Benzyl Alcohol SDS MSDS Sheet

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Benzyl Alcohol SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 01-Dec-20

Product Name & Other Names: Benzyl Alcohol or Benzenecarbinol; benzenemethanol or alpha-hydroxytoluene or Phenylmethyl alcohol or Phenyl carbinol.
CAS No.: 100-51-6
EINECS EC-No.: 202-859-9
Molecular Weight: 108.14
Chemical Formula: C6H5CH2OH
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral Category 4, H302
Acute toxicity, dermal Category 4, H312
Skin corrosion/irritation Category 2, H315
Acute toxicity, inhalation Category 4, H332
Hazardous to the aquatic environment, acute hazard Category 2, H401

Hazard statements:
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H401: Toxic to aquatic life.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P501 Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn = Harmful
Risk Phrase:
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R38 Irritating to skin.
R51 Toxic to aquatic organisms.

Product Name & Other Names: Benzyl Alcohol or Benzenecarbinol; benzenemethanol or alpha-hydroxytoluene or Phenylmethyl alcohol or Phenyl carbinol.
CAS No.: 100-51-6
EINECS EC-No.: 202-859-9

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Fire: Flash point: 93C (199F)
Auto ignition temperature: 436C (817F). Combustible. High heat or direct flame is necessary to cause ignition.
Explosion: Above the flash point, explosive vapor-air mixtures may be formed.
Fire Extinguishing Media: Dry chemical, foam, or carbon dioxide. Do not use a solid stream of water since the stream will scatter and spread the fire. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Benzyl Alcohol is Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Finish cleaning by spreading water on the contaminated surface and dispose as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, oxidizing agents, and aluminum. Outside or detached storage is preferred. Inside storage should be in a standard flammable liquid storage room or cabinet. Separate from oxidizing materials. Storage and use areas should be No Smoking areas. Containers may be hazardous when empty.

Airborne Exposure Limits: AIHA Workplace Environmental Exposure Level (WEEL):10 ppm, 8-hour, TWA
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear, colorless liquid.
Odor: Faint aromatic odor.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.05
Boiling Point: 205C (401F)
Melting Point: -15C (5F)
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Density (Air=1): 3.72
Vapor Pressure (mm Hg): 0.15 @ 25C (77F)
Evaporation Rate (BuAc=1): 1.8 (Ether = 1)
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 1g/25ml water @ 17C
Viscosity: Not available.
Molecular Weight: 108.14
Chemical Formula: C6H5CH2OH

Stability: Stable under ordinary conditions of use and storage. Undergoes slow oxidation in the presence of air or oxygen to form benzaldehyde and benzoic acid.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: When heated past 100C, Benzyl Alcohol containing hydrogen bromide and dissolved iron may polymerize with a rapid increase in temperature.
Incompatibilities: Acids, oxidizing agents, and aluminum. Will attack some plastics.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

Oral rat LD50: 1230 mg/kg
LD50 Oral - Rat - male - 1.620 mg/kg
Skin rabbit LD50: 2000 mg/kg; irritation, skin rabbit, standard Draize, 100 mg/24-hour, open, moderate.
Mutagenic Effects: Mutagenic for bacteria and/or yeast.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Environmental Fate: When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material may evaporate to a moderate extent. When released into the soil, this material may biodegrade to a moderate extent. When released into water, this material is not expected to evaporate significantly. When released into water, this material may biodegrade to a moderate extent. This material has an estimated bio concentration factor (BCF) of less than 100. This material is not expected to significantly bio accumulate. When released into the air, this material is expected to be readily degraded by reaction with photo chemically produced hydroxyl radicals. When released into the air, this material is expected to have a half-life between 1 and 10 days. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition.
Toxicity to fish LC50 - Lepomis macrochirus (Bluegill): 10 mg/l - 96 h
LC50 - Pimephales promelas (fathead minnow): 460 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates:
EC50 - Daphnia magna (Water flea) - 55 mg/l - 24 h
- Daphnia magna (Water flea) - 230 mg/l - 48 h
Environmental Toxicity: The LC50/96-hour values for fish are from 10 to over 100 mg/l. This material may be toxic to aquatic life.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.
IATA/ICAO: Not regulated.

USA:
SARA 311/312: See section 2.
SARA 302 Extremely Hazardous Substance: None present in regulated quantities.
SARA 304 Emergency Release Notification: None present or none present in regulated quantities.
SARA 313 (TRI Reporting): None present or none present in regulated quantities.
US California Proposition 65: No ingredient regulated by CA Prop 65 present.

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H312 = Harmful in contact with skin.
H315 = Causes skin irritation.
H332 = Harmful if inhaled.
H401 = Toxic to aquatic life.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

MUBY CHEMICALS
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