Bentonite BP USP NF EP JP Manufacturers, with SDS GHS MSDS Sheet
Supplier, Manufacturer, Exporter of Bentonite, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.
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Bentonite: CAS Number: 1302-78-9, EINECS EC Number: 215-108-5, Molecular Formula: ---, Molecular Weight: ---, HS Code ---**
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SDS MSDS Sheet of Bentonite ManufacturersBentonite
BP USP NF EP JP Grade Suppliers
Bentonite BP
Ph Eur 1302-78-9DEFINITION
Natural clay containing a high proportion of montmorillonite, a native hydrated aluminium silicate in which some aluminium and silicon atoms may be replaced by other atoms such as magnesium and iron.CHARACTERS
Appearance: Very fine, homogeneous, greyish-white powder with a more or less yellowish or pinkish tint.
Solubility: Practically insoluble in water and in aqueous solutions. It swells with a little water forming a malleable mass.IDENTIFICATION
A. To 0.5 g in a metal crucible add 1 g of potassium nitrate and 3 g of sodium carbonate and heat until the mixture melts. Allow to cool. To this residue add 20 ml of boiling water, mix and filter. Wash the insoluble residue with 50 ml of water. To this residue add 1 ml of hydrochloric acid and 5 ml of water. Filter. To the filtrate add 1 ml of strong sodium hydroxide solution and filter. To this filtrate add 3 ml of ammonium chloride solution. A gelatinous white precipitate is formed.
B. Swelling power with water (see Tests).
C. 0.25 g gives the reaction of silicates.TESTS
Alkalinity: To 2 g add 100 ml of carbon dioxide-free water and shake for 5 min. To 5 ml of this suspension add 0.1 ml of thymolphthalein solution. The liquid becomes bluish. Add 0.1 ml of 0.1 M hydrochloric acid. The liquid is decolourised within 5 min.
Coarse particles: Maximum 0.5 per cent.
To 20 g add 1000 ml of water and mix for 15 min using a high-speed mixer capable of operating at not less than 5000 r/min. Transfer the suspension to a wet sieve (75), tared after drying at 100-105C. Wash with 3 quantities, each of 500 ml, of water, ensuring that any agglomerates have been dispersed. Dry the sieve at 100-105C and weigh. The particles on the sieve weigh a maximum of 0.1 g.
Sedimentation volume: To 6.0 g add 200 ml of water and mix for 20 min using a high-speed mixer capable of operating at 10000 r/min. Transfer 100 ml of this suspension to a graduated cylinder. Allow to stand for 24 h. The volume of the clear supernatant liquid is not greater than 2 ml.
Swelling power with water: Add 2.0 g in 20 portions to 100 ml of a 10 g/l solution of sodium laurilsulfate in a 100 ml graduated cylinder about 30 mm in diameter. Allow 2 min between additions for each portion to settle. Allow to stand for 2 h. The apparent volume of the sediment is not less than 22 ml.
Heavy metals: Maximum 50 ppm.
Loss on drying: Maximum 15 per cent, determined on 1.000 g by drying in an oven at 105C.
Microbial contamination: Total viable aerobic count not more than 103 micro-organisms per gram, determined by plate-count.
Bentonite USP NF
Bentonite [1302-78-9].
Bentonite is a native, colloidal, hydrated aluminum silicate.Identification: Add 2 g in small portions to 100 mL of water, with intense agitation. Allow to stand for 12 hours to ensure complete hydration. Place 2 mL of the mixture so obtained on a suitable glass slide, and allow to air-dry at room temperature to produce an oriented film. Place the slide in a vacuum desiccator over a free surface of ethylene glycol. Evacuate the desiccator, and close the stopcock so that the ethylene glycol saturates the desiccator chamber. Allow to stand for 12 hours. Record the Xray diffraction pattern, and calculate the d values: the largest peak corresponds to a d value between 15.0 and 17.2 angstrom units. Prepare a random powder specimen of Bentonite, record the X-ray diffraction pattern, and determine the d values in the region between 1.48 and 1.54 angstrom units: the peak is between 1.492 and 1.504 angstrom units.
Microbial limits: It meets the requirements of the test for absence of Escherichia coli.
pH: Disperse 4.0 g in 200 mL of water, mixing vigorously to facilitate wetting. The pH of this suspension is between 9.5 and 10.5.
Loss on drying: Dry it at 105C for 2 hours: it loses between 5.0% and 8.0% of its weight.
Arsenic: limit is 5 ppm.
Lead: (0.004%).
Gel formation: Mix 6 g with 300 mg of magnesium oxide. Add the mixture, in several divided portions, to 200 mL of water contained in a blender of approximately 500-mL capacity. Blend thoroughly for 5 minutes at high speed, transfer 100 mL of the mixture to a 100-mL graduated cylinder, and allow to remain undisturbed for 24 hours: not more than 2 mL of supernatant appears on the surface.
Swelling power: To 100 mL of water contained in a glass-stoppered cylinder of 100-mL capacity add 2 g in portions, dropping it upon the surface of the water and allowing each portion to settle before adding the next. The mass at the bottom gradually swells until it occupies an apparent volume of not less than 24 mL at the end of a 2-hour period.
Fineness of powder: Sprinkle 2 g upon 20 mL of water contained in a mortar. Allow to swell, disperse evenly with a pestle, and dilute with water to 100 mL. Pour the suspension through a No. 200 standard sieve, and wash the sieve thoroughly with water. No grit is felt when the fingers are rubbed over the wire mesh of the sieve.For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Bentonite SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 02-Oct-20Section 1: Chemical Product and Company Identification
Product Name & Other Names: Bentonite or Montmorillonite
CAS Number: 1302-78-9
Relevant Uses: Industrial and Laboratory use only.
Supplier: As per letterhead.Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
NONESignal Word: None
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.Section 3: Composition and Information on Ingredients
Product Name & Other Names: Bentonite or Montmorillonite
CAS Number: 1302-78-9
EINECS EC Number: 215-108-5
% by Weight: 95-100%Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt, or waistband.Section 5: Fire and Explosion Data
Flammability of the Product: Non flammable.
Products of Combustion: Aluminum oxide, silicon oxides.
Fire Hazards in Presence of Various Substances: Not available.
Risks of explosion of the product in presence of mechanical impact: Not available.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.Section 6: Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled material in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.Section 7: Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and acids.Section 8: Exposure Controls/Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.Section 9: Physical and Chemical Properties
Physical state and appearance: Beige or grayish solid.
Odor: Not available.
Odor threshold: Not available.
pH (1% soln/water): 6-9.
Relative density: around 2.4
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in cold water, hot water.
Viscosity: Not available.Section 10: Stability and Reactivity Data
Stability: It is stable.
Conditions of Instability: Excess heat, incompatible materials.
Incompatibility with various substances: Strong acids and strong oxidizing agents.
Special Remarks on Reactivity: Not available.
Polymerization: Will not occur.Section 11: Toxicological Information
Toxicity to Animals: LD50 Intravenous - rat - 35 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.Section 12: Ecological Information
Toxicity to fish LC50: Oncorhynchus mykiss (rainbow trout) - 19,000 mg/l - 96 h
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with environmental control regulations.
Section 14: Transport Information
DOT USA & ADR/RID Europe: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods.Section 15: Other Regulatory Information
USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Sec: 313.
SARA 311/312 Hazards: Chronic Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.16. Other Information
Disclaimer:
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Our company provides this Bentonite SDS MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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