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Copper Sulfate, Copper Sulfate Pentahydrate SDS MSDS Sheet

For MSDS Sheet Click
MSDS of Copper sulfate, Copper sulphate anhydrous Manufacturers

MSDS of Copper sulphate Copper sulphate pentahydrate manufacturers

Specifications of Copper sulphate Copper sulfate Manufacturers

Copper Cupric Sulfate Pentahydrate SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Copper (II) Sulfate Pentahydrate (1:1:5); blue vitriol; Sulfuric acid copper (2+) salt (1:1), Pentahydrate
CAS No.: 7758-99-8
EINECS EC Number: 231-847-6
Molecular Weight: 249.69
Chemical Formula: CuSO4-5H2O
Intended Use: Industrial Manufacturing
SUPPLIER: As per Letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 3
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Hazardous to the aquatic environment, long-term hazard Category 1

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Toxic
Toxic

Signal Words: Danger

Hazard statements:
H301 Toxic if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store in a closed container.
P501 Dispose of contents/ container to an approved waste disposal plant

OSHA Hazards: Target organ effect, toxic by ingestion, Irritant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22
Xi Irritant R36/38
N Dangerous for the environment
R50/53
For the full text of the H-Statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Copper Sulfate
CAS No.: 7758-99-8
EINECS EC Number: 231-847-6
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Contact a poison control center or physician for treatment advice. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Fire: Copper Chloride is not considered to be a fire hazard.
Explosion: Copper Sulfate is Slightly explosive in presence of heat & Metals.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Material is acidic when dissolved in water, contact with magnesium metal may evolve hydrogen gas. Anhydrous cupric sulfate formed on water loss (white color). Anhydrous salt will ignite hydroxylamine, if present.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Cupric sulfate is a corrosive solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Danger! Toxic & Fatal if swallowed. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Copper Sulphate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Permissible 1 mg/m3 TWA (dust and mist, as Cu, except copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.). 0.2 mg/m3 TWA (fume).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Cupric Sulfate is transparent blue powder or crystals.
Odor: It is odorless.
Solubility: It is freely soluble in water.
pH: 3.7-4.2 for 10% solution.
Density: 2.28 g/mL at 16C
Molecular formula
: CuSO4-5H2O
Molecular weight: 249.69
% Volatiles by volume @ 21C (70F): -
Boiling Point: Loses water of crystallization above 110C
Melting Point: Starts losing water @ 110C decomposes

10. Stability and Reactivity

Stability: Cupric Sulphate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of sulfur, irritating and toxic fumes and gases, oxides of copper, copper fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Metals & alkalies. Avoid hydroxylamine, magnesium, hydrazine, nitromethane.
Conditions to Avoid: Incompatibles and moisture. Avoid Heat, Moisture & incompatibles

11. Toxicological Information

Acute toxicity
Acute toxicity is largely due to the corrosive (acidic) properties of this material. Harmful or fatal if swallowed. Product is an eye and skin irritant, and may cause burns. Product is a respiratory tract irritant, and inhalation may cause nose irritation, sore throat, coughing, and chest tightness and possibly, ulceration and perforation of the nasal septum. Chronic overexposure to this product may cause liver and kidney damage, anemia and other blood cell abnormalities.
Toxicity data
ORL-RAT LD50 ----- 300mg kg-1
ORL-MOUSE LD50 - 369 mg kg-1
Carcinogenic Effects: Not known to be a carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Mutagenic for mammalian somatic cells. May cause damage to the following organs: kidneys, liver.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Environmental Fate: When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater. When released into water, this material is not expected to biodegrade. When released into water, this material is not expected to evaporate significantly. This material is expected to significantly bioaccumulate.
Environmental Toxicity: Toxicity data for copper. This material is expected to be very toxic to aquatic life. The LC50/96-hour values for fish are less than 1 mg/l. The IC50/72-hour values for algae are less than 1 mg/l.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0.024 mg/l - 48 h
48 Hr EC50 water flea: 0.024 mg/L
96 Hr LC50 rainbow trout: 0.1 mg/L;
48 Hr LC50 bluegill: 0.6 mg/L;
96 Hr LC50 goldfish: 0.1 mg/L
BOD5 and COD: Not available.

13. Disposal Considerations

This product is a registered pesticide. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticides, spray mixtures, or rinsate is a violation of Law. Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
UN-Number: UN 3077
Shipping Name: Cupric Sulfate
CLASS 9
Packing group: III
Canada TDG Classification:
UN-Number: UN 9109
Shipping Name: Cupric Sulfate
CLASS 9.2
Packing group: II
IATA
UN-Number: UN 3077
Shipping Name: Cupric Sulfate, Environmentally Hazardous Substance, solid, n.o.s.
CLASS 9 (Miscellaneous Dangerous Goods)
Packing group: III
Identification: 8(Corrosive)
ADR/RID:
UN-Number: UN 3077
Shipping Name: Cupric Sulfate, Environmentally Hazardous Substance, solid, n.o.s.
CLASS 9 (Miscellaneous Dangerous Goods)
Packing group: III
Identification: 8(Corrosive)
Marine Pollutant: This material is considered a marine pollutant by the IMO.

15. Regulatory Information

USA:
OSHA Hazards
: Hazardous
TSCA: CAS# 7758-99-8 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA Codes: CAS # 7758-99-8: immediate, delayed. CAS # 7758-98-7: immediate..
SARA 313 Components: This material contains Cupric sulfate pentahydrate (Copper  compounds), (CAS# 7758-99-8) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Immediate Health Hazard, Chronic Health Hazard.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: CAS# 7758-98-7: 10 lb final RQ; 4.54 kg final RQ
Massachusetts Right To Know Components: Listed
Pennsylvania Right To Know Components: Listed
New Jersey Right To Know Components: Listed
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act: Copper Sulfate Pentahydrate is listed as a Priority and Toxic Pollutant under the Clean Water Act.
WGK (Water Danger/Protection): CAS# 7758-99-8: 2; CAS# 7758-98-7: 2

Canada - DSL/NDSL: CAS# 7758-98-7 is listed on Canada's DSL List.
Canada - WHMIS: CLASS D-1B, D2B.
Canadian Ingredient Disclosure List: CAS# 7758-99-8 (listed as Copper compounds, n.o.s.) is listed on the Canadian Ingredient Disclosure List. CAS# 7758-98-7 is listed on the Canadian Ingredient Disclosure List.

16. Other Information

EINECS EC Number: 231-847-6
Full text of H-Statements:
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Full text of R-phrases:
N Dangerous for the environment
Xn Harmful
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases: S 22 Do not breathe dust. S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Contact

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Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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Last 21 August, 2017

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