Gentian Violet SDS, MSDS Sheet

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Gentian Violet SDS Crystal Violet Methylrosanilinium Chloride
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 02-Dec-20

Product Name & Other Names: Gentian Violet or Methylrosanilinium Chloride or Crystal violet or CI Basic Violet 3.
CAS No.: 548-62-9
EINECS EC Number: 208-953-6
Molecular Weight: 407.99
Chemical Formula: C25H30ClN3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral Category 4, H302
Serious eye damage Category 1, H318
Carcinogenicity Category 2, H351, H410
Hazardous to the aquatic environment, long-term hazard Category 1

Hazard statements:
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H351: Suspected of causing cancer.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 : Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
C Corrosive.
Xn Harmful.
Xi Irritant.
N Dangerous for the environment Harmful.
Risk Phrases:
R21/22 Harmful in contact with skin and if swallowed.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: Gentian Violet or Methylrosanilinium Chloride or Crystal violet or CI Basic Violet 3.
CAS No.: 548-62-9
EINECS EC Number: 208-953-6

Inhalation: Allow the victim to rest in a well-ventilated area. Seek immediate medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes and wash before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention immediately.

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Dilute with water and mop up or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.
Large Spill: Contain spilled material. Cover with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizers. Store away from sources of heat, moisture.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Gentian Violet is dark green powder or greenish glistening pieces having a metallic luster.
Odor: Gentian Violet has slight characteristic odor.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: 215C (419F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 407.99
Chemical Formula: C25H30ClN3

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: When heated to decomposition it emits toxic fumes of nitrogen oxides and hydrogen chloride.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Incompatibles.

Acute toxicity:
LD50 Oral - Mouse - 96 mg/kg.
LD50 Oral - Rabbit - 150 mg/kg.
LD50 Intraperitoneal - Rat - 8,9 mg/kg.
LD50 Intraperitoneal - Mouse - 5,1 mg/kg.
LD50 Intraperitoneal - Rabbit - 5 mg/kg.
LD50 Intraduodenal - Rabbit - 160 mg/kg.
Investigated as a tumorigen, mutagen, reproductive effector.
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.

Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0,35 mg/l - 48 h
Toxicity to algae: EC50 - Pseudokirchneriella subcapitata - 0,42 mg/l - 72 h
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused material in accordance with legal requirements.

DOT USA, TDG Canada & ADR/RID Europe:
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III
Emergency Response Guide Number 171
IMDG/IMO:
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III
IATA/ICAO:
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III

USA:
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA): This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories: Acute health hazard, Chronic Health Hazard. See section 2.
California Proposition 65: This product does not contain any Proposition 65 chemicals.

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H318 = Causes serious eye damage.
H351 = Suspected of causing cancer.
H410 = Very toxic to aquatic life with long lasting effects.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

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