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Lithium Carbonate BP USP Grade Manufacturers, SDS GHS MSDS Sheet
Lithium Carbonate: CAS Number: 554-13-2, EINECS EC Number: 209-062-5, Molecular Formula: Li2CO3, Molecular Weight: 73.89, HS Code ---**
For SDS MSDS Sheet Click
SDS MSDS Sheet of Lithium Carbonate Manufacturers
Pure BP USP
Lithium Carbonate BP Grade
Li2CO3 --- 73.9 --- 554-13-2
Content: 98.5 per cent to 100.5 per cent.
Appearance: White or almost white powder.
Solubility: Slightly soluble in water, practically insoluble in ethanol (96 per cent).
A. When moistened with hydrochloric acid, it gives a red colour to a non-luminous flame.
B. Dissolve 0.2 g in 1 ml of hydrochloric acid. Evaporate to dryness on a water-bath. The residue dissolves in 3 ml of ethanol (96 per cent).
C. It gives the reaction of carbonates.
Solution S: Suspend 10.0 g in 30 ml of distilled water and dissolve by the addition of 22 ml of nitric acid. Add dilute sodium hydroxide solution until the solution is neutral and dilute to 100 ml with distilled water.
Appearance of solution: Solution S is clear and colourless.
Chlorides: Maximum 200 ppm.
Sulphates: Maximum 200 ppm.
Arsenic: Maximum 2 ppm, determined on 0.5 g.
Calcium: Maximum 200 ppm.
Iron: Maximum 20 ppm.
Magnesium: Maximum 150 ppm.
Potassium: Maximum 300 ppm.
Sodium: Maximum 300 ppm.
Lithium Carbonate USP GradeIdentification:
Li2CO3 --- 73.89
Carbonic acid, dilithium salt.
Dilithium carbonate -- [554-13-2].
Lithium Carbonate contains not less than 99.0 percent of Li2CO3, calculated on the dried basis.
A: It effervesces upon the addition of an acid, yielding a colorless gas which, when passed into calcium hydroxide, immediately causes a white precipitate to form.
B: When moistened with hydrochloric acid, it imparts an intense crimson color to a nonluminous flame.
Reaction: A saturated solution is alkaline to litmus.
Loss on drying: Dry it at 200 for 4 hours: it loses not more than 1.0% of its weight.
Insoluble substances: Transfer 10 g to a 250-mL beaker, add 50 mL of water, then add slowly 50 mL of 6 N hydrochloric acid. Cover with a watch glass, and boil the solution for 1 hour. Filter the solution through a dried, tared filtering crucible fitted with a glass-fiber filter disk, using suction. Wash the filter with hot water until the last washing is free from chloride when tested with. Dry the crucible in an oven at 110 for 1 hour: the weight of the residue is not more than 0.02% of the weight of Lithium Carbonate taken.
Chloride: To 500 mg of it add 1.2 mL of nitric acid, dilute with water to 50 mL, and add 1 mL of silver nitrate any turbidity formed is not greater than that produced in a similarly treated control solution containing 0.50 mL of 0.020 N hydrochloric acid (0.07%).
Sulfate: Dissolve 1.0 g in 10 mL of 3 N hydrochloric acid, dilute with water to 40 mL, and add 1 mL of barium chloride. Prepare a standard solution of equal volume containing 1.0 mL of 0.020 N sulfuric acid, 1 mL of 3 N hydrochloric acid, and 1 mL of barium chloride. The turbidity produced in the test solution, after 3 minutes, is not greater than that produced in the standard solution (0.1%).
Aluminum and iron: Dissolve 500 mg in 10 mL of water by the dropwise addition, with agitation, of hydrochloric acid. Boil the solution, then cool it, and to 5 mL of the solution add 6 N ammonium hydroxide until the reaction is alkaline: no turbidity or precipitate is observed.
Calcium: Suspend 5.0 g in 50 mL of water, and add a slight excess of 3 N hydrochloric acid. Boil the clear solution to expel carbon dioxide, add 5 mL of ammonium oxalate, render alkaline with 6 N ammonium hydroxide, and allow to stand for 4 hours. Filter through a filtering crucible, and wash with warm water until the last washing yields no turbidity with calcium chloride. Place the crucible in a beaker, cover it with water, add 3 mL of sulfuric acid, heat to 70 , and titrate with 0.10 N potassium permanganate to a pale pink color that persists for 30 seconds. Not more than 3.76 mL of 0.10 N potassium permanganate is consumed (0.15%).
Sodium: the sodium limit is 0.1%.
Heavy metals: the limit is 0.002%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last : 11 April, 2017
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Lithium Carbonate GHS SDS, MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Carbolithium, Carbonic acid lithium salt
CAS No.: 554-13-2
EINICS EC-No.: 209-062-5
Molecular Weight: 73.89
Chemical Formula: Li2CO3
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, oral Category 4
Serious eye damage/eye irritation Category 2A
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Words: Warning
H302: Harmful if swallowed.
H319: Causes serious eye irritation.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P270: Do not eat, drink or smoke when using this product.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorised agents only.
Labelling in accordance with Directive 67/548/EEC:
Symbols: Xi Irritant
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.
3. Composition/Information on Ingredients
Ingredient: Lithium Carbonate
CAS No.: 554-13-2
EINICS EC-No.: 209-062-5
4. First Aid Measures
Always get medical attention after the first aid is over.
Inhalation: If Lithium Carbonate is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire: Not considered as a fire hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas.
7. Handling and Storage
Keep Lithium Carbonate in a tightly closed container, stored in a cool, dry, ventilated area. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Protect against physical damage. Containers of Lithium Carbonate may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: OSHA-PELs TWA: 15 (Total dust), 5 (Respirable fraction) as Particulates not otherwise classified
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Lithium Carbonate is white to off-white crystals or powder.
Solubility: Slightly soluble in water.
Density: 1,6 g/cm3 at 20 °C
pH: Approximately 9-11.
% Volatile by volume @ 21C (70F): 0
Molecular Weight: 73.89
Chemical Formula: Li2CO3
Melting Point: 618C - lit.
10. Stability and Reactivity
Stability: Lithium Carbonate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide along with lithium oxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Excessive heat, Strong oxidizers and acids.
Conditions to Avoid: Heat, dusting and incompatibles.
11. Toxicological Information
LD50 Oral - Rat - 525 mg/kg(Lithium carbonate)
LC50 Inhalation - Rat - 4 h - > 2.17 mg/l(Lithium carbonate)
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
12. Ecological Information
Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 30.3 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 33.2 mg/l - 48 h
Mobility in soil: No data available
PBT & vPvB: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Lithium Carbonate in accordance with legal requirements.
14. Transport Information
DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
ADR/RID: Not regulated
15. Regulatory Information
TSCA 12(b): Listed
SARA 313: Not applicable
Canada WHMIS Hazard: Class D2A Very Toxic materials
DSL: Listed on DSL.
16. Other Information
EINICS EC-No.: 209-062-5Disclaimer:
Xi = Irritant
R36= Irritating to eyes.
H302 = Harmful if swallowed.
H319 = Causes serious eye irritation.
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.