Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ethyl 4-Chloroacetoacetate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid: CAS Number: 638-07-3, EINECS EC Number: 211-317-0, Molecular Formula: C6H9ClO3 or ClCH2COCH2CO2C2H5, Molecular Weight: 164.59, HS Code ---**

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SDS MSDS Sheet of Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid Manufacturers

Ethyl 4-Chloroacetoacetate
Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid Pure Suppliers
Ethyl 4-Chloroacetoacetate

Ethyl-4-chloro-acetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid ethyl ester is used in pharmaceutical coating, formulation and regular film coating.

General Properties and Specifications of Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid ethyl ester:
Appearance: Colorless transparent liquid.
Assay: 97% minimum.
Ethyl acetoacetate: 1.12%
Relative density: around 1.21
Refractive Index: 1.4495-1.4545 @ 20C
Melting point: -8C.
Boiling Point: 115C at 14mm Hg.
Flash Point: 92C.
Solubility: Miscible with water and most organic solvents.

We also manufacture and supply as under:

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2-Chlorobenzaldehyde

4-Chlorobenzaldehyde

Ethyl 4-Chloroacetoacetate

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3-Methoxy-1-Propanol

Ethyl Acetate

Aluminum Acetate

Butyl Acetate

Ethyl Acetoacetate

Ethyl 4-Chloroacetoacetate

Ethyl Cyanoacetate.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 26 August, 2022

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Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 18-Oct-20

1. Product Identification

Product Name & Other Names: Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid.
CAS No.: 638-07-3
EINECS EC Code: 211-317-0
Molecular Weight: 164.59
Chemical Formula: C6H9ClO3 or ClCH2COCH2CO2C2H5
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Category 1B), H314
Chronic aquatic toxicity (Category 1), H410
Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Word: Danger

Hazard Statements:
H301 + H311 Toxic if swallowed and in contact with skin.
H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P220: Keep/Store away from clothing/other combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
C Corrosive
N Dangerous for the environment
Risk Phrase:
R24/25 Toxic in contact with skin and if swallowed
R34 Causes burns
R41 Risk of serious damage to eyes
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. Composition/Information on Ingredients

Product Name & Other Names: Ethyl 4-Chloroacetoacetate or Ethyl 4-chloro-3-oxobutanoate or 4-Chloroacetoacetic acid.
CAS No.: 638-07-3
EINECS EC Code: 211-317-0

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If is inhaled, it will cause irritation and damage to nose and throat. It can cause headache, bleeding from nose coughing and chest discomfort. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: It will cause irritation and burns to mouth, digestive tract and stomach. It may lead to pain, nausea, vomiting, and even collapse. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: Flash point: 92C. The material is combustible.
Toxic fumes, carbon dioxide, carbon monoxide, hydrogen chloride may be formed in fire.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet. No limitation of suitable extinguishing media is specified, however, avoid solid water jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental  precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Mop and pick up the material and place in an appropriate waste disposal container. Soak up with inert absorbent material and dispose of as hazardous waste. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Avoid mist formation. Wear full protective equipment and ensure proper ventilation. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Vacuum or sweep up and remove to disposal container.

7. Handling and Storage

Precautions for safe handling: Keep away from heat and source of fire preferably in a ventilated area. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Keep locked up in tightly closed container. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not ingest. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, acids, bases and reducing agents. Containers may be hazardous when empty since they retain product residues. Do not store near food items. Light sensitive. Store under inert gas. Moisture sensitive.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Colorless transparent liquid.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.21
Melting point/freezing point: -8C.
Initial boiling point and boiling range: 115C at 14mm Hg.
Flash point: 92C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Miscible with water and most organic solvents.
Viscosity: Not available.
Molecular Weight: 164.59
Chemical Formula: C6H9ClO3 or ClCH2COCH2CO2C2H5

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, hydrogen chloride and toxic fumes may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Oxidizing agents acids, bases and reducing agents.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

LD50 Oral Rat: 200 mg/kg.
LD50 Oral, Mouse: 150 mg/kg;
LC50 Inhalation Rat - 6 h: > 1.4 mg/l.
LD50 Dermal Rabbit: 200 - 316 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSGHA or NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity to fish: LC50 - Danio rerio (zebra fish) - 3 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 3 mg/l - 48 h.
Biodegradability: The product is biodegradable.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA & ADR/RID Europe
UN Number: 2922
Proper shipping name: CORROSIVE LIQUID, TOXIC, N.O.S. (ethyl 4-chloroacetoacetate)
Class: 8 (6.1), Packing group: II
IMDG & IATA
UN Number: 2922
Proper shipping name: CORROSIVE LIQUID, TOXIC, N.O.S. (ethyl 4-chloroacetoacetate)
Class: 8 (6.1), Packing group: II

15. Regulatory Information

USA:
California Prop 65
: Not listed.
SARA 302 Components: Not listed.
SARA 313 Components: Not listed.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H301 + H311 Toxic if swallowed and in contact with skin.
H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
C Corrosive
N Dangerous for the environment
Risk Phrase:
R24/25 Toxic in contact with skin and if swallowed
R34 Causes burns
R41 Risk of serious damage to eyes
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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