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Barium Chloride Anhydrous SDS MSDS Sheet
Barium Chloride Dihydrate Anhydrous Manufacturers Specifications
MSDS of Barium Chloride Dihydrate Manufacturers
Barium Chloride Anhydrous SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Barium Dichloride; Barium Di Chloride
CAS No.: 10361-37-2
EINECS: EC Number: 233-788-1
Molecular Weight: 208.23
Chemical Formula: BaCl2 (Barium Chloride Anhydrous)
Relevant Uses: Industrial use only.
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral: Category 3
Serious eye damage/eye irritation Category 2A
Acute toxicity, Inhalation: Category 4
Acute aquatic toxicity: Category 3
Labeling according Regulation (EC) No 1272/2008
GHS Label Elements
GHS Label Elements
Signal Words: Danger
H301: Toxic if swallowed.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H402: Harmful to aquatic life.
Hazards not otherwise classified (HNOC):
May causes mild skin irritation
May cause mild respiratory irritation
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P273: Avoid release to the environment.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P:273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. P337+P313: If eye irritation persists get medical advice/attention.
Remove contact lenses if present and easy to do – continue rinsing.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403+P404: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.
3. Composition/Information on Ingredients
Ingredient: Barium Chloride Anhydrous
CAS No.: 10361-37-2
EINECS: EC Number: 233-788-1
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended. Monitor patients with significant ingestion for respiratory, cardiovascular, and blood pressure status. Watch for cardiac arrhythmias, respiratory failure due to flaccid paralysis of respiratory muscles, pulmonary edema, vocal cord paralysis, severe hypertension, and late effect kidney failure. Acute barium poisoning results in hypokalemia. The administration of fluids containing dilute concentrations of potassium salts may be indicated.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Products of Combustion: Not available.
Fire: It is not considered to be a fire hazard.
Explosion: Barium Chloride is not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: It is a poisonous solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.
7. Handling and Storage
Toxic! Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist barium chloride and concentrated solutions can corrode steel. When exposed to the atmosphere, it will absorb water and form a solution.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Permissible Exposure Limit (PEL) is 0.5 mg (Bad)/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: White powder or granules.
Odor: It is odorless.
Solubility: It is freely soluble in water, exothermic.
pH: Not available.
Density: 3.856 g/mL at 25C (77F)
Molecular formula: BaCl2
Molecular weight: 208.23
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 1560C
Melting Point: 962C
10. Stability and Reactivity
Stability: Barium Chloride Anhydrous is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic chlorine fumes when heated to decomposition. It may form barium oxide and hydrogen chloride and chlorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, bromine trifluoride, 2 -furan percarboxylic acid.
Conditions to Avoid: Incompatibles.
11. Toxicological Information
Toxic, and may be fatal, if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled. Typical TLV/TWA 0.5 mg m-3.
ORL-RAT LD50 118 mg kg-1
SCU-RAT LD50 178 mg kg-1
IPR-MUS LD50 54 mg kg-1
IVN-MUS LD50 12 mg kg-1
ORL-MAM LD50 398 mg kg-1
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
Toxicity to fish: static test LC50 - Danio rerio (zebra fish) - > 174 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 14,5 mg/l - 48 h
Toxicity to algae: Growth inhibition EC50 - Pseudokirchneriella subcapitata (green algae) - > 100 mg/l - 72 h
Toxicity to bacteria: Respiration inhibition EC50 - Sludge Treatment - > 1.000 mg/l - 3 h
Environmental Toxicity: Barium chloride accumulates in plants when it exceeds calcium and magnesium levels in soil. It is also toxic to fish.
BOD5 and COD: Not available.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
US DOT, ADR/RID, IMDG & Canada TDG Classification: UN-Number: 1564 CLASS 6.1: Poisonous material. Packing group: III
Identification: Barium Compound, n.o.s. (Barium Chloride) UNNA: 1564 PG: III
Special Provisions for Transport:
Marine Pollutant No
Poison Inhalation Hazard: No
UN-Number: 1564 Class: 6.1 Packing group: III
Proper shipping name: Barium compound, n.o.s.
15. Regulatory Information
OSHA Hazards: Target organ effect, Toxic by inhalation, Toxic by ingestion
Target Organs: Heart, Nerves, Kidneys, Gastrointestinal tract, Bone marrow, Spleen, Liver.
TSCA: CAS# 10361-37-2 is listed on the TSCA inventory.
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA Codes: CAS # 10326-27-9: immediate, delayed. CAS # 10361-37-2: immediate, delayed.
SARA 313 Components: This material contains Barium chloride anhydrous (listed as Barium compounds, n.o.s.), 99+%, (CAS# 10361-37-2) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Acute Health Hazard. Chronic Health Hazard.
Massachusetts Right To Know Components: No Components Listed
Pennsylvania Right To Know Components: Barium chloride anhydrous, CAS-No. 10361-37-2
New Jersey Right To Know Components: Barium chloride anhydrous; CAS-No. 10361-37-2
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
HMIS (Perceived): Health Hazard: 2, Fire Hazard: 0, Reactivity: 0, Personal Protection: E
NFPA (Perceived): Health: 2, Flammability: 0, Reactivity: 0
WGK (Water Danger/Protection)
Canada - DSL/NDSL: CAS# 10361-37-2 is listed on Canada's DSL List.
Canada - WHMIS: This product has a WHMIS classification of D1B.
Canadian Ingredient Disclosure List: CAS# 10361-37-2 is listed on the Canadian Ingredient Disclosure List.
DSL Status: All components of this product are on the Canadian DSL list.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
EINECS: EC Number: 233-788-1
Hazard Symbols: T = toxic
Risk Phrases: R 25 Toxic if swallowed. R 20 Harmful by inhalation.
Safety Phrases: S 45 In case of accident or if you feel unwell, seek medical advice immediately. S28- After contact with skin, wash immediately with plenty of water. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S46- If swallowed, seek medical advice immediately.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Last 21 August, 2017
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