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Cerium Ceric Ammonium Nitrate SDS MSDS Sheet

Cerium Ceric Ammonium Nitrate Manufacturers Specifications

Ceric Ammonium Nitrate SDS MSDS Sheet, Material Safety Data Sheet Cerium Ammonium Nitrate

1. Product Identification

Synonyms: CAN, Ammonium Hexanitratocerate (IV), Diammonium Hexanitratocerate, Hexanitrato Ammoniumcerate, Ceric Ammonium Nitrate, Ammonium Cerium Nitrate.
CAS No.: 16774-21-3
EINECS: EC Number: 240-827-6
Molecular Weight: 548.23
Chemical Formula: (NH4)2Ce(NO3)6
Intended Use: Industrial Manufacturing
SUPPLIER: As per Letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing liquids; Oxidizing solids Category 3
Acute toxicity, oral Category 4
Skin corrosion/irritation Category 1A, B, C
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizer
Oxidizing Solid

GHS Label Elements
Corrosive
Corrosive

Signal Word: Danger

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC
Hazard Symbols
: XN O
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 8 Contact with combustible material may cause fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.

OSHA Hazards: Oxidizer, Toxic by ingestion, Irritant
HMIS (Perceived): Health hazard: 2, Flammability: 0, Physical hazards: 2
NFPA (Perceived): Health hazard: 2, Fire: 0, Reactivity Hazard: 2

3. Composition/Information on Ingredients

Ingredient: Ceric Ammonium Nitrate
CAS No.: 16774-21-3
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable but it is an oxidizer.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: It emits toxic oxides of nitrogen when heated to decomposition.
Fire: Ceric Ammonium Nitrate is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ceric Ammonium Nitrate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with combustible substances.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Cerium ammonium nitrate is Orange Red or Orange Yellow crystals or powder or granules.
Odor: Slight.
Solubility: 141g/100ml water @ 25C (77F).
pH: Not available at 10% solution at 25C (77F)
Density: No information found.
Molecular formula: (NH4)2Ce(NO3)6
Molecular weight: 548.23
% Volatile by volume @ 21C (70F): 0
Boiling Point: > 1600C (> 2912F)
Melting Point: 107C with decomposition for Ceric Ammonium Nitrate.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Cerium Ammonium Nitrate is stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.
Hazardous Decomposition Products: It emits toxic oxides of nitrogen when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Metal powders and Reducing agents.
Conditions to Avoid: Incompatibles.

11. Toxicological Information

Toxicity to Animals: LD50: Not available. LC50: Not available.
Special Remarks on Toxicity to Animals: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

BOD5 and COD: Not available.
Environmental Fate: No information found.
Environmental Toxicity: The material is not considered as environmental hazard.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

14. Transport Information

DOT (USA)
UN number: 1477 Class: 5.1 Oxidizing material. Packing group: II
Proper shipping name: Nitrates, inorganic, n.o.s.
Reportable Quantity (RQ):
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 1477 Class: 5.1 Packing group: II EMS-No: F-A, S-Q
Proper shipping name: NITRATES, INORGANIC, N.O.S.
Marine pollutant: No
IATA
UN number: 1477 Class: 5.1 Packing group: II
Proper shipping name: Nitrates, inorganic, n.o.s.

15. Regulatory Information

USA:
OSHA Hazards
: Oxidizer, Toxic by ingestion, Irritant.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: This material contains Ammonium cerium(IV) nitrate (listed as Water Dissociable Nitrate Compounds), 98+%, (CAS# 16774-21-3) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Acute Health Hazard.
TSCA: CAS# 16774-21-3 is listed on the TSCA inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
SARA Codes: CAS # 16774-21-3: immediate, fire.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed.
Massachusetts Right To Know Components: No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components: Diammonium hexanitratocerate, CAS-No. 16774-21-3
New Jersey Right To Know Components: Diammonium hexanitratocerate, CAS-No. 16774-21-3
WGK (Water Danger/Protection): CAS# 16774-21-3: 1

Canada - DSL/NDSL: CAS# 16774-21-3 is listed on Canada's DSL List.
Canada - WHMIS: This product has a WHMIS classification of C, D2B.
Canadian Ingredient Disclosure List: CAS# 16774-21-3 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

EINECS: EC Number: 240-827-6
H272 = May intensify fire; oxidizer.
H302 = Harmful if swallowed.
H314 = Causes severe skin burns and eye damage.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
Hazard Symbols: Xn = Harmful; O = Oxidizer; N = Dangerous for the environment
Risk Phrases:
R 22 = Harmful if swallowed.
R 36/37/38 = Irritating to eyes, respiratory system and skin.
R 41 = Risk of serious damage to eyes.
R 8 = Contact with combustible material may cause fire.
Safety Phrases:
S 17 = Keep away from combustible material.
S 26 = In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 = Wear suitable gloves and eye/face protection.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Last 21 August, 2017

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