Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance & Flavor chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.
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Calcium Nitrite SDS MSDS Sheet

Specifications of Calcium Nitrite Manufacturers

Calcium Nitrite Crystals SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Calcium Salt of Nitrous Acid, Calcium dinitrite, Daraset.
CAS No.
: 13780-06-8
EINECS: EC Number: 237-424-2.
Molecular Weight: 132.09
Chemical Formula: Ca(NO2)2 ( Calcium Nitrite)
Relevant Uses: Industrial use only.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3
Acute toxicity - Oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2B
Hazardous to the aquatic environment, acute hazard Category 3

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizing Solid
Oxidizing Solid

GHS Label Elements
Health Hazard
Health Hazard

Signal Word: Warning

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H320: Causes eye irritation.
H402: Harmful to aquatic life.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash thoroughly after handling.
P273: Avoid release to the environment.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorized agents.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
O Oxidizer
Xn Harmful
Xi Irritant
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms

3. Composition/Information on Ingredients

Ingredient: Calcium Nitrite
CAS No.: 13780-06-8
EINECS: EC Number: 237-424-2.
Percent: 94 - 100% Apart from the assay, it has mainly Calcium Nitrate.

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable. However the product supports combustion.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: When heated to decomposition, emits acid fumes.
Fire: Calcium Nitrite is not considered to be a fire hazard though it supports combustion as an oxidizer.
Explosion: Containers may explode in the heat of a fire.
Fire Extinguishing Media: Preferably use water sprat. Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Calcium Nitrite  is a Strong Oxidizer. May decompose explosively when heated or involved in a fire. May accelerate burning if involved in a fire.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Calcium Nitrite in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Calcium Nitrite is white crystals or powder or granules.
Odor: It is odorless.
Solubility: It is freely soluble in water.
pH: Not known.
Density: : 2.26 gm/cc.
Molecular formula: Ca(NO2)2
Molecular weight: 132.09
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not known.
Melting Point: 390C.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Calcium Nitrite is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic acid fumes when heated to decomposition. Nitrogen oxides (NOx), Calcium oxide are formed.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reactive with reducing agents, organic materials. The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.
Conditions to Avoid: Incompatibles. Avoid contact with combustible material (paper, wool, oil).

11. Toxicological Information

Toxicity to Animals: LD50 (Oral-Rat) 940 mg/kg
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: IARC: 2A - Group 2A: Probably carcinogenic to humans.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

BOD5 and COD: Not available.
Environmental Fate: Based on available information Calcium Nitrite will not biodegrade or bio accumulate.
Environmental Toxicity: The product may be harmful to plants, animals and fish.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Proper Shipping Name: Nitrites, Inorganic, (Calcium Nitrite)
U.N. No.: 2627
Hazard Class and Packing Group Number: 5.1, PG II
Marine Pollutant: NO

15. Regulatory Information

USA:
OSHA
: Not Listed
TSCA: Listed
CERCLA: (RQ) Not Listed
SARA Title III Information:
Extremely Hazardous Substance
: Not Listed
Toxic Chemicals: Not Listed
Hazard Category: Immediate (Acute), Fire Hazard
US SARA reporting requirements: The components of this product are subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, and are listed as follows:
Chemical Name Calcium Nitrite (as Nitrite Compounds, Water Dissociable)
SARA 302 (40 CFR 355, Appendix A) No
SARA 304 (40 CFR Table 302.4) No
SARA 313 (40 CFR 372.65) Yes
US SARA Hazard categories (section 311/312, 40 CFR 370-21): Acute: Yes; Chronic: Yes; Fire: No; Reactive: No; Sudden Release: No
US TSCA Inventory Status: The components of this product are on the U.S. TSCA Inventory.
New Jersey - Right to Know Hazardous
Substance List: Calcium Nitrite.

Canadian DSL Inventory: The components of this product are on the DSL Inventory.
Canadian WHMIS Symbols: Class D2B: Materials Causing Other Toxic Effects.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H320: Causes eye irritation.
H402: Harmful to aquatic life.
O Oxidizer
Xn Harmful
Xi Irritant
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms
S Phrases:
S07/09 - Keep container tightly closed and in well-ventilated place.
S17 - Keep away from combustible material.
S35 - This material and its container must be disposed of in a safe way.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Contact

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA & Canadian Customers may
e-mail: usa@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 21 August, 2017

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