Urea SDS, MSDS Sheet

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Product Name & Other Names: Urea, Carbamide resin or Isourea or Carbonyl diamide or Carbonyldiamine.
CAS No.: 57-13-6
EINECS EC Number: 200-315-5
Molecular Weight: 60.06
Chemical Formula: (NH2)2CO
Relevant uses and uses advised against (if any): Industrial use.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name & Other Names: Urea, Carbamide resin or Isourea or Carbonyl diamide or Carbonyldiamine.
CAS No.: 57-13-6
EINECS EC Number: 200-315-5

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wash affected areas with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if symptoms occur.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire: Not considered to be a fire hazard.
Explosion: Reactions with incompatibles may pose an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Vacuum or sweep up and remove to an approved disposal container.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Urea will absorb moisture from air. Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like sodium nitrite, gallium perchlorate, strong oxidizing agents (permanganate, dichromate, nitrate, chlorine), phosphorus pentachloride, nitrosyl perchlorate, titanium tetrachloride and chromyl chloride. Reacts with hypo chlorites to form nitrogen trichloride, which explodes spontaneously in air. Reacts with nitric acid to form urea nitrate that decomposes explosively when heated. Containers of Urea may be hazardous when empty.

Airborne Exposure Limits:
AIHA Workplace Environmental Exposure Limit (WEEL): 10 mg/m3, 8-hour TWA
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the Urea exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If heat is involved, an ammonia/methylamine, dust/mist cartridge may be necessary.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection:: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Urea is white crystals or white powder.
Odor: Develops odor of ammonia.
Odor: Not available.
Odor threshold: Not available.
pH: 7.2 (10% in water)
Relative density: 1.32.
Boiling Point: Decomposes.
Melting Point: 132 - 135C (270 - 275F)
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very soluble in water.
Viscosity: Not available.
Molecular Weight: 60.06
Chemical Formula: (NH2)2CO

Stability: Urea is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Urea decomposes upon heating and can form products including ammonia, oxides of nitrogen, cyanuric acid, cyanic acid, biuret, carbon dioxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Urea reacts with calcium hypochlorite or sodium hypochlorite to form the explosive nitrogen trichloride. It is incompatible with sodium nitrite, gallium perchlorate, strong oxidizing agents (permanganate, dichromate, nitrate, chlorine), phosphorus pentachloride, nitrosyl perchlorate, titanium tetrachloride and chromyl chloride.

Urea Oral rat LD50: 8471 mg/kg. Investigated as a tumorigen, mutagen, reproductive effector.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: LC50 - Poecilia reticulata (guppy) - 17,500 mg/l - 96 h(Urea)
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 3,910 mg/l - 48 h(Urea)
Environmental Fate: When released to soil, Urea will hydrolyze into ammonium in a matter of days to several weeks. When released into the soil, this material may leach into groundwater. When released into water, this material may biodegrade to a moderate extent. This material is not expected to significantly bio-accumulate.
Environmental Toxicity: Urea can be toxic to domestic animals and has caused poisonings when it was applied unevenly on pastures as a fertilizer. Large amounts of urea can damage plant seedlings and inhibit germination. At high concentrations, urea can be toxic to aquatic life.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Urea is not considered a hazardous waste under USA Federal Hazardous Waste Regulations 40 CFR 261. Follow standard disposal procedures. Dispose of container of Urea and unused contents in accordance with legal requirements.

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO & IATA/ICAO: Not dangerous goods.

USA Regulations:
SARA Section 302 Extremely Hazardous Substances: Does not have a TPQ.
SARA 311/312: Immediate health hazard. See section 2.
Section 313: No chemicals are reportable under Section 313.
California Proposition 65: Not listed.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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