Ammonium Bicarbonate SDS MSDS Sheet
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Ammonium Bicarbonate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 30-Sep-201. Product Identification
Product Name & Other Names: Ammonium Bicarbonate, Ammonium hydrogen carbonate; Ammonium acid carbonate.
CAS No.: 1066-33-7
EINECS EC Number: 213-911-5
Molecular Weight: 79.06
Chemical Formula: NH4HCO3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:Acute toxicity, Oral Category 4, H302
Hazardous to the aquatic environment, acute hazard Category 3, H402Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
IrritantSignal Words: Warning
Hazard statements:
H302 Harmful if swallowed.
H402: Harmful to aquatic life.Precautionary statements:
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P314: Get Medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P501 Dispose of contents/ container to an approved waste disposal plant.Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn: Harmful
Risk Phrases:
R22: Harmful if swallowed.
R52 Harmful to aquatic organisms.3. Composition/Information on Ingredients
Product Name & Other Names: Ammonium Bicarbonate, Ammonium hydrogen carbonate; Ammonium acid carbonate.
CAS No.: 1066-33-7
EINECS EC Number: 213-911-54. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt, or waistband. If large amounts were swallowed, get medical advice.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.5. Fire Fighting Measures
Fire: Not considered to be a fire hazard. Irritating and toxic ammonia gas and nitrogen oxides may form in fires.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, caustic alkalis, and strong oxidizing agents. Store at temperatures below 80F (27C) to minimize decomposition. Segregate from nitrites and alkaline substances. Storage and transport only combined with food materials or food additives. Separate from flavoring agents. Segregate from strong acids. Segregate from strong bases. Do not store with: Sodium nitrate, nitrite, and similar materials.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Fine white crystals.
Odor: Slight ammonia odor.
Odor threshold: Not available.
pH: 7.8
Relative density: 1.59
Melting Point: 107.5C (226F) (Decomposes 36-60C)
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 17.4% @ 20C (68F) in water.
Viscosity: Not available.
Molecular Weight: 79.06
Chemical Formula: NH4HCO310. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Burning may produce ammonia, nitrogen oxides. Burning may produce ammonia, carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Can react dangerously with acids, caustic alkalis, and strong oxidizing agents.
Conditions to Avoid: Heat, incompatibles.11. Toxicological Information
Acute toxicity: LD50 Oral - Rat - 1576 mg/kg
Carcinogenicity: The product is not classed as carcinogen by IARC, ACGIH, NTP, OSHA.
Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.12. Ecological Information
Toxicity to fish:
LC50 Fish 1: 0.16 - 1.1 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
LC50 Fish 2: 0.615 - 0.712 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
Environmental Toxicity: Harmful to aquatic life. Avoid release to the environment.
Persistence and Degradability: Not likely to persist due to water solubility.
Mobility: Mobile due to water solubility.
Bioaccumulation/ Accumulation: Unlikely to accumulate.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
IMDG/IMO: Not dangerous goods.
IATA/ICAO: Not dangerous goods.15. Regulatory Information
USA:
California Proposition 65: Not Listed
SARA 302: Not Listed
SARA 304: Not Listed
SARA 311: No SARA Hazards
SARA 312: No SARA Hazards
SARA 313: Not Listed.16. Other Information
European Labeling in Accordance with EC Directives:
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
H302 Harmful if swallowed.
H402: Harmful to aquatic life.
Hazard Symbol:
Xn: Harmful
Risk Phrases:
R22: Harmful if swallowed.
R52 Harmful to aquatic organisms.Disclaimer:
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Our company provides this SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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