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Calcium Chloride Hexahydrate & Solution SDS MSDS Sheet
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Calcium Chloride BP USP ACS Analytical Reagent Food Grade
Calcium Chloride Anhydrous Fused Dihydrate Hexahydrate Solution IP Grade Manufacturers Specifications & Uses
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CaCl2 Anhydrous MSDS Sheet
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CaCl2 Hexahydrate Solution MSDS Sheet
Calcium Chloride Hexahydrate or Solution SDS MSDS, Material Safety Data Sheet
1. Product Identification
Synonyms: Calcium Dichloride Hexahydrate; Calcium Di Chloride Hexahydrate
CAS No.: 7774-34-7
EINECS EC Number: 233-140-8
Molecular Weight: 210.08
Chemical Formula: CaCl2.6H2O (Calcium Chloride Hexahydrate) (Solution will have more water)
Relevant Uses: Industrial use only.
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Skin irritation Category 2
Serious eye damage/eye irritation Category 2A
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Words: Warning
H315: Causes skin irritation.
H319: Causes serious eye irritation.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Risk Phrases: R36/38- Irritating to eyes and skin..
For the full text of the S-statements R-phrases mentioned in this Section, see Section 16.
3. Composition/Information on Ingredients
Ingredient: Calcium Chloride Hexahydrate
CAS No.: 7774-34-7
EINECS EC Number: 233-140-8
Percent: 97 - 100% (Solution will have more water)
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire: Calcium Chloride Hexahydrate is not considered to be a fire hazard.
Explosion: Calcium Chloride Hexahydrate is not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
6. Accidental Release Measures
Small Spill: Ensure adequate ventilation. Use appropriate tools to put the spilled material in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.
7. Handling and Storage
Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation. If you feel unwell, seek medical attention.
Keep Calcium Chloride Hexahydrate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist calcium chloride and concentrated solutions can corrode steel. When exposed to the atmosphere, it will absorb water and form a solution.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Deposits on floors and other surfaces may cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Calcium Chloride Hexahydrate is white crystals or powder or granules.
Odor: It is odorless.
Solubility: It is freely soluble in water.
pH: 5.0 - 9 at 10% solution at 25C (77F)
Density: 1.50 g/cm3 as liquid at 30C.
Molecular formula: CaCl2•6H2O
Molecular weight: 210.08
% Volatiles by volume @ 21C (70F): 0
Boiling Point: > 1600C (> 2912F) (Solution will have different B.P.)
Melting Point: 29C (84F) for Calcium Chloride Hexahydrate. (Solution will have different M.P.)
10. Stability and Reactivity
Stability: Calcium Chloride Hexahydrate is stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.
Hazardous Decomposition Products: It emits toxic chlorine fumes when heated to decomposition. It may form hydrogen chloride in presence of sulfuric or phosphoric acids or with water at elevated temperatures.
Hazardous Polymerization: Will not occur.
Incompatibilities: Methyl vinyl ether, water, zinc, bromine trifluoride, mixtures of lime and boric acid, barium chloride, and 2-furan percarboxylic acid. Metals will slowly corrode in aqueous calcium chloride solutions. Aluminum (and alloys) and yellow brass will be attacked by calcium chloride.
Conditions to Avoid: Incompatibles.
11. Toxicological Information
Toxicity to Animals: Oral rat LD50: 2301 mg/kg on Anhydrous CaCl2 basis.
Acute toxicity: Not classified
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: Not classified
Symptoms/injuries after inhalation: EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Slight irritation. Runny nose.
Symptoms/injuries after skin contact: Slight irritation.
Symptoms/injuries after eye contact: Irritation of the eye tissue. Visual disturbances.
12. Ecological Information
Environmental Fate: Based on available information Calcium Chloride Hexahydrate will not biodegrade or bio accumulate.
Environmental Toxicity: The material is not considered as environmental hazard.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
14. Transport Information
DOT: Not regulated.
IMDG: Not regulated.
IATA: Not regulated.
Canada TDG hazard class: Not regulated.
Europe ADR/RID hazard class: Not regulated.
ICAO/IATA (air) hazard class: Not regulated.
15. Regulatory Information
OSHA Hazards: Irritant
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold reporting levels.
SARA 311/312 Hazards: Acute Health Hazard
Massachusetts Right To Know Components: No Components Listed
Pennsylvania Right To Know Components: Calcium Chloride; CAS-No.: 10035-04-8
New Jersey Right To Know Components: Calcium Chloride; CAS-No.: 10035-04-8
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
TSCA: CAS# 10035-04-8 is not on the TSCA Inventory because it is a hydrate.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
HMIS (Perceived): Health Hazard: 2; Fire Hazard: 0; Reactivity: 0; Personal Protection: E
NFPA (Perceived): Health: 2; Flammability: 0; Reactivity: 0
Canada - DSL/NDSL: CAS# 10043-52-4 is listed on Canada's DSL List.
WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
EINECS EC Number: 233-140-8
H315: Causes skin irritation.
H319: Causes serious eye irritation.
R36/38- Irritating to eyes and skin..
Safety Phrases: R36/37/38- Irritating to eyes, respiratory system and skin. S22- Do not breathe dust. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Last 25 March, 2017
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