Hydrobromic Acid or Hydrogen bromide Solution in Acetic Acid Manufacturers, SDS GHS, MSDS Sheet

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Hydrobromic Acid Solution in acetic Acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 03-Dec-20

Product Name & Other Names: Hydrobromic acid solution in acetic Acid or Hydrogen bromide solution in acetic acid.
Relevant identified uses of the substance or mixture and uses advised against: Laboratory chemicals, Manufacture of substances. For Industrial use.
Details of the supplier of the safety data sheet: As per letter head.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 4 H227
Corrosive to Metals Category 1 H290
Skin corrosion/irritation Category 1A, B, C H314
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335

Hazard statements:
H227: Combustible liquid.
H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340+P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide for extinction.
P403+235: Store in a well ventilated place. Keep cool.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
C Corrosive.
Xn Harmful.
Risk Phrases:
R30 Can become highly flammable in use
R35 Causes severe burns.
R41 Risk of serious damage to eyes.
R42 May cause sensitization by inhalation.

Product Name & Other Names: Hydrobromic acid solution in acetic Acid or Hydrogen bromide solution in acetic acid.

Ingredient 1: Hydrobromic Acid or Hydrogen bromide
CAS No.: 10035-10-6
EINECS EC Number: 233-113-0
Percent: 30% - 40%
Ingredient 2: Glacial acetic acid
CAS No.: 64-19-7
EINECS EC Number: 200-580-7
Percent: 60% - 70%

Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eye with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before reuse..
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to and unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Medical Conditions generally Aggravated by Exposure: Repeated exposure of the eyes can produce eye irritation. Inhalation can produce respiratory irritation or sensitization.

Fire Extinguishing Media: Adapt extinguishing media to the environment. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unusual Fire and Explosion Hazards: Flammable hydrogen gas may be produced on prolong contact with metals such as aluminum, tin lead and zinc.
Hazardous combustion products: Hydrogen bromide, carbon oxides and toxic fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Steps to be Taken in Case Material is Released or Spilled: Evacuate the area of all unnecessary personnel. Wear suitable protective equipment. Contain the release and eliminate its source, if this can be done without risk. Take up and containerize for proper disposal. Comply with local, state and Federal regulations on reporting releases.
Methods for cleaning up: Take up liquid spill into absorbent material, e.g.: dry sand/earth or powdered limestone. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Small quantities of liquid spill may be neutralized with alkali solution. Wash away neutralized product with plentiful water. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.
Waste Disposal Methods: Do not let product enter drains. Dispose of waste according to Federal, State and Local Regulations.

Avoid contact with skin and eyes. Avoid inhalation of vapors or mist. Keep in a tightly closed original container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat and incompatibilities. Containers may be hazardous when empty since they retain product residues; observe all warnings and precautions listed for the product. Air and light sensitive.

Components with workplace control parameters
USA ACGIH TLV: 2 ppm (The lowest for Hydrobromic Acid).
USA OSHA PEL: 3 ppm Vacated (The lowest for Hydrobromic Acid).
USA ACGIH TLV: 10 ppm (For Acetic Acid).
USA OSHA PEL: 10 ppm Vacated (For Acetic Acid).
Engineering Controls Ventilation required: It should be handled or transferred in an approved fume hood or with adequate ventilation.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance and Physical State: Colorless to light yellow liquid.
Odor (threshold): Pungent.
Odor threshold: Not available.
pH: Highly acidic.
Relative density: around 1.4
Melting Point: -11C literature.
Boiling Point: <200C literature.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility in Water: Soluble
Viscosity: Not available.

Stability: It is stable under ordinary conditions of use and storage.
Reactivity: Reacts with metals to release hydrogen.
Materials to Avoid (Incompatibility): Strong oxidizing agents, Strong bases, Ammonia, Ozone, Fluorine, Powdered metals. Light sensitive. Air sensitive. Heat sensitive.
Hazardous Decomposition Products: Thermal decomposition may produce hydrogen bromide, carbon oxides and toxic fumes.
Hazardous Polymerization: Will not occur.

Results of component toxicity test:
Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Carcinogenicity: This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Mutagenic Effects: No information available.
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Toxicity to fish: No information available for the product.
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No information available.

State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.

USA DOT & ADR/RID:
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Hydrobromic acid, Acetic acid)
Hazard Class: 8, Packaging group: II,
UN Number: UN3265
IATA:
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Hydrobromic acid, Acetic acid)
Hazard Class: 8, Packaging group: II
UN Number: UN3265
IMO:
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Hydrobromic acid, Acetic acid)
Hazard Class: 8, Packaging group: II
UN Number: UN3265

USA:
SARA Section 311/312 Hazard Classes: Immediate (acute) health hazard. See section 2.
SARA 302 Extremely Hazardous Substance: None present or none present in regulated quantities.
SARA 313: None present or none present in regulated quantities.
California Proposition 65: None.

European Labeling in Accordance with EC Directives:
H227: Combustible liquid.
H290: May be corrosive to metals
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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