Aluminium Chloride Aluminum Chloride Hexahydrate Manufacturers, SDS MSDS Sheet

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Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 30-Nov-20

Product Name & Other Names: Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate or Aluminum trichloride hexahydrate or Trichloro aluminum hexahydrate
CAS Number: 7784-13-6
EINECS: EC Number: 231-208-1
Chemical Formula: AlCl3-6H2O
Molecular Weight: 241.43
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Acute toxicity, Oral (Category 5), H303
Skin corrosion/irritation (Category 2), H315
Serious eye damage/eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), H335
Acute aquatic toxicity (Category 3), H402

Hazard statements:
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant
Xn Harmful
Risk Phrases:
R36/37/38 = Irritating to eyes, respiratory system, and skin.
R52 = Harmful to aquatic organisms.

Product Name & Other Names: Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate or Aluminum trichloride hexahydrate or Trichloro aluminum hexahydrate.
CAS Number: 7784-13-6
EINECS: EC Number: 231-208-1
Percent: almost 100%

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.

Flammability of the Product: The product is not flammable.
Flammable Limits: NA.
Products of Combustion: It forms oxides of aluminum and hydrochloric acid when heated to decomposition.
Fire: Non flammable.
Explosion: not known.
Fire Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Avoid formation of dust and aerosols. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alkalis, and moisture.

Airborne Exposure Limits: None established. Assure it as below 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Crystals or powder or granules.
Odor: Mild typical.
Odor threshold: Not available.
pH: Not available.
Relative density: around 2.4
Melting Point: 100C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Readily soluble in water.
Viscosity: Not available.
Molecular Weight: 241.43
Molecular Formula: AlCl3-6H2O

Stability: Stable under ordinary conditions of use and storage. It must be kept in air tight containers.
Hazardous Decomposition Products: It produces oxides of aluminum along with hydrochloric acid when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Incompatible with water including moisture, oxidizing material and alkalis.
Conditions to Avoid: Moisture, Heat, Sun light, Incompatibles.

Toxicity to Animals:
Oral, mouse: LD50 = 1990 mg/kg;
Oral, rat: LD50 = 3311 mg/kg;
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Environmental Toxicity:
Toxicity to fish: LC50 - fish - 27.1 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 27.3 mg/l - 48 h
BOD5 and COD: Not available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Aluminum chloride Hexahydrate in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe:
Not Regulated.
IMDG/IMO:
Not Regulated.
IATA/ICAO:
Not Regulated.

USA:
OSHA Hazards: Irritant.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: This material contains Aluminum chloride hexahydrate (listed as ** undefined **), 100%, (CAS# 7784-13-6) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

MUBY CHEMICALS
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