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Copper Cupric Chloride Anhydrous SDS MSDS Sheet

Copper Cupric Chloride Dihydrate Anhydrous Manufacturers

Cupric Chloride Anhydrous MSDS

Cupric Chloride Dihydrate MSDS

Copper Chloride Solution MSDS

Copper or Cupric Chloride Anhydrous SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification                      

Synonyms: Coppertrace; Copper (2+) chloride anhydrous
CAS No.: 7447-39-4
Molecular Weight: 134.45
Chemical Formula: CuCl2
Intended Use: Industrial Manufacturing
SUPPLIER: As per Letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral Category 4
Skin irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3
Hazardous to the aquatic environment, long-term hazard Category 2

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
Corrosive
Corrosive

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H411: Toxic to aquatic life with long lasting effects.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P501: Dispose of contents/ container to an approved waste disposal plant.

OSHA Hazards: Hazardous. Harmful by ingestion., Irritant.
Target Organs: Liver, Nerves., Kidney, Lungs

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn N
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Cupric Chloride
CAS No.: 7447-39-4
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire: Copper Chloride is not considered to be a fire hazard.
Explosion: Copper Chloride is Slightly explosive in presence of heat & Metals.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen chloride. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Cupric chloride is a corrosive solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Toxic! Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Copper Chloride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Permissible 1 mg/m3 TWA (dust and mist, as Cu, except copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.).
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Cupric Chloride is fine brown powder or crystals.
Odor: It is odorless.
Solubility: It is soluble in water.
pH: 3.
Density: 3.38 g/mL at 20C (68F)
Molecular formula
: CuCl2
Molecular weight: 134.45
% Volatiles by volume @ 21C (70F): -
Boiling Point: 993C
Melting Point: 620C (Variously reported in literature)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Hygroscopic. Cupric Chloride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic chlorine or hydrogen chloride fumes when heated to decomposition. It may form cupric oxide and hydrogen chloride and chlorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, metals & acids. Also incompatible with potassium, sodium, hydrazine, nitromethane, acetylene, sodium hypobromite.
Conditions to Avoid
: Incompatibles and moisture.

11. Toxicological Information

Acute toxicity
Toxic if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled.
Toxicity data
CAS# 7447-39-4
Oral, mouse: LD50 = 233 mg/kg;
Oral, rat: LD50 = 584 mg/kg;
Oral, rat: LD50 = 140 mg/kg;
Carcinogenic Effects: Not known to be a carcinogen.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, lungs, liver, skin.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Environmental Fate: Not available.
Environmental Toxicity: It is also toxic to fish. Harmful to aquatic life in very low concentrations. Copper Chloride Anhydrous is toxic to fish and marine organisms when applied to streams, rivers, ponds or lakes.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
UN-Number: UN 2802
Shipping Name: Copper Chloride
CLASS 8, Packing group: III, Identification: 8(Corrosive)
Canada TDG Classification:
UN-Number: UN 2802
Shipping Name: Copper Chloride
CLASS 8, Packing group: III, Identification: 8(Corrosive)
IATA
UN-Number: UN 2802
Shipping Name: Copper Chloride
CLASS 8, Packing group: III, Identification: 8(Corrosive)
IMDG
UN number: 2802
Class: 8, Packing group: III, EMS-No: F-A, S-B
Proper shipping name: COPPER CHLORIDE
Marine pollutant: Marine pollutant.
RID/ADR
UN number: 2802
Class: 8, Packing group: III,
Proper shipping name: COPPER CHLORIDE

15. Regulatory Information

USA:
OSHA Hazards
: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
TSCA: Listed.
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA Codes: CAS # 7447-39-4: immediate, delayed.
SARA 313 Components: This material contains Cupric chloride (Copper  compounds),  (CAS# 7447-39-4) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Component CAS # 7447-39-4 Fire Hazard: No, Reactivity Hazard: No, Pressure Hazard: No, Immediate Health Hazard: Yes, Chronic Health Hazard: Yes
Health & Safety Reporting List: Listed
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: CAS# 7447-39-4: 10 lb final RQ; 4.54 kg final RQ
Massachusetts Right To Know Components: Listed
Pennsylvania Right To Know Components: Listed
New Jersey Right To Know Components: Listed
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
Copper Chloride Anhydrous (CAS # 7447-39-4) is listed as a Priority and Toxic Pollutant under the Clean Water Act.
CAS# 7447-39-4 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 7447-39-4is listed as a Toxic Pollutant under the Clean Water Act. CAS# 7447-39-4 is listed as a Toxic Pollutant under the Clean Water Act.
WGK (Water Danger/Protection): CAS# 7447-39-4: 2

Canada - DSL/NDSL: CAS# 7447-39-4 is listed on Canada's DSL List.
Canada - WHMIS
: CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS E: Corrosive solid.
Canadian Ingredient Disclosure List: CAS# 7447-39-4 is listed on Canada's DSL List.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
EINECS EC Number: 231-210-2
Hazard Symbols: Xn = Harmful; N = Dangerous for the environment
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
H302 = Harmful if swallowed.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
H411 = Toxic to aquatic life with long lasting effects.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Last 21 August, 2017

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