Sodium Perborate Tetrahydrate SDS, MSDS Sheet

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Sodium Perborate CAS Number 7632-04-4 or 11138-47-9 (Anhydrous), - 10332-33-9 Monohydrate) - 10486-00-7 (Tetrahydrate),
EINECS EC Number 231-556-4 or 234-390-0 (Anhydrous, Monohydrate),
Molecular Formula: BNaO3 Anhydrous, BNaO3.H2O Monohydrate, BNaO3 • 4H2O Tetrahydrate
Molecular Weight 81.82 Anhydrous, 99.81 Monohydrate, 153.86 Tetrahydrate,
HS Code 28403000

Sodium Perborate Tetrahydrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 05-Dec-20

Product Name & Other Names: Sodium Perborate or Tetrahydrate Perborax or Hydrate of Peroxometaborate.
CAS No.: 10486-00-7
EINECS: EC Number: 239-172-9
Molecular Weight: 153.86
Chemical Formula: NaBO3-4H2O
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3, (H272)
Acute toxicity, Oral Category 4, (H302)
Serious eye damage Category 1, (H318)
Acute toxicity, inhalation Category 3 (H331)
Specific target organ toxicity - single exposure Category 3, (H335)
Reproductive toxicity Category 1B, (H360)

Hazard statements:
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.

Precautionary statements:
P201 Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220 Keep/Store away from clothing/ combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P330: Rinse mouth.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Water spray, Foam for extinction.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P308+313: IF exposed or concerned: Get medical advice/attention.
P405: Store locked up.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container to an authorized agent only.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC:
Hazard Symbols:
T = Toxic
O = Oxidizing
Xn = Harmful
Xi = Irritant
Risk Phrases:
R8 Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R23 Toxic by inhalation.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility.

Product Name & Other Names: Sodium Perborate or Tetrahydrate Perborax or Hydrate of Peroxometaborate.
CAS No.: 10486-00-7
EINECS: EC Number: 239-172-9

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

Flammability of the Product: Non-flammable but it is an oxidizer.
Products of Combustion: It emits toxic oxides of boron, sodium and fumes when heated to decomposition.
Fire: It is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray, Foam. Use means suitable for extinguishing surrounding fire. Avoid carbon dioxide and gas filled extinguisher.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Eliminate all sources of ignition. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Eliminate all sources of ignition. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system if local laws permit.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool <32C, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like combustible substances, organic substances, reducing agents, powdered metals, strong bases, alcohols, phosphorous, anhydrides, halogens, acids, metal powders.

Airborne Exposure Limits: None established. Limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White crystals or powder.
Odor: None.
Odor threshold: Not available.
pH: 10 at 1% solution at 25 C (77F)
Relative density: Not available.
Melting Point: Decomposes at 60C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 153.86
Chemical Formula: NaBO3-4H2O

Stability: It is stable under ordinary conditions of use and storage. It becomes unstable by heat and moisture.
Hazardous Decomposition Products: Oxygen, oxides of sodium, boron oxides and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Strong reducing agents, Powdered metals, Strong bases, Alcohols, phosphorous, Anhydrides, Halogens, Acids, Metal powders and Reducing agents.
Conditions to Avoid: Moisture, Heat, Incompatibles.

Toxicity to Animals:
ORAL (LD50): 1908 mg/kg (Rat) on anhydrous basis.
ORAL (LD50): 1060 mg/kg [Mouse] on anhydrous basis.
Intravenous (LD50 ): 600 mg/kg (Cat) on anhydrous basis.
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

BOD5 and COD: Not available.
Environmental Toxicity:
LC50/96h: 51 mg/l (Brachydanio rerio) on anhydrous basis.
NOEC/48h: 8 mg/l (Daphnia magna) on anhydrous basis.
NOEC/96h: 25 mg/l (Brachydanio rerio) on anhydrous basis.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

DOT USA, TDG Canada & ADR/RID Europe
Shipping Name: OXIDIZING SOLID, N.O.S. (Sodium peroxometaborate tetrahydrate)
Hazard Class: 5.1; Packing Group: III
UN Number: UN1479
IMDG/IMO
Shipping Name: OXIDIZING SOLID, N.O.S. (Sodium peroxometaborate tetrahydrate)
Hazard Class: 5.1; Packing Group: III
UN Number: UN1479
Marine pollutant: No
IATA/ICAO
Shipping Name: OXIDIZING SOLID, N.O.S. (Sodium peroxometaborate tetrahydrate)
Hazard Class: 5.1; Packing Group: III
UN Number: UN1479

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard, Immediate (Acute) Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

MUBY CHEMICALS
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GHS Label Elements Oxidizing Solid	GHS Label Elements Health Hazard
GHS Label Elements Toxic	GHS Label Elements Corrosive