Allyl Chloride or 3-Chloropropene or 3-Chloropropylene Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Allyl Chloride or 3-Chloropropylene, of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Allyl Chloride or 3-Chloropropene or 3-Chloropropylene: CAS Number: 107-05-1, EINECS EC Number: 203-457-6, Molecular Formula: C3H5Cl or CH2=CHCH2Cl, Molecular Weight: 76.52, HS Code 2903 29 00

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Allyl Chloride or 3-Chloropropene or 3-Chloropropylene.

Allyl chloride or 3-Chloropropene or 3-Chloropropylene is the organic compound with the formula CH2=CHCH2Cl. This colorless liquid is insoluble in water but soluble in common organic solvents. Allyl Chloride is used in preparation of allyl alcohol and other allyl derivatives, thermosetting resins for varnishes, plastics, adhesives, synthesis of pharmaceuticals glycerol and insecticides.

General Properties and Specifications of Allyl Chloride or 3-Chloropropene or 3-Chloropropylene:
CAS Number: 107-05-1
Appearance: Clear colorless liquid.
Odor: Unpleasant pungent
Relative density: around 0.94
Boiling point: 45C.
Melting point: -135C.
Flash point: -32C.
Autoignition Temperature: 390C.
Solubility: Practically insoluble in water. Miscible with alcohol, chloroform, ether, petrol ether.

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Allyl Chloride or 3-Chloropropene or 3-Chloropropylene SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

Product Name & Other Names: Allyl Chloride or 3-Chloropropene or 3-Chloropropylene.
CAS No.: 107-05-1
EINECS EC No.: 203-457-6
Molecular Formula: C3H5Cl or CH2=CHCH2Cl
Molecular Weight: 76.52
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids, Category 2, H225
Acute toxicity, Category 4, Oral, H302
Acute toxicity, Category 4, Dermal, H312
Acute toxicity, Category 4, Inhalation, H332
Skin irritation, Category 2, H315
Eye irritation, Category 2, H319
Germ cell mutagenicity, Category 2, H341
Carcinogenicity, Category 2, H351
Specific target organ toxicity - single exposure, Category 3, Respiratory system, H335
Specific target organ toxicity - repeated exposure, Category 2, Kidney, Liver, Nervous system, H373
Acute aquatic toxicity (Category 1) H400

Hazard statements:
H225: Highly flammable liquid and vapor.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Kidney, Liver, Nervous system) through prolonged or repeated exposure.
H400: Very toxic to aquatic life.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray or fog for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

According to European Directive 67/548/EEC as amended.
Hazard symbol(s):
F = Flammable.
T = Toxic.
Xi = Irritant.
Xn = Harmful.
N = Dangerous for the environment.
R-phrase(s):
R11 Highly flammable
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R40 Limited evidence of a carcinogenic effect
R48 Danger of serious damage to health by prolonged exposure
R50 Very toxic to aquatic organisms.
R68 Possible risk of irreversible effects

Product Name & Other Names: Allyl Chloride or 3-Chloropropene or 3-Chloropropylene.
CAS No.: 107-05-1
EINECS EC No.: 203-457-6

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable. Forms explosive mixtures with air at ambient temperatures.
Flash Points: -32C.
Auto-Ignition Temperature: 390C.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes & Hydrochloric Acid and fumes.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use water spray or fog. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Avoid a solid water jet on the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water spray to prevent pressure build-up, auto-ignition, or explosion.
Unsuitable extinguishing media: For this substance/mixture no limitations of extinguishing agents are given. However solid water jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures it may produce toxic or irritating fumes. Use water spray to cool unopened containers. Pay attention to flashback.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep up or swab the material without causing dust/mist. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Do not ingest. Do not breathe dust vapors or mist. Work under hood. Ensure proper ventilation. Provide appropriate exhaust ventilation at places where dust/mist is formed. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, alkali metals, alkaline earth metals, light metals, amides, amines, powdered metals. Keep away from open flames, hot surfaces, and sources of ignition. Take precautionary measures against static discharge.

Airborne Exposure Limits:
USA: ACGIH TLV(TWA): 1 ppm (skin)
ACGIH TLV(STEL): 2 ppm (skin)
OSHA PEL(TWA): 1 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear colorless liquid.
Odor: Unpleasant pungent.
Odor threshold: Not available.
pH: Not available.
Relative density: around 0.94
Boiling Point: 45C.
Melting Point: -135C.
Flash Point: -32C.
Auto-ignition Temperature: 390C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Practically insoluble in water. Miscible with alcohol, chloroform, ether, petrol ether.
Viscosity: Not available.
Molecular Formula: C3H5Cl or CH2=CHCH2Cl
Molecular Weight: 76.52

Stability: Stable under ordinary conditions of use and storage. Forms explosive mixtures with air at ambient temperatures.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide, Hydrochloric Acid, and fumes.
Hazardous Polymerization: May polymerize on exposure to heat, light or on contact with polymerization initiators such as peroxides etc.
Incompatibilities: Oxidizing agents, Alkali metals, Alkaline earth metals, Light metals, Amides, Amines, Powdered metals.
Conditions to Avoid: May polymerize on exposure to light. Exposure to moisture Exposure to air. Heat, flames, sunlight, air, static discharge, and sparks. Extremes of temperature and direct sunlight.

Toxicity data
Oral-Rat LD50: 450 mg kg-1
Dermal-Rabbit LD50: 2026 mg/kg.
Inhalation - Rat LC50: - 4 hr. 11 mg/l
Carcinogenicity: Suspected of causing cancer.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Mutagenicity: Suspected of causing genetic defects.
Neurotoxicity: No information found.
May cause damage to organs through prolonged or repeated exposure.

Toxicity to fish: LC50 Pimephales promelas (fathead minnow): 20 mg/l; 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 Daphnia magna (Water flea): 250 mg/l; 24 h.
Persistence and Degradability: Degradable.
Mobility: Will likely be mobile in the environment due to its volatility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

US DOT Classification:
UN Number: UN1100, Hazard Class: 3 (6.1), Packing Group: I
Shipping Name: ALLYL CHLORIDE
Canada TDG Classification:
UN Number: UN1100, Hazard Class: 3 (6.1), Packing Group: I
Shipping Name: ALLYL CHLORIDE
IATA & ADR/RID Europe
UN Number: UN1100, Hazard Class: 3 (6.1), Packing Group: I
Shipping Name: ALLYL CHLORIDE

USA:
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard, Chronic Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H225 Highly flammable liquid and vapor.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Kidney, Liver, Nervous system) through prolonged or repeated exposure.
H400 Very toxic to aquatic life.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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