvant in textile dyeing and printing, as a tracer in oil fields, in the separation of hafnium from zirconium, and in titrimetric analyses. Ammonium thiocyanate can also be used to determine the iron content in soft drinks by colorimetry.

Specifications of Ammonium Thiocyanate Extra Pure:
Assay (argentometric): 99.0% minimum.
Insoluble matter: 0.005% maximum.
pH-value (5%; water, 25C): 4.8 - 5.8
Chloride (Cl): 0.005% maximum.
Sulfate (SO₄): 0.0025% maximum.
Sulphide (S): 0.001% maximum.
Heavy metals (as Pb): 0.0005% maximum.
Cu (Copper): 0.0004% maximum.
Fe (Iron): 0.0001% maximum.
Pb (Lead): 0.0004% maximum.
Residue on ignition (as sulfate): 0.025% maximum.
Iodine consuming substances: ≤ 0.02 %

Ammonium Thiocyanate Reagent Grade Specifications:
NH4SCN --- Formula Wt 76.12
CAS Number 1762-95-4

REQUIREMENTS
Appearance: Colorless or white crystals
Assay: 97.5% NH4SCN
pH of a 5% solution: 4.5-6.0 at 25C

MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Residue after ignition: 0.025%
Chloride (Cl): 0.005%
Sulfate (SO4): 0.005%
Heavy metals (as Pb): 5 ppm
Iron (Fe): 3 ppm
Iodine-consuming substances: 0.004 meq/g.

MUBY CHEMICALS
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Ammonium Thiocyanate or Ammonium Rhodanide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 01-Oct-20

Product Name & Other Names: Ammonium Thiocyanate or Ammonium Rhodanide
CAS No.: 1762-95-4
EINECS EC-No.: 217-175-6
Molecular Weight: 76.12
Chemical Formula: NH4SCN
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral Category 4 - H302
Acute toxicity, dermal Category 4 - H312
Skin corrosion/irritation Category 2 - H315
Acute toxicity, inhalation Category 4 - H332
Long-term (chronic) aquatic hazard Category 3 - H412

Hazard statements:
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
H412: Harmful to aquatic life with long lasting effects.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+ P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn = Harmful
Risk Phrase:
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: Ammonium Thiocyanate or Ammonium Rhodanide
CAS No.: 1762-95-4
EINECS EC-No.: 217-175-6

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Fire: Flash point: 190C.
Auto ignition temperature: High heat or direct flame is necessary to cause ignition.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Avoid solid stream of water since the stream will scatter and spread the fire. Water spray may be used to keep fire exposed containers cool. Carbon dioxide and carbon monoxide, Nitrogen oxides (NOx) Sulfur oxides Hydrogen cyanide (hydrocyanic acid) Ammonia will be formed on combustion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Mop up and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Pick up and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Finish cleaning by spreading water on the contaminated surface and dispose as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids. Hygroscopic and air sensitive.

Airborne Exposure Limits: OSHA PEL: (Vacated) TWA: 5 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): Use only under a chemical fume hood. For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White solid.
Odor: Odorless.
Odor threshold: Not available.
pH: 5 to 6.
Relative density: 1.3
Boiling Point: Not available.
Melting Point: 150C
Flash point: 190C
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Density (Air=1): Not available.
Vapor Pressure (mm Hg): Not available.
Evaporation Rate (BuAc=1): Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 76.12
Chemical Formula: NH4SCN

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide, Nitrogen oxides (NOx) Sulfur oxides Hydrogen cyanide (hydrocyanic acid) Ammonia may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Strong oxidizing agents, Strong acids, Forms shock-sensitive mixtures with certain other materials., Lead nitrate.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles. Avoid dust formation, Excess heat. Exposure to light and Exposure to moisture.

Oral rat LD50: 750 mg/kg
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSHA, NTP.

Toxicity to fish: static test LC50 - Oncorhynchus mykiss (rainbow trout) - 65 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 3,56 mg/l - 48 h.
Persistence and Degradability: Persistence is unlikely due to water solubility.
Mobility: Mobility likely due to water solubility.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

DOT USA & ADR/RID Europe & Canada TDG: Not regulated.
IMDG & IATA: Not regulated.

USA:
SARA 311/312: Acute health hazard. See section 2.
SARA 313 (TRI Reporting): None present, or none present in regulated quantities.
US California Proposition 65: No ingredient regulated by CA Prop 65 present.

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
H412: Harmful to aquatic life with long lasting effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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