EDTA, Edetic Acid SDS, MSDS Sheet

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EDTA or Edetic Acid SDS, Safety Data Sheet
Ethylenediaminetetraacetic acid MSDS Sheet, Material Safety Data Sheet
02-Dec-20

Product Name & Other Names: EDTA or Edetic acid or Versene acid or Ethylenediaminetetraacetic acid.
CAS Number: 60-00-4
EINECS EC Number: 200-449-4
Molecular Weight: 292.24
Chemical Formula: (HOCOCH2)2NCH2CH2N- (HOCOCH2)2
Relevant uses and uses advised against (if any): For Industrial use only.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 5, H303
Serious eye damage/eye irritation Category 1, H319
Hazardous to the aquatic environment, acute hazard Category 3 H402

Hazard statements:
H303: May be harmful if swallowed
H319: Causes serious eye irritation.
H402: Harmful to aquatic life.

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May cause mild respiratory irritation.
Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P330: Rinse mouth.
P270: Do not eat, drink, or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352-IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to comply with local, state, and federal regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrase:
R36 Irritating to eyes.

3. Composition/Information on Ingredients
Product Name & Other Names: EDTA or Edetic acid or Versene acid or Ethylenediaminetetraacetic acid.
CAS Number: 60-00-4
EINECS EC Number: 200-449-4

Always seek medical advice after the first aid treatment.
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. Get Medical advice.
Ingestion: Give several glasses of water to drink to dilute the effect and get medical advice.
Skin Contact: Remove any contaminated clothing and shoes. Wash soap or mild detergent and water for at least 15 minutes. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention.

Fire: Not considered to be a fire hazard. However, it can burn at high temperatures.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong bases, aluminum, copper, copper alloys, nickel.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: EDTA is white crystals.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 0.9
Melting Point: 250C (483F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 0.05 g/100 ml @ 20C (68F)
Viscosity: Not available.
Molecular Weight: 292.24
Chemical Formula: (HOCOCH2)2NCH2CH2N- (HOCOCH2)2

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, strong bases, aluminum, copper, copper alloys, nickel.
Conditions to Avoid: Incompatibles, heat and sunlight.

Oral LD50 Rat: >2000 mg/kg.
Dermal LD50 Rabbit: >5000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Environmental Fate: When released into the soil, it is expected to leach into groundwater. When released into the soil, this material may biodegrade to a moderate extent. When released into the soil, this material is not expected to evaporate significantly. When released into water, this material is not expected to evaporate significantly. This material is not expected to significantly bio accumulate. When released into the air, this material is expected to be readily degraded by photolysis.
Environmental Toxicity:
24 Hr LC50 rainbow trout: 340 mg/L;
96 Hr LC50 bluegill sunfish:486 mg/L;
96 Hr LC50 channel catfish: 129 mg/L.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused EDTA or Edetic Acid in accordance with legal requirements.

DOT USA, TDG Canada & ADR/RID Europe:
Not Regulated.
IMDG/IMO:
Not Regulated.
IATA/ICAO:
Not Regulated.

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives
H303 May be harmful if swallowed
H319: Causes serious eye irritation.
H402 Harmful to aquatic life.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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