Copper Sulfate, Copper Sulfate Anhydrous SDS, MSDS Sheet

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Copper Sulphate Anhydrous or Cupric Sulfate Anhydrous SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 02-Dec-20

Product Name & Other Names: Copper Sulphate Anhydrous or Cupric Sulfate Anhydrous.
CAS No.: 7758-98-7 (anhydrous).
EINECS EC Number: 231-847-6
Molecular Weight: 159.62
Chemical Formula: CuSO4
Relevant uses and uses advised against (if any): Industrial Manufacturing
SUPPLIER: As per Letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, oral Category 4, H302

Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Hazardous to the aquatic environment, long-term hazard Category 1, H410

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store in a closed container.
P501 Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
Xi Irritant
N Dangerous for the environment
Risk Phrase:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: Copper Sulphate Anhydrous or Cupric Sulfate Anhydrous.
CAS No.: 7758-98-7 (anhydrous).
EINECS EC Number: 231-847-6

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Contact a poison control center or physician for treatment advice. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Products of Combustion: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Fire: Copper Chloride is not considered to be a fire hazard.
Explosion: Copper Sulfate is Slightly explosive in presence of heat & Metals.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. Material is acidic when dissolved in water, contact with magnesium metal may evolve hydrogen gas. Anhydrous salt will ignite hydroxylamine if present.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Danger! Very harmful if swallowed. Do not ingest.
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alkalis, hydroxylamine, magnesium, hydrazine, nitromethane.

Airborne Exposure Limits: Permissible 1 mg/m3 TWA (dust and mist, as Cu, except copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.). 0.2 mg/m3 TWA (fume).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Light-grey powder or crystals.
Odor: It is odorless.
Odor threshold: Not available.
pH: 3.7-4.2 for 10% solution.
Relative density: around 2.28
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is freely soluble in water.
Viscosity: Not available.
Molecular Weight: 159.62
Molecular Formula: CuSO4

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of sulfur, irritating and toxic fumes and gases, oxides of copper, copper fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Metals & alkalis. Avoid hydroxylamine, magnesium, hydrazine, nitromethane.
Conditions to Avoid: Incompatibles and moisture. Avoid Heat, Moisture & incompatibles.

Acute toxicity
Acute toxicity is largely due to the corrosive (acidic) properties of this material. Very harmful if swallowed. Product is an eye, skin irritant and may cause burns. Product is a respiratory tract irritant, and inhalation may cause nose irritation, sore throat, coughing, and chest tightness and possibly, ulceration and perforation of the nasal septum. Chronic overexposure to this product may cause liver and kidney damage, anemia, and other blood cell abnormalities.
Toxicity data
ORL-RAT LD50 ----- 300mg kg-1
ORL-MOUSE LD50 - 369 mg kg-1
Carcinogenic Effects: Not known to be a carcinogen.
Mutagenic Effects: Mutagenic for mammalian somatic cells. May cause damage to the following organs: kidneys, liver.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Environmental Fate: When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater. When released into water, this material is not expected to biodegrade. When released into water, this material is not expected to evaporate significantly. This material is expected to significantly bioaccumulate.
Environmental Toxicity: Toxicity data for copper. This material is expected to be very toxic to aquatic life. The LC50/96-hour values for fish are less than 1 mg/l. The IC50/72-hour values for algae are less than 1 mg/l.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0.024 mg/l - 48 h
48 Hr. EC50 water flea: 0.024 mg/L
96 Hr. LC50 rainbow trout: 0.1 mg/L;
48 Hr. LC50 bluegill: 0.6 mg/L;
96 Hr. LC50 goldfish: 0.1 mg/L
BOD5 and COD: Not available.

This product is a registered pesticide. Pesticide wastes are acutely hazardous. Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe:
UN-Number: UN 3077
Shipping Name: Cupric Sulfate Anhydrous
CLASS 9; Packing group: III
IATA/ICAO:
UN-Number: UN 3077
Shipping Name: Cupric Sulfate Anhydrous, Environmentally Hazardous Substance, solid, n.o.s.
CLASS 9 (Miscellaneous Dangerous Goods); Packing group: III
IMDG/IMO:
UN-Number: UN 3077
Shipping Name: Cupric Sulfate Anhydrous, Environmentally Hazardous Substance, solid, n.o.s.
CLASS 9 (Miscellaneous Dangerous Goods); Packing group: III

USA:
SARA 302 Components: Not subject to the reporting requirements of SARA Title III, Sec. 302.
SARA 313 Components: This material contains Cupric sulfate pentahydrate (Copper compounds), (CAS# 7758-99-8) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Immediate Health Hazard, Chronic Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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