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Calcium Propionate Propionate MSDS Sheet
Calcium Propionate Manufacturers Specifications
Calcium Propionate Manufacturers
MSDS of Calcium Propionate Manufacturers
Calcium Propionate MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Propionic acid, calcium salt; Calcium dipropionate.
CAS No.: 4075-81-4
Molecular Weight: 186.22
Chemical Formula: (CH3CH2COO)2Ca
2. Composition/Information on Ingredients
Ingredient: Calcium Propionate
CAS No.: 4075-81-4
Percent: 97 - 100%
3. Hazards Identification
Not Hazardous as per OSHA
Health hazard: 2
Reactivity Hazard: 0
Physical hazards: E
Health hazard: 2
Reactivity Hazard: 0
Contact Rating: 3 - Severe
Protective Equip: Goggles, Lab Coat.
WARNING! May cause digestive tract, respiratory tract irritation and skin irritation.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause irritation.
Ingestion: May cause irritation to digestive tract. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause irritation to respiratory tract. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Chronic: No information found.
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Fumes, Calcium Oxide Carbon dioxide & Carbon Monoxide.
Fire: Calcium Propionate is slightly flammable on heating.
Explosion: Slightly explosive on heating.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit carbon monoxide. Containers may explode on heating
6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.
7. Handling and Storage
Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Calcium Propionate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Not Specified.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Calcium Propionate is colorless white powder or crystals.
Odor: It is odorless.
Solubility: It is soluble in water.
Density: 3.13 g/mL at 20C (68F)
Molecular formula: (CH3CH2COO)2Ca
Molecular weight: 186.2
% Volatile by volume @ 21C (70F): -
Boiling Point: NA
Melting Point: 681C 1257F
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
10. Stability and Reactivity
Stability: Calcium Propionate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form calcium oxide harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Incompatibles and moisture.
11. Toxicological Information
Harmful if swallowed. Harmful if inhaled. Irritating to skin.
ORL-RAT LD50 3290 mg kg-1
ORL-MAM LD50 2350 mg kg-1
Routes of Entry: Inhalation. Ingestion.
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: Not known to be a carcinogen.
Mutagenic Effects: NA
Developmental Toxicity: NA.
12. Ecological Information
Environmental Fate: Not classified as environmentally hazardous.
Environmental Toxicity: This chemical is expected to cause little oxygen depletion in aquatic systems.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation and the product are not classed as toxic.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
US DOT Classification:
Canada TDG Classification:
15. Regulatory Information
Not Hazardous as per OSHA
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
No chemicals in this material are subject to the reporting requirements
SARA 311/312 Hazards
Fire Hazard: -
Reactivity Hazard: -
Pressure Hazard: -
Immediate Health Hazard: -
Chronic Health Hazard: -
Massachusetts Right To Know Components
Pennsylvania Right To Know Components
New Jersey Right To Know Components
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
EINECS: EC Number: 223-795-8
WGK (Water Danger/Protection)
CAS# 4075-81-4: 1
Canada - DSL/NDSL
CAS# 4075-81-4 is listed on Canada's DSL List.
Canada - WHMIS
Canadian Ingredient Disclosure List
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
R36- Irritating to eyes.
S24/25- Avoid contact with skin and eyes.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Health Hazard: 2
Fire Hazard: 1
Personal Protection: E
National Fire Protection Association (U.S.A.):
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.
Australian Hazchem Code: -
Poison Schedule: -
16. Other Information
Our company provides this Calcium Propionate MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Calcium Propionate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Last 25 February, 2016
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