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Ammonium Chloride SDS MSDS Sheet

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Ammonium Chloride BP USP IP ACS Analytical Reagent Food Grade FCC Food grade Manufacturers Specifications

Commercial Information, Specifications and Uses click Ammonium Chloride Manufacturers Specifications

Ammonium Chloride SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Sal ammoniac; Ammonium muriate, Salamaka, Salmiac, Muriate of Ammonia
CAS No.: 12125-02-9
EINECS EC Number: 235-186-4
Molecular Weight:
53.49
Chemical Formula: NH4Cl
Relevant Uses: Industrial use only.
Supplier: As per letterhead.

2.Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Eye irritation (Category 2A), H319
Hazardous to the aquatic environment, acute hazard Category 3

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H402: Harmful to aquatic life.

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P501 Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22
Xi Irritant R36
For the full text of the H-statements and R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Ammonium Chloride
CAS No.: 12125-02-9
EINECS EC Number: 235-186-4
Percent
: 99 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: Ammonium Chloride is not considered to be a fire hazard. At fire temperatures ammonium chloride begins to corrode metals and may dissociate into ammonia and hydrogen chloride. Mixtures of about 16% to 25% (by volume) ammonia gas in air are flammable.
Explosion: It is not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

7. Handling and Storage

Keep in a tightly closed container. Protect it from physical damage. Store it in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers of Ammonium Chloride material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Ammonium chloride:
-ACGIH Threshold Limit Value (TLV): 10 mg/m3 (TWA); 20 mg/m3 (STEL) Fume
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

pH of Ammonium Chloride : 5.5 (1% aq.sol.); 5.1 (3% aq.sol.); 5.0 (10% aq.sol.)
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 520C (968F)
Melting Point: 338C (640F) Sublimes
Vapor Density (Air=1): 1.9
Vapor Pressure (mm Hg): 1.0 @ 160C (320F)

10. Stability and Reactivity

Stability: Ammonium Chloride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Ammonium Chloride involvement in a fire causes decomposition to form hydrogen chloride and ammonia.
Hazardous Polymerization: Will not occur.
Incompatibilities: Concentrated acids, strong bases, silver salts, potassium chlorate, ammonium nitrate, bromine trifluoride and iodine heptafluoride. Ammonium Chloride reacts explosively with potassium chlorate or bromine trifluoride, and violently with bromide pentafluoride, ammonium compounds, nitrates and iodine heptafluoride. Explosive nitrogen trichloride may result from reaction of ammonium chloride and hydrogen cyanide.
Conditions to Avoid: Heat, moisture, incompatibles.

11. Toxicological Information

Oral rat LD50 : 1650 mg/kg Investigated as a mutagen.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

12. Ecological Information

Toxicity to fish:
LC50 - Cyprinus carpio (Carp) - 209,00 mg/l - 96 h
LC50 - Oncorhynchus mykiss (rainbow trout) - 3,98 mg/l - 96 h
NOEC - Oncorhynchus mykiss (rainbow trout) - 57 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna (Water flea) - 161 mg/l - 48 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Environmental Toxicity: Toxic to aquatic life.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Ammonium Chloride in accordance with legal requirements.

14. Transport Information

DOT (USA) & ADR/RID:
Not Regulated
IMDG
:
Not dangerous goods
IATA:
Not dangerous goods

15. Regulatory Information

USA:
TSCA: CAS# 12125-02-9 is listed on the TSCA inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
SARA Section 302 (RQ): CAS# 12125-02-9: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
SARA Codes: CAS # 12125-02-9: acute, chronic.
Section 313: No chemicals are reportable under Section 313.
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: CAS# 12125-02-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
CAS# 12125-02-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed.
WGK (Water Danger/Protection): CAS# 12125-02-9: 1

Canada: CAS# 12125-02-9 is listed on Canada's DSL List. This product has a WHMIS classification of

D2B. CAS# 12125-02-9 is listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): This product has a WHMIS classification of D2B.

Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.

16. Other Information

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Hazard Symbols:
Xn = Harmful
Xi = Irritant
Risk Phrases: R 22 = Harmful if swallowed. R 36 Irritating to eyes.
Safety Phrases: S 22 = Do not breathe dust.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Contact

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Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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Last 19 May, 2017

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